全文获取类型
收费全文 | 2486篇 |
免费 | 317篇 |
国内免费 | 1021篇 |
专业分类
安全科学 | 540篇 |
废物处理 | 87篇 |
环保管理 | 249篇 |
综合类 | 1840篇 |
基础理论 | 421篇 |
污染及防治 | 437篇 |
评价与监测 | 104篇 |
社会与环境 | 78篇 |
灾害及防治 | 68篇 |
出版年
2024年 | 4篇 |
2023年 | 28篇 |
2022年 | 80篇 |
2021年 | 115篇 |
2020年 | 122篇 |
2019年 | 109篇 |
2018年 | 132篇 |
2017年 | 133篇 |
2016年 | 154篇 |
2015年 | 176篇 |
2014年 | 180篇 |
2013年 | 250篇 |
2012年 | 261篇 |
2011年 | 273篇 |
2010年 | 185篇 |
2009年 | 178篇 |
2008年 | 133篇 |
2007年 | 204篇 |
2006年 | 162篇 |
2005年 | 138篇 |
2004年 | 104篇 |
2003年 | 113篇 |
2002年 | 102篇 |
2001年 | 68篇 |
2000年 | 61篇 |
1999年 | 61篇 |
1998年 | 43篇 |
1997年 | 45篇 |
1996年 | 37篇 |
1995年 | 36篇 |
1994年 | 37篇 |
1993年 | 25篇 |
1992年 | 15篇 |
1991年 | 15篇 |
1990年 | 10篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 2篇 |
1986年 | 5篇 |
1985年 | 4篇 |
1984年 | 1篇 |
1983年 | 4篇 |
1981年 | 1篇 |
1980年 | 2篇 |
1979年 | 3篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1973年 | 1篇 |
1972年 | 1篇 |
1970年 | 1篇 |
排序方式: 共有3824条查询结果,搜索用时 421 毫秒
211.
Bajda T 《Chemosphere》2011,83(11):1493-1501
Due to its relatively low solubility, mimetite Pb5(AsO4)3Cl may control Pb and As(V) solution levels at a low value in contaminated soils. The time-dependent dissolution of mimetite by low-molecular-weight organic acids (LMWOAs) such as acetic, lactic, citric, and ethylene diamine tetra-acetic acid (EDTA) was determined. At pH 3.5, the presence of citric acid or EDTA significantly increases the solubility of mimetite while acetic or lactic acids show little effect. The effect of all organic anions on the dissolution of mimetite increased with the increase in solution pH. The rate of mimetite dissolution depended on the kind and concentration of organic solvents in the sequence rEDTA > rlactate > racetate > rcitrate. Soluble Pb and As(V) released in LMWOAs and EDTA were higher than the WHO guideline value for these elements in drinking water (10 μg As(V) L−1, 10 μg Pb L−1). This suggests that soil organic acids in rhizosphere can potentially liberate Pb and As(V) from mimetite in contaminated soils. 相似文献
212.
Polychlorinated dibenzo-p-dioxins (PCDDs), polychlorinated dibenzofurans (PCDFs), and dioxin-like polychlorinated biphenyls (DL-PCBs) contained in the smoke generated from rice straw burning in post-harvest paddy fields in Japan were analyzed to determine their congener profiles. Both the apportionment of toxic equivalent (TEQ) by using indicative congeners and the comparison of the homolog profiles showed that the PCDDs/PCDFs/DL-PCBs present in the rice-straw smoke were greatly influenced by those present as impurities in pentachlorophenol (PCP) and chlornitrofen (CNP, 4-nitrophenyl-2,4,6-trichlorophenyl ether) formulations that had been widely used as herbicides in paddy fields in Japan. Further, in order to investigate the effects of paddy-field soil on the PCDDs/PCDFs/DL-PCBs present in rice-straw smoke, PCDD/PCDF/DL-PCB homolog profiles of rice straw, rice-straw smoke and paddy-field soil were compared. Rice-straw smoke was generated by burning rice straw on a stainless-steel tray in a laboratory. The results suggested that the herbicides-originated PCDDs/PCDFs/DL-PCBs and the atmospheric PCDDs/PCDFs/DL-PCBs contributed predominantly to the presence of PCDDs/PCDFs/DL-PCBs in the rice-straw smoke while the contribution of PCDDs/PCDFs/DL-PCBs formed during rice straw burning was relatively minimal. The major sources of the PCDDs/PCDFs/DL-PCBs found in the rice-straw smoke were attributed primarily to the paddy-field soil adhered to the rice straw surface and secondarily to the air taken by the rice straw. The principal component analysis supported these conclusions. It is concluded that rice straw burning at paddy fields acts as a driving force in the transfer of PCDDs/PCDFs/DL-PCBs from paddy-field soil to the atmosphere. 相似文献
213.
The bromination of five selected pharmaceuticals (metoprolol, naproxen, amoxicillin, phenacetin, and hydrochlorothiazide) was studied with these compounds individually dissolved in ultra-pure water. The apparent rate constants for the bromination reaction were determined as a function of the pH, obtaining the sequence amoxicillin > naproxen ? hydrochlorothiazide ≈ phenacetin ≈ metoprolol. A kinetic mechanism specifying the dissociation reactions and the species formed for each compound according to its pKa value and the pH allowed the intrinsic rate constants to be determined for each elementary reaction. There was fairly good agreement between the experimental and calculated values of the apparent rate constants, confirming the goodness of the proposed reaction mechanism.In a second stage, the bromination of the selected pharmaceuticals simultaneously dissolved in three water matrices (a groundwater, a surface water from a public reservoir, and a secondary effluent from a WWTP) was investigated. The pharmaceutical elimination trend agreed with the previously determined rate constants. The influence of the main operating conditions (pH, initial bromine dose, and characteristics of the water matrix) on the degradation of the pharmaceuticals was established. An elimination concentration profile for each pharmaceutical in the water matrices was proposed based on the use of the previously evaluated apparent rate constants, and the theoretical results agreed satisfactorily with experiment. Finally, chlorination experiments performed in the presence of bromide showed that low bromide concentrations slightly accelerate the oxidation of the selected pharmaceuticals during chlorine disinfection. 相似文献
214.
用软锰矿吸收SO2生成MnSO4时会伴随有副产物MnS2O6生成。产品中MnS2O6的存在会降低硫酸锰产品质量,同时会缓慢释放出SO2气体污染环境。本文用单因素实验方法研究了粗MnSO4溶液中MnS2O6的最优去除条件。研究结果显示,软锰矿用量为12.2 g,硫酸加入量为20 mL、反应温度100℃、反应时间3 h、搅拌速度500 r/min,MnS2O6的去除率可达91%以上。其最终产品能达到GB1622-1986一级品标准。 相似文献
215.
采用浸渍-热分解法制备了含IrOx-TiO2中间层的IrO2-SnO2电极,得到的电极具有较高的析氯电催化活性和较强的稳定性,并通过电化学氧化法对Na2SO3海水脱硫模拟液进行处理,考察了电流密度、温度、pH值和电解时间等电解工艺参数对Na2SO3去除率和化学需氧量COD的影响。结果表明,在电流密度为200 mA/cm^2,pH值为3.5,电解440 mg/L的Na2SO3海水脱硫模拟液,15 min时Na2SO3去除率可达96.5%,COD去除率可达82.6%。 相似文献
216.
217.
218.
219.
The recovery and utilization of recovered paper have increased over past decades all over the world due to economic, environmental, and social issues. However, it is well known that an extended recovered paper collection is detrimental to its quality, either by the exploitation of lower quality sources such as households, or the spreading of commingled systems instead of selective collection systems. The influence of these two factors was assessed by analyzing the quality of different recovered paper grades used as raw material in a mill located in Madrid (Spain) producing newsprint and light weight coated paper from recovered paper. Part 1 of the paper deals with the impact of increased collection rates on the quality of recovered paper and Part 2 with the use of commingled collection systems. Results of Part 1 show that increased collection rates have a large impact on the quality of the recovered paper. The quality, measured as total unusable material and moisture contents, had deteriorated very rapidly in only 4 years (2005–2008) as a consequence of increased collection rates. Collection rates increased in Spain from 58.5% to 68.6% during this period, resulting in more than 50% increase of total unusable material and 25% of moisture content. The downgrading of the quality of recovered paper is one of the major threats for extending the current limits of paper recycling. Therefore, future challenge is to increase its availability but maintaining its quality. 相似文献
220.
介绍了灰霾遥感监测的基本原理,论述了基于图像变换的TC法、HOT法和基于反演气溶胶光学厚度的灰霾遥感监测技术,以及造成灰霾天气的秸秆燃烧遥感监测方法.指出卫星遥感技术可以提供大尺度、长时间序列的污染物时空分布特征和变化趋势,以及全球性的大气环境综合遥感数据,是灰霾监测与综合治理的重要途径. 相似文献