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超临界流体色谱分析有机污染物 总被引:5,自引:0,他引:5
概述了超临界流体色谱的进展,特点、原理及影响超临界流体色谱测定的主要因素。介绍了超临界流体色谱与其他测定仪器的联用技术。列举了该技术在分析环境样品中有机污染物的应用。如分析有机氯、有机磷和氨基酸酯及农药的残留组分,多环芳烃,芳香烃等化合物。 相似文献
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超临界CO2处理含氰废水初步研究 总被引:8,自引:0,他引:8
超临界CO2能萃取出含氰废水中的CN^-,萃取物在压力降低时释放出来,释放物用饱和FeCl2溶液吸收稳定。萃取的最佳条件是:压力为10MPa-15MPa,温度为30-50℃,时间为20min-30min。 相似文献
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为对比研究超临界态CO_2、液态CO_2和气态N_2注入采空区的防灭火性能,自主研制了模拟采空区残煤自燃过程实验系统,开展了超临界态CO_2、液态CO_2和气态N_2注入采空区防灭火实验。实验结果表明:12 MPa、39℃超临界态CO_2对采空区自燃残煤的降氧降温能力优于6 MPa、30℃液态CO_2优于6 MPa、39℃气态N_2;12 MPa、39℃超临界态CO_2对残煤的降温能力是6 MPa、30℃液态CO_2的1.7倍,是6 MPa、39℃气态N_2的10倍,对采空区的降温能力是液态CO_2的2倍,为气态N_2的8倍;12 MPa、39℃超临界CO_2对采空区的降氧速率比6 MPa、30℃液态CO_2和6 MPa、39℃气态N_2高12.5%;12 MPa、39℃超临界CO_2的降温能力是8 MPa、39℃超临界CO_2的1.7倍,因此适当提高超临界态CO_2的注入压力,防灭火性能更佳。 相似文献
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On December 7, 2009, a 50-foot-tall high-pressure vessel ruptured in the Nihon Dempa Kogyo Crystal, Inc. facility in Belvidere, Illinois. Several projectiles rapidly traveled outward from the facility, killing a truck driver 650 feet away and injuring an employee in another building 435 feet away. This paper summarizes the lessons learned from this incident both on causal and consequential aspects. Stress corrosion cracking was identified as the failure mechanism by the U.S. Chemical Safety and Hazard Investigation Board. After analyzing the operating conditions and the aftermath, this incident has been identified as a Boiling Liquid Expanding Vapor Explosion (BLEVE) under a supercritical pressure. A consequence analysis of the incident is performed where overpressure and fragment distance are calculated, together with safety distance estimation. Additionally, other safety-related problems, such as safety culture, management inside the corporation, and communication between this facility and the government are discussed. 相似文献
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Yan Wang Guanyi Chen Yanbin Li Beibei Yan Donghui Pan 《Waste management (New York, N.Y.)》2013,33(11):2408-2415
Environment-friendly treatment of sewage sludge has become tremendously important. Conversion of sewage sludge into energy products by environment-friendly conversion process, with its energy recovery and environmental benefits, is being paid significant attention. Direct liquefaction of sewage sludge into bio-oils with supercritical water (SCW) was therefore put forward in this study, as de-water usually requiring intensive energy input is not necessary in this direct liquefaction. Supercritical water may act as a strong solvent and also a reactant, as well as catalyst promoting reaction process. Experiments were carried out in a self designed high-pressure reaction system with varying operating conditions. Through orthogonal experiments, it was found that temperature and residence time dominated on bio-oil yield compared with other operating parameters. Temperature from 350 to 500 °C and reaction residence time of 0, 30, 60 min were accordingly investigated in details, respectively. Under supercritical conversion, the maximum bio-oil yield could achieve 39.73%, which was performed at 375 °C and 0 min reaction residence time. Meanwhile, function of supercritical water was concluded. Fuel property analysis showed the potential of bio-oil application as crude fuel. 相似文献
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Eremurus spectabilis samples were liquefied in organic solvents (methanol, ethanol and acetone) with (sodium hydroxide and ferric chloride) and without catalyst in a cylindrical reactor at temperatures of 270, 290 and 310 °C under supercritical conditions. The effects of liquefaction parameters such as temperature, catalyst and solvent on product yields were investigated. The liquid products were extracted with diethyl ether and benzene using an extraction procedure. The product yields in supercritical methanol, ethanol and acetone were found to as 41.6%, 53.8% and 64.3% in the non-catalytic runs at 310 °C, respectively. The highest conversion was obtained in supercritical acetone in the presence of ferric chloride (10%) at same temperature in the catalytic runs. The produced liquids in acetone were analyzed and characterized by elemental, Fourier transform infrared spectroscopy (FT-IR), gas chromatography–mass spectrometry (GC–MS). The liquid products (bio-oils) obtained with acetone contained various types of components including aromatics, nitrogenated and oxygenated compounds. As the bio-oils obtained exhibit high heat values, E. spectabilis is presented as a potential feedstock candidate for production of bio-fuels or valuable chemicals. 相似文献
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Akio Kamimura Eisuke Konno Shigehiro Yamamoto Takeru Watanabe Kazuo Yamada Fumiaki Tomonaga 《Journal of Material Cycles and Waste Management》2009,11(2):133-137
The synthesis of recycled plastics from recovered monomeric materials obtained from the depolymerization reaction of fiber-reinforced
plastics (FRP) was examined. The depolymerization reaction of FRP in the presence of N,N-dimethylaminopyridine (DMAP) smoothly yielded the corresponding monomers, which mainly consisted of dimethyl phthalates.
The polymerization reaction with this monomer failed to form the corresponding unsaturated polyesters due to contamination
by N-methyl-4-pyridone, a decomposition product of DMAP. An efficient purification of the recovered monomer was achieved by washing
with water, and the purified monomer successfully yielded the corresponding polymers. A hardness test revealed that the polymers
were as hard as the polyester made from virgin materials. The present modification provides a practical method for the preparation
of recycled plastics from depolymerized plastics. 相似文献
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Sodium 3,5,6-trichloropyridin-2-ol (STCP) is a necessary precursor compound for the production of chlorpyrifos and triclopyr, which are extensively used as pesticide and herbicide, respectively. In the process of STCP production, however, large amount of wastewater containing STCP is discharged, which causes increasingly environmental concerns. Therefore, it is of great significance to develop a rapid and effective method for the disposal of containing STCP contaminants. In this work, the thermal decomposition of STCP in sub- and supercritical water was investigated using a continuous tubular reactor. While STCP was stable below 280 °C, it could be effectively decomposed at elevated temperature. FT-IR spectra of the decomposition products indicated that the pyridine ring structure in the STCP molecule was stable even at temperatures up to 400 °C. The decomposition reaction was mainly caused by the substitution of Cl groups in the STCP molecule with OH groups, resulting in polyhydroxylated pyridines as the major decomposition product. Moreover, high pressure favored the substitution reaction. To completely decompose STCP into non-toxic or low toxic compounds, supercritical water oxidation (SCWO) was employed to evaluate the oxidation of STCP using H2O2 as an oxidant. It was found that STCP could be completely oxidized to H2O, CO2 and corresponding inorganic ammonium salts with an oxidation rate of 99%. 相似文献