近10 a武汉市城市热岛效应演变及其#br# 与土地利用变化的关系

城市化进程的加快,农村人口大量涌入城市,城市布局及局部气候改变等因素使得城市热岛效应问题日益突出,已成为当前城市环境研究热点之一。以武汉市为例,应用遥感技术与地理信息系统技术,选取2004~2015年5个时相Landsat系列影像数据,利用单窗算法反演地表温度,并以此为基础进行热岛强度分级,获取了近10 a武汉市城市热岛效应变化结果,并分析了武汉市11个辖区城市热岛效应动态变化特征及热岛效应与土地利用变化的关系。研究结果表明：（1）自2007年后,武汉市老城区热岛面积持续减少,而新城区热岛面积则持续增加,呈现出以老城区为中心向新城区扩张的趋势,至2015年,新老城区热岛面积仅相差20.74 km2;（2）东西湖区、蔡甸区、江夏区与洪山区是近些年城市热岛面积增长较为显著的辖区,其中江夏区的热岛面积年际变化最大,最高值达95.42 km2;（3）城市热岛效应与土地利用类型的面积年际平均值拟合关系显示,2004~2015年,城市热岛效应与建筑用地的R2值最大,为0.681 2,建筑用地面积的增加是城市热岛强度面积扩张的重要影响因素。     

关天经济区农户农地流转行为研究

农地流转是现阶段实现农地规模经营的必经之路。本文基于关天经济区622份调查问卷,建立了农地流转的农户模型,利用Heckman两阶段模型研究了交易成本认知和农户禀赋对农户参与农地流转(转出)、农地流转率的影响。研究结果表明:(1)关天经济区农户参与农地流转的积极性不高,样本农户参与农地流转的仅为23%,农地流转率均值为11%;(2)流转价格了解程度、农地流转组织形式、农地流转合约期限和对外交通便利情况影响农户是否参与农地流转决策,而农地流转率仅受流转价格了解程度和农地流转契约形式影响;(3)劳动力和土地禀赋正向影响农户转出土地,农地流转率随农业生产能力增强而降低;(4)文化程度与农户是否参与农地流转、农地流转率呈现显著的负相关关系,与天水的农户相比,关中地区的农户更倾向于参与农地流转。因此,要促进农户参与农地流转、提升农地流转率,首先要加强农地流转政策的宣传力度,提高农户整体认知水平,增强农户农地流转政策的理解程度和接受能力;其次,深化农村土地产权改革,加快农地确权颁证,提升农户产权的稳定性和可预期性;再次,建立健全农地流转市场,完善市场在农地流转过程中的信号生成机制和传递功能,降低农地流转过程中的交易成本;第四,采取相应的激励政策提高农户土地、劳动力的利用程度,提升农户农业生产能力,避免农户在农地流转市场中的逆向选择行为;最后,建立有效的农地"经营权退出机制",将束缚在农业生产上的低效劳动力和土地释放出来,实现资源的最优化配置。     

Experimental investigation of a solar water distillation-cum-drying unit

In this communication, a new design of solar-energy-based water distillation cum drying unit with parabolic reflector has been designed, fabricated, and tested. Bitter gourd and potato slices are chosen as a drying commodity. Thermal performance of the developed system has been evaluated based on the experimental results and using linear regression analysis. Heat transfer coefficients (convective, evaporative, and radiative) for solar distillation system have been observed to be 2.48–4.09, 13.25–52.38, and 8.75–9.66 W/m²°C, respectively. Overall thermal efficiency and exergy efficiency for the distillation system has been found to be 18.77% and 1.2%, respectively. The convective heat transfer coefficient for potato slices are observed higher for initial hours and decreases as the day progresses. The average convective heat transfer coefficients for bitter gourd and potato slices have been observed as 2.18 and 5.04 W/m²°C, respectively. Experimental error in terms of percent uncertainty for bitter gourd and potato slices are found to be 42.93% and 37.06%, respectively. The present design of solar distillation and drying in a single unit could be beneficial for the development of remote, arid, and rural areas.     

Experimental thermal storage research of organic binary phase change materials in building environment

This paper aims to reveal the heat transfer mechanism of low-temperature phase change material (PCM) and design PCM heat storage device in building heating environment. Firstly, low-temperature binary PCMs of lauric acid and stearic acid are prepared, and their thermal properties are investigated by DSC. Then, shell and tube latent heat thermal energy storage units are conducted, and heat transfer experiments are carried out to analyze the heat transfer mechanism of PCM. The results demonstrate that natural convection plays an important role in heat transfer process, and the heat storage efficiency of PCMs can be significantly enhanced by increasing the fin width and improving the inlet heat transfer fluid (HTF) temperature. Furthermore, some proposals are put forward to guide the design of PCM storage device in building heating environment.     

The impact of the electricity tariff reform on renewable energies and energy efficiency investments: The case of the Italian residential market

This article investigates the impact that the electricity tariff reform is likely to have on investments in renewable energies (i.e., photovoltaics) and the adoption of energy efficiency measures (i.e., installation of heat pumps and efficient home appliances) in the residential market in Italy. The study develops detailed cost comparisons and simulations considering two different investment scenarios (before and after the reform) to conclude that the reform will: (i) have a negative impact on investments in photovoltaic systems; (ii) favor the adoption of energy efficiency measures, such as efficient home appliances.     

高铝粉煤灰提取氧化铝后硅钙渣用作水泥混合材

为了使高铝粉煤灰提取氧化铝后所产生的硅钙渣被大量的用作水泥混合材,通过水泥强度、水化放热和干缩性实验研究了原状硅钙渣和脱碱硅钙渣对水泥强度和稳定性的影响。结果表明,当硅钙渣掺量达30%时,硅钙渣水泥强度仍可满足P·C 32.5水泥要求。且随硅钙渣掺入量的增加,水泥早期水化放热速率增加的同时水泥累计水化放热量和干缩率还会显著降低。与原状硅钙渣相比,在同等掺量的情况下,脱碱硅钙渣更有利于保持水泥强度,降低其水化热和改善干缩性。     

Electrochemical oxidation of herbicide bifenox acid in aqueous medium using diamond thin film electrode

The electrochemical oxidation of bifenox acid was studied at a boron-doped diamond thin film by cyclic voltammetry and galvanostatic electrolysis. The course of the electrolysis was monitored by measurement of chemical oxygen demand (COD) and by gas chromatography/mass spectrometry (GC / MS) analysis. It was found that exhaustive electrolysis leads to degradation and, ultimately, to mineralization of the starting herbicide. The degradation intermediates were identified showing that the oxidation process begins with the fragmentation of the molecule followed by reactions involving the hydroxyl radical, which is generated by the discharge of water. The study of the effect of current density and concentration showed that the degradation efficiency increases with decreasing current densities and increasing concentrations. The whole results were interpreted in a mechanistic scheme involving two oxidation pathways, the first is a direct oxidation at the electrode and the second uses hydroxyl radical as mediator of the oxidation. Finally, a kinetic study based on spectrophotometric measurements showed that the degradation process is pseudo first order.     

热真空设备中与温度相关的试验技术探讨

以RZHM-1400-AB型热真空试验箱为实例,简述设备主要工作原理。强调其温度传递方式及航天产品在热真空试验中温度参数的重要性。以无数试验数据为依据,着重论证何种类型测温传感器与实际设备相匹配,同时论证选取何种外形的测温传感器为最佳温度测量工具。同时,进一步介绍几种在热真空试验中使用这些测温传感器的方法,以减少不必要的人为测量误差。     

PM2.5在线监测技术概述

针对PM2.5颗粒物监测技术和PM2.5的监测网络的建设,重点介绍了美国多年来对PM2.5的监测状况,以及采用的Beta射线法、Beta射线光浊度法、微量振荡天平法等监测技术的方法和原理;指出综合国内外多年的监测经验,PM2.5的在线监测需要经过大量手工经典方法数据作为比对和校验,才能给出有效而高质量的PM2.5监测数据。     

Influence of dissolved humic substances on the mass transfer of organic compounds across the air-water interface

The effect of dissolved humic substances (DHS) on the rate of water-gas exchange of two volatile organic compounds was studied under various conditions of agitation intensity, solution pH and ionic strength. Mass-transfer coefficients were determined from the rate of depletion of model compounds from an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution (dynamic system). Under these conditions, the overall transfer rate is controlled by the mass-transfer resistance on the water side of the water-gas interface. The experimental results show that the presence of DHS hinders the transport of the organic molecules from the water into the gas phase under all investigated conditions. Mass-transfer coefficients were significantly reduced even by low, environmentally relevant concentrations of DHS. The retardation effect increased with increasing DHS concentration. The magnitude of the retardation effect on water-gas exchange was compared for Suwannee River fulvic and humic acids, a commercially available leonardite humic acid and two synthetic surfactants. The observed results are in accordance with the concept of hydrodynamic effects. Surface pressure forces due to surface film formation change the hydrodynamic characteristics of water motion at the water-air interface and thus impede surface renewal.