煤矿危险源风险预警与控制的研究

根据现代安全管理的理论与方法,结合煤矿人-机-环境特点和不同煤矿事故的发生机理,对煤矿危险源风险预警和控制的基本理论和方法进行了探讨,提出了基于危险源的煤矿风险预警与控制的一般流程,给出煤矿危险源辨识、风险评价、监控和预警的方法,为煤矿安全管理信息系统提供理论基础。     

一种基于事故后果的重大危险源安全规划方法

介绍了一种基于事故后果的重大危险源安全规划方法。该方法详细阐述了“最坏”事故情景选择、事故后果阈值确定及后果伤害范围划分的方法,以危险源周边人群作为主要脆弱性目标,通过分析事故后果伤害范围和目标的脆弱性级别确定危险源与周边环境的兼容性。另外,以危险品仓储区为例,利用该方法对仓储区可能发生的事故后果影响范围进行计算,对仓储区选址的可行性进行分析。本文提出的重大危险源安全规划方法可为城市土地使用及危险源的安全规划提供参考。     

Acid generation upon thermal concentration of natural water: The critical water content and the effects of ionic composition

Thermal evaporation of a variety of simulated pore waters from the region of Yucca Mountain, Nevada, produced acidic liquids and gases during the final stages of evaporation. Several simulated pore waters were prepared and then thermally distilled in order to collect and analyze fractions of the evolved vapor. In some cases, distillates collected towards the end of the distillation were highly acidic; in other cases the pH of the distillate remained comparatively unchanged during the course of the distillation. The results suggest that the pH values of the later fractions are determined by the initial composition of the water. Acid production stems from the hydrolysis of magnesium ions, especially at near dryness. Near the end of the distillation, magnesium nitrate and magnesium chloride begin to lose water of hydration, greatly accelerating their thermal decomposition to form acid. Acid formation is promoted further when precipitated calcium carbonate is removed. Specifically, calcium chloride-rich pore waters containing moderate (10–20 ppm) levels of magnesium and nitrate and low levels of bicarbonate produced mixtures of nitric and hydrochloric acid, resulting in a precipitous drop in pH to values of 1 or lower after about 95% of the original volume was distilled. Waters with either low or moderate magnesium content coupled with high levels of bicarbonate produced slightly basic fractions (pH 7–9). If calcium was present in excess of bicarbonate, waters containing moderate levels of magnesium produced acid even in the presence of bicarbonate, due to the precipitation of calcium carbonate. Other salts such as halite and anhydrite promote the segregation of acidic vapors from residual basic solids. The concomitant release of wet acid gas has implications for the integrity of the alloys under consideration for containers at the Yucca Mountain nuclear waste repository. Condensed acid gases at very low pH, especially mixtures of nitric and hydrochloric acid, are capable of corroding even alloys, such as nickel-based Alloy 22, which are considered to be corrosion-resistant under milder conditions.     

Structure and thermal stability of toxic chromium(VI) species doped onto TiO2 powders through heat treatment

Chromium(VI)-containing sorbents in the form of sludge or solid residue from treatment processes are often landfilled or used as fill materials, therefore the long-term stability of metal binding is important. The reduction of Cr(VI)–Cr(III) through heat treatment may be a useful detoxification method. After heating at 500, 900, 1000, and 1100 °C for 4 h, the transformation of chemical states of chromium on 105 °C-dried, 7.9% Cr(VI)-doped TiO₂ powders was studied on the basis of surface area measurements, scanning electron microscopy (SEM) images, X-ray diffraction (XRD), and extended X-ray absorption fine structure (EXAFS) spectra. It was shown that Cr(VI) was reduced to Cr(III) in the Cr(VI)-doped samples after heating within 500–900 °C. The present results also suggested that the chromium octahedral was bridged to the titanium tetrahedral and was incorporated in TiO₂ minerals formed after 1000 °C treatment.     

基于道化法(DOW)的计算机辅助软件开发

传统的评价方法费时费力,效率低下.将计算机技术与评价方法相结合是评价工作发展的趋势.介绍了为世界各国石油化工企业所广为接受的美国道化学公司(DOW)火灾、爆炸危险性指数评价法,以及根据该法的评价思路所开发的辅助软件的设计思路和功能.     

风险管理在水电工程中的应用

水电工程是一个在建设过程中充满风险的、相当复杂的系统工程,其风险管理伴随着工程建设的全过程.随着我国水电工程建设体制改革的进一步深化,风险管理越来越受到工程界的重视.分析了在水电工程中存在的主要危险有害因素,提出了具体的风险管理和评价方法,并对一些主要的评价方法进行了大致的比较,同时对水电工程的风险管理工作提出了一些改进措施.     

化学品危险性鉴别分类研究的现状与展望

从对GHS(化学品分类及标记全球协调制度)化学品危险性鉴别分类的分析出发,归纳和总结了联合国、欧盟、美国以及中国的化学品危险性鉴别分类研究现状;提出化学品危险性鉴别分类是获取化学品安全信息、评估化学品的固有危险性的重要手段;给出化学品危险性鉴别分类试验必须满足OECD(经济合作与发展组织)的各项标准和准则;对化学品危险性鉴别分类的应用前景及未来工作进行评述和展望;指出为化学品安全管理、事故应急救援、事故调查及做好基础数据的积累是今后研究工作的努力方向;提出了借鉴GHS,REACH(化学品注册、评估、许可和限制)等先进化学品安全监管法规,对完善我国的化学品安全监管制度,化学品鉴别分类标准的重要现实意义。     

我国商用厨房火灾危险分析及对策研究

烹饪操作特点及食用油燃烧特性决定了商用厨房火灾呈现的特定危害规律,因此必须采用专门规范和技术加以防治。针对我国商用厨房消防安全现状,分析其火灾危险特点,探讨商用厨房消防监管的不足,在研究商用厨房灭火技术发展的基础上,提出加强商用厨房消防安全和健全商用厨房法规体系的对策及建议,建议从主动灭火和被动防火两方面,完善现有的灭火系统和厨具设备消防安全规范,加强商用厨房本质型消防安全,为通风系统和排油烟系统等火灾高发区域的消防安全提供了新手段。     

成都市土壤天然放射性核素的外照射水平估算研究

利用IED22000A便携式微机多道能谱仪对成都市区土壤的天然放射性核素进行了直接就地测量,估算出天然环境放射性核素^238U、^232Th、^40K的比活度范围分别为10.37～77．19Bq／kg、17,85～225．74Bq／kg、284．83～892．67Bq／kg;外照射指数范围为0．16—0．8;离地面1m高的空气吸收剂量率均值为83．23nGy／h;1外照射年有效剂量当量为0．34～0．70mSv;等效镭浓度的变化范围是59．06-386．45Bq／kg,均值为164．15Bq／kg。各项指标均在容许范围之内,因而成都市属于外照射水平的安全区域,人居环境不受影响。     

论重大危险源理论与实践之结合

重大危险源及其监管越来越受到关注,历经十多年,重大危险源的表述及其基本定义并没有取得共识而完全统一,现在开始实施重大危险源申报登记制度,涉及重大危险源的辨识、评价、分级等大量的具体工作,相关的理论和方法应用比较复杂。笔者就有关问题提出了自己的看法,认为重大危险源分级不仅是一项技术方法,而且是一项政策性行为,标准的制定一定要紧密联系实际,有利推动安全生产工作。