我国触电防护基础理论和观念存在问题剖析

触电形式、触电防护措施、供电系统的选择属于触电防护的基本问题.就触电形式而言,存在分类不完整、不同分类之间缺乏联系等问题,从触电相关导电体着手,提出了多层次系统化触电形式分类方法.就触电防护措施而言,就IEC最新标准由“平面式”分类转向“立体式”分类的深层意义进行了解读,并对“立体式”分类方法仍存在的问题进行了分析,提出了改进建议;指明我国翻译制定的等同标准未能充分体现IEC“立体式”分类方法的真正用意.就供电系统选择而言,“只能借用过流保护装置完成漏电保护”时代已经结束,建议我国从标准层面上放弃对TN供电系统的推荐,积极推广TT系统.     

添加SO42-对SCR中V2O5基催化剂性能影响的实验研究

通过实验,研究了添加SO42-对SCR中V2O5基催化剂活性和热稳定性的影响。实验时,在催化剂制作过程中加入硫酸铵,通过浸渍法制得活性物质V2O5的含量均为1%,而SO42-的含量不同的催化剂,并在自制的固定床反应器上,在NH3/NOx为1.0,模拟烟气流量为72L·h-1的条件下对其活性进行了研究。结果表明,当加入的SO42-质量分数为5.01%时,对催化剂活性的提高最显著。随后在TGA92热重-差热分析仪上进行了热重实验,分析结果表明添加的硫酸根可以轻微提高热稳定性,且不会影响电厂SCR催化剂的使用。     

若尔盖高原湿地生态旅游资源保护性开发研究

若尔盖湿地以其独特的自然和人文景观为湿地生态旅游提供了有利条件。本文从分析若尔盖湿地的旅游资源入手，提出了若尔盖湿地生态旅游资源保护性开发的几点建议。     

掘进巷道风流温度分布规律的数值模拟

根据紊流状态下的守恒原理 ,导出了描述掘进巷道风流紊流流动和温度分布的微分方程。通过对矿内风流流动及热力过程的理论分析及现场实测 ,系统地开展矿内风流流场和风流温度场的分布规律及其耦合作用机理的理论分析与研究 ,并利用PHOENICS程序进行数值模拟 ,初步得出了矿井掘进巷道风流温度与各种参数的变化规律。掘进巷道风流温度随风速提高呈负幂函数规律降低 ,随入风流温度升高而线性升高。     

An incident investigation on an unexpected loss of containment and damage to PHI-TEC II during acrylonitrile runaway tests

This article investigates a laboratory incident that occurred during the analysis of a thermal runaway reaction of acrylonitrile monomer. This failure, which was attributed to an human error, resulted in financial losses and corresponding unexpected results. The incident not only damaged the interior of the vessel and other instrument parts, but also exposed the researchers to considerable danger, necessitating their escape from the laboratory. The failure characteristics are discussed, and countermeasures are developed to prevent such a type of incident from reoccurring.     

长江中游现代河流沉积物磁组构参数值特征研究

对长江中游簿洲湾一带不同类型河段(平直和弯曲)、不同水文环境(高滩、低滩、心滩)沉积物磁组构参数特征的系统取样、测量和统计分析结果表明：1)平直河段沉积物的磁化率各向异性参数的K、P、F、Fs、T以及E的统计平均值均比弯曲河段处相应磁组构参数值略偏大。而q、L的统计平均值却比弯曲河段河流沉积物的相应磁组构值略偏小；2)平直河段各向异性量值椭球长轴磁偏角方向明显，其与水流作用方向具有很好的一致性。而在弯曲河段各向异性量值椭球长轴磁偏角的方向分散，反映了在弯曲河段处水流具有方向多变的特点；3)从河流高滩、低滩到心滩沉积物的磁化率各向异性参数P、F、Fs、T、E的统计平均值均具有从小逐渐变大，而磁基质颗粒度q、磁线理L却从大逐渐变小的变化趋势。这一特点与溃口、高水位时沉积环境不稳定，水流方向多变的、沉积物分选性差的特点是一致的。研究结果对研究古河道的演化、变迁、古河道的识别确定具有重要的意义。     

Full scale treatment of ASR wastes in a modified rotary kiln

A plant, designed for the thermo-valorisation of tyres, was specifically modified in order to treat Automobile Shredder Residue (ASR). Results from two full-scale combustion experiments, carried out on large ASR feeding lots (thousands of tons) indicate the proposed technology as a potential route to help the fulfilling of impending 95% reuse and recovery target set by the End of life Vehicle (ELV) Directive (January 2015). The paper describes the main operational troubleshot occurred during the first experiment (emissions at the stack out of regulatory limits and problems of clogging on the conveyer belt) and the consequent upgrading solutions (pre-treatment, introduction of waste double low-flow screw feeder and a cyclone prior to the main fan, modification of rotatory kiln inlet) adopted to allow, during the second long-term experiment, a continuous basis operation of the plant in full compliance with the discharge limit to the atmosphere. Characterization of both ASR and combustion residues allowed to quantify a 18% of combustion residues as not dangerous waste while only the 2% as hazardous one. A pre-treatment for the reduction of fines in the ASR was recommended in order to achieve the required energy recovery efficiency.     

Thermal risk in batch reactors: Theoretical framework for runaway and accident

Thermal safety and risk of accidents are still challenging topics in the case of batch reactors carrying exothermic reactions. In the present paper, the authors develop an integrated framework focusing on defining the governing parameters for the thermal runaway and evaluating the subsequent risk of accident. A relevant set of criteria are identified in order to find the prior conditions for a thermal runaway: failure of the cooling system, critical temperature threshold, successive derivatives of the temperature (first and second namely) vs. time and no detection in due time (reaction time) of the runaway initiation. For illustrative purposes, the synthesis of peracetic acid (PAA) with hydrogen peroxide (HP) and acetic acid (AA) is considered as case study. The critical and threshold values for the runaway accident are identified for selected sets of input data. Under the conditional probability of prior cooling system failure, Monte Carlo simulations are performed in order to estimate the risk of thermal runaway accident in batch reactors. It becomes then possible to predict the ratio of reactors, within an industrial plant, potentially subject to thermal runaway accident.     

Pressure and temperature increase of LPG in a thermally coated pressure vessel exposed to fire: Experimental and model results

Damage caused by incidents with transport tanks with compressed liquified gas is amongst the most extreme that can be encountered with transport vessels. This is particularly the case with the Boiling Liquid Expanding Vapor Explosion (BLEVE), which may occur if such a tank is exposed to fire for a prolonged period. Therefore, the local Dutch LPG transport sector adopted a thermally insulating tank coating as a ‘standard outfit’ for their tank trailers, with the aim to delay a BLEVE for a sufficiently long period for emergency services to take appropriate measures and for people near the accident location to be evacuated. On a European scale however, no consensus has been reached on the cost-benefit of such measures.With the current drive towards “greener” and renewable energy sources, this issue has regained attention with alternative fuels such as LNG, CNG and Hydrogen and a need was felt for (better) theoretical models and experimental data concerning the behavior of transport tanks carrying these substances.In this paper a new tank thermal (equilibrium) model is described to predict pressure and temperature behavior of a multi layered, thermally insulated tank containing a compressed liquified gas exposed to heat. Results are compared with data of three bonfire experiments, in which 3 m³ tanks, filled for ca. 50% with LPG were exposed to fire. A good match between modelled and experimental pressure and temperature evolution in time could be obtained using a constant value for the thermal conductivity of the insulation layer. The modelling showed that the thermal insulation value is crucial for an accurate prediction of these parameters as well as the opening time for a pressure safety valve. As relevant temperatures may cover a very wide range (from cryogenic in LNG-tanks to over 1000 °C in a fire) knowledge of the thermal (and physical) behavior of the insulating layer over a large temperature range is essential.The same holds for the behavior of the PRV when subjected to fire. Extreme temperatures may also lead to deviating behavior from what is expected based on the initial settings.     

Thermal failure of 2/3 PCP in high temperature environment and optimization analysis of stator and rotor meshing parameters

Progressive cavity pump (PCP), which has problems such as invalid and leakage of rubber bushings, is employed in heavy oil field exploitation. In this paper, based on the thermal aging mechanical test of rubber and the fitting precision evaluation result of the constitutive model, the rubber constitutive model is optimized; the finite element model of PCP is established; the deformation law of stator bushing inner wall is quantitatively analyzed by numerical simulation method; and the phenomenon that temperature field distribution and thermal aging failure of stator rubber bushings is revealed. As results: The increase in well depth, which leads to the increase in the overall temperature of the stator bushing and the decrease of the thermal hysteresis, have greatest influence on the temperature of the stator bushing; the interference, which leads the maximum temperature increases first and then decreases, has a great impact on the thermal hysteresis; and the eccentricity have little effect on the thermal hysteresis of the stator bushing. The research results provide theoretical support to optimize stator and rotor parameter matching, recommending applicable working conditions, improving invalid of stator bushing, pump leakage and other issues.