液/液界面电化学及在环境监测分析中的应用

介绍了液/液界面电化学四种基本结构和主要实验方法,综述了液/液界面电化学分析方法在环境监测分析中的应用。作为一种新方法测定离子载体及能与其形成络合物的金属离子组分的浓度,它具有简便、快捷、经济实用等特点。     

岩溶区地下水补给型水库表层无机碳时空变化特征及影响因素

为更深入地认识岩溶区地下水补给型水库表层无机碳的循环过程,于2014-07-12~2014-07-20期间,以广西上林县大龙洞岩溶水库表层水体为研究体系,对无机碳循环研究的重要指标进行定点观测和高密度的昼夜监测.结果发现:1从上游到下游DIC含量和水体p CO2值逐渐增加[DIC(平均):122.88 mg·L-1增至172.02 mg·L-1,p CO2(平均):637.91×10-6增至1 399.97×10-6],δ13CDIC值逐渐偏负[δ13CDIC(平均):-4.34‰降至-6.97‰].2库区均为大气CO2的源,CO2交换通量在7.11~335.54 mg·(m2·h)-1之间,平均125.03 mg·(m2·h)-1,上游和下游地区CO2交换通量较大[平均131.73 mg·(m2·h)-1、170.25 mg·(m2·h)-1],中游狭窄地区CO2交换通量较小[平均116.05 mg·(m2·h)-1].3表层水体p CO2值和水-气界面CO2交换通量存在晚上升高,白天降低的昼夜变化规律,且与叶绿素a(Chla)呈负相关关系.分析认为:1大龙洞水库表层水体DIC含量、δ13CDIC值和水体p CO2的空间分布主要受浮游植物浓度、浊度、电导率、水深、透明度等的影响,而水-气界面CO2交换通量除了受浮游植物浓度空间变化的影响外还受风速的影响.2浮游植物昼夜垂向运动及光合作用和呼吸作用昼夜变化控制着水库表层水体溶解性无机碳的昼夜循环过程.     

Vigilance monitoring for operator safety: A simulation study on highway driving

INTRODUCTION: Alertness of individuals operating vehicles, aircrafts, and machinery is a pre-requisite for safety of the individual and for avoiding economic losses. In this paper, we present a new technique for determining the alertness level of the operator and elaborate the methodology for the specific case of highway driving METHOD: Our hypothesis is that the time derivative of force exerted by the driver at the vehicle-human interfaces can be used to construct a signature of individual driving styles and to discern different levels of alertness RESULTS: In this study, we present experimental results corroborating this hypothesis and introduce a parameter, 'spikiness index,' for the time series data of the force derivative to quantify driver alertness IMPACT ON INDUSTRY: The low cost, ruggedness, and low-volume data processing requirements of the proposed technique give it a competitive edge over existing predominantly image processing based vigilance monitoring systems.     

Boundary work in climate policy making in Brazil: Reflections from the frontlines of the science-policy interface

Despite challenges to the authority and legitimacy of science as a neutral representation of the world, expert advisors are playing an increasingly central role in environmental policy-making in both the Global North and South. This article explores the science-policy interface, based on the experience of the main author as a scientist and policy-maker at FEAM, a state-level environmental agency in Brazil. Contributing to the literature on boundary objects and organizations, the article details the practices necessary to manage the relationship between political and scientific norms in the development of the regional Climate and Energy Plan (CEP) for the state of Minas Gerais. To sustain the role of FEAM as a boundary organization mediating between political and scientific demands, a team of scientists and policy-makers had to perform different types of boundary work in a closely connected manner. It was necessary to actively frame climate change as an economic problem, and structure its solution in terms of mitigation mechanisms. Responding to changes in the national and international political context, FEAM reframed climate change from mitigation into largely an adaptation issue that could lead to win-win solutions as to attain saliency and avoid insurmountable political obstacles for its approval. Based on this experience, the article argues that the performance of boundary objects and organizations in the science-policy interface not only requires an ability to bring ‘truth to power’ but to also the capacity to sense, anticipate and avoid political obstacles. For this reason even though boundary organizations provide a breeding ground for institutional learning it is an unsuitable location for scientific or political revolutions.     

Democratising planetary boundaries: experts,social values and deliberative risk evaluation in Earth system governance

ABSTRACT

Recent debates about the concept of planetary boundaries recall longstanding concerns about whether ecological limits are compatible with ecological democracy. The planetary boundaries framework (originally set out in Rockström et al., 2009a, 2009b) defines values for key Earth-system processes such as climate change and biodiversity that aim to maintain a ‘safe’ distance from thresholds or levels that could endanger human wellbeing. Despite having a significant impact in policy debates, the framework has been criticised as implying an expert-driven approach to governing global environmental risks that lacks democratic legitimacy. Drawing on research on deliberative democracy and the role of science in democratic societies, we argue that planetary boundaries can be interpreted in ways that remain consistent with democratic decision-making. We show how an iterative, dialogical process to formulate planetary boundaries and negotiate ‘planetary targets’ could form the basis for a democratically legitimate division of labour among experts, citizens and policy-makers in evaluating and responding to Earth-system risks. Crucial to this division of evaluative labour is opening up space for deliberative contestation about the value judgments inherent in collective responses to Earth-system risks, while also safeguarding the ability of experts to issue warnings about what they consider to be unacceptable risks.     

COMPARATIVE STUDY OF FRESH-SALT WATER INTERFACES USING FINITE ELEMENT AND SIMPLE APPROACHES

ABSTRACT: The fresh-salt water interface in artesian aquifers has been investigated by various techniques on the basis of its analogy to the free surface in earth dams or cores of dams. Although various approximations are used, some more or less exact solutions exist. One of the simple methods, that would appeal to practical workers, was developed by the analysis of hydraulic forces. However, this method has not been checked thoroughly due to the lack of wide ranges of coverage by the more or less exact solutions. In this paper a suggested finite element method is used for the purpose of comparing with the method of hydraulic forces. The presented procedure eliminates some of the difficulties and uncertainties in current finite element procedures. Both methods proved to be in close agreement. Moreover, the hydraulic heads along the upper boundary of the artesian aquifer were found to be in close agreement with Dupuit's equation. The results of this investigation would greatly simplify the more complex management problems when the effects of discharge and/or recharge wells are added to the natural flow effects.     

LARGE AREA HYDROLOGIC MODELING AND ASSESSMENT PART II: MODEL APPLICATION1

ABSTRACT: This paper describes the application of a river basin scale hydrologic model (described in Part I) to Richland and Chambers Creeks watershed (RC watershed) in upper Trinity River basin in Texas. The inputs to the model were accumulated from hydro-graphic and geographic databases and maps using a raster-based GIS. Available weather data from 12 weather stations in and around the watershed and stream flow data from two USGS stream gauge station for the period 1965 to 1984 were used in the flow calibration and validation. Sediment calibration was carried out for the period 1988 through 1994 using the 1994 sediment survey data from the Richland-Chambers lake. Sediment validation was conducted on a subwatershed (Mill Creek watershed) situated on Chambers Creek of the RC watershed. The model was evaluated by well established statistical and visual methods and was found to explain at least 84 percent and 65 percent of the variability in the observed stream flow data for the calibration and validation periods, respectively. In addition, the model predicted the accumulated sediment load within 2 percent and 9 percent from the observed data for the RC watershed and Mill Creek watershed, respectively.     

人机操作界面中有或无外部反应对后继作业的干扰作用

实验结果提示：在高速复杂人机系统操作界面的优化设计中,有或无外部反应都不能消除对后继作业的瓶颈干扰。但是,有外部反应比无外部反应,对后继作业的瓶颈干扰更大;无外部反应降低了瓶颈的干扰强度,从而显示出提高了被交叠作业绩效的趋向。另外,降低反应选择复杂度可有效提高被交叠作业的绩效     

钢筋混凝土界面的疲劳损伤

钢筋与混凝土界面的脱粘是钢筋混凝土材料与结构的主要失效形式之一。针对笔者建立的几何剪切筒模型和选取的常用实验加载方式 ,推导出循环荷载作用下钢筋与混凝土界面脱粘应力解析模型 ,借助断裂力学的基本理论 ,进一步研究和分析了界面疲劳脱粘速率及界面摩擦剪应力与循环加载次数的关系 ,同时考虑了泊松比对疲劳特性的影响 ,为混凝土结构的安全评估提供一个新思路。     

Nutrient exchange and release experiment and its simulation study in lake water-sediment interface

The sediment distributed and insolated under lake was collected for experiments. The nutrient layer distribution conditions of sampled sediment and its physical and chemical characteristics were analyzed to simulate and assess the influence degree to lake water quality. Based on the dynamic water exchanging experiments the nutrient release process in sediment and influence mechanism to substance exchanging on water-sediment interface was studied, and the correlation between the changing content of total phosphors and total nitrogen in sediment and covered water were analyzed for setting up a simulation model. At the same time the influence degree is explained in detail. The experimental results indicated that even if clean water without nutrient contents was used for water exchangement so as to decrease pollution or prevent eutrophication, however owing to the vertical nutrient distribution in lake sediment, it will lead to the increasing release amount greatly especially when the organic nutrient contained in sediment turns into inorganic status because of isolation. Besides the release process of total phosphate （TP） and total nitrogen （TN） were modeled and each nutrient＇s exchanging equation at interface caused by covered water nutrient concentration changing was set up. According to the simulating prediction, TP and TN content of cover water will also sustain a steady higher level in a long period. The nutrient release amount of sediment is not only affected by the covered water concentration but also connects with accumulative time. The experiments provide the fundamental theoretical and practical basis for taking ecological restoration project. And research is helpful to prevent or restore lake eutrophication.