空气和废气监测中H2S标液的选择

有2种不同方法制备的H2S标准溶液进行测定,结果表明,所得标准曲线斜率一致,因此,在实际工作中可对其灵活运用。     

浅谈TOC与CODCr的关系

介绍了TOC和CODCr的含义,比较了TOC与CODCr测定方法、使用仪器的不同和各自的优缺点,并从理论上和实际水样测定中论述了TOC和CODCr的相关性。对于不同的废水,TOC 与CODCr的相关性不一样,必须先实验求出二者之间的关系。     

Heavy metals in water, sediment and tissues of Liza saliens from Esmoriz–Paramos lagoon, Portugal

Esmoriz–Paramos lagoon is an ecosystem of great ecological importance that is located on the northwest coast of Portugal and has been degraded as a result of industrial and anthropogenic activities. Concentrations of heavy metals (Cr, Cu, Pb and Zn) were measured in water, sediment and in tissues (liver and muscle) of Liza saliens, which is the dominant fish from the lagoon. Comparisons between metal concentrations in water and sediments were made with those in tissues of fish caught at the lagoon. Metals in water were quantified predominantly bound to particulate and equalled or exceeded the limit of chronic reference values. Metal concentrations in sediments varied among sampled sites. The relative order of concentrations was “Zn > Cu ∼ Pb > Cr” the same pattern observed for metals in water. Metals in fish tissues showed higher concentrations in liver (262 mg Cu·Kg⁻¹ and 89 mg Zn·Kg⁻¹) than in muscle (<3 mg Cu·Kg⁻¹ and 26 mg Zn·Kg⁻¹), while Pb and Cr were not detected. These results suggest that Cu and Zn are the metals of major concern in the lagoon. Mullet detritivorous feeding habits, bioaccumulation pattern and the high sediment metals concentrations relative to the water suggest that sediments can be the most important source of contamination in this ecosystem. The positive relationship found between Cu in liver and fish length demonstrates that time of exposure is a crucial factor in bioaccumulation. Condition indices (K and HSI) in mullets from the lagoon were higher compared to mullets from sea, suggesting abnormal condition in the lagoon population. We conclude that metals chronic exposure in the lagoon can impose considerable fish stress. The results also show that the lagoon is an area of environmental concern.     

Monitoring urban growth and detecting land-cover changes on the Istanbul metropolitan area

Istanbul is the most populated city of Turkey with a population of around 10.58 M (2000) living on around 5,750 km². In 1980, the population was only 4.7 M and then it has been more than doubled in only two decades. The population has been increasing as a result of mass immigration. An urbanization process continues and it causes serious increases in urban areas while decreasing the amount of green areas. This rapid, uncontrolled, and illegal urbanization accompanied by insufficient infrastructure has caused degradation of forest and barren lands in the metropolitan area, especially through the last two decades. The watershed basins inside the metropolitan area and the transportation network have accelerated the land-cover changes, which have negative impacts on water quality of the basins. Monitoring urban growth and land cover change will enable better management of this complex urban area by the Greater Istanbul Metropolitan Municipality (GIMM). A temporal assessment of land-cover changes of Istanbul has been documented in this study. The study mainly focuses on the acquisition and analysis of Landsat TM and Landsat GeoCover LC satellite images reflecting the significant land-cover changes between the years of 1990 and 2005. Raster data were converted to vector data and used in Geographic Information Systems (GIS). A database was created for Istanbul metropolitan area to plan, manage, and utilize statistical attribute data covering population, water, forest, industry, and topographic position. Consequently an overlay analysis was carried out and land use/cover changes through years have been detected for the case study area. The capability of Landsat images in determining the alterations in the macro form of the city are also discussed.     

Modelling vegetation greenness responses to climate variability in a Mediterranean terrestrial ecosystem

Accurate knowledge of the quality and environmental impact of the highway runoff in Pear River Delta, South China is required to assess this important non-point pollution source. This paper presents the quality characterization and environmental impact assessment of rainfall runoff from highways in urban and rural area of Guangzhou, the largest city of Pear River Delta over 1 year’s investigation. Multiple regression and Pearson correlation analysis were used to determine influence of the rainfall characteristics on water quality and correlations among the constituents in highway runoff. The results and analysis indicates that the runoff water is nearly neutral with low biodegradability. Oil and grease (O&G), suspended solids (SS) and heavy metals are the dominant pollutants in contrast to the low level of nutrient constituents in runoff. Quality of highway runoff at rural site is better than that of at urban site for most constituents. Depth and antecedent dry period are the main rainfall factors influencing quality of highway runoff. The correlation patterns among constituents in highway runoff at urban site are consistent with their dominant phases in water. Strong correlations (r ≥ 0.80) are found among chemical oxygen demand (COD), total phosphorus, Cu and Zn as well as conductivity, nitrate nitrogen and total nitrogen. O&G, COD, SS and Pb in highway runoff at urban site substantially exceed their concentrations in receiving water of Pear River. The soil directly discharged by highway runoff at rural site has contaminated seriously by heavy metals in surface layer accompanying with pH conversion from original acidic to alkaline at present.     

5—(4—磺酸基苯偶氮)8—(2,4—二硝基苯氨基)喹啉测定食品中铜的研究应用

在弱碱性介质中 ,5— (4—磺酸基苯偶氮 ) 8— (2 ,4—二硝基苯氨基 )喹啉 (SPDNPAQ)与铜反应生成 2∶ 1紫红色络合物 ,体系 λmax=56 0 nm,ε=1.2 3× 10 5L· mol-1· cm-1。铜含量在 0～ 0 .4 mg/ L内符合比耳定律 ,方法用于一些生物样品和水样中铜的测定。     

水和废水中黄磷的测定

试验了黄磷在紫外光区的吸收光谱,建立了紫外分光光度法测定水和废水中黄磷的方法.该方法不需酸化、氧化,可在萃取后直接比色测定.当样品中含有石油类干扰物质时,可用含氧化剂的酸性水溶液对萃取液进行反萃取即能将其排除.该方法灵敏,具有测定范围宽、准确度高、精密度好、操作简便等特点.     

Impact of changed trophic status on the zooplankton composition in six water bodies of Dharwad district, Karnataka state (South India)

Morgan Island, located within the ACE Basin National Estuarine Research Reserve in South Carolina, is home to the only free-ranging colony of rhesus monkeys (Macca mulatta) in the continental United States. The purpose of this study was to assess environmental impacts of the monkey colony on water quality in adjacent tidal creeks and on island vegetation. Three tidal creeks were sampled: Morgan Creek, adjacent to the monkey colony; Back Creek, on Morgan Island not adjacent to the colony; and Rock Creek, on a nearby island unoccupied by monkeys. Temperature, salinity, pH, dissolved oxygen, nutrients and fecal coliform bacteria were measured six times at three sites in each of these creeks, and vegetation change analysis was conducted in a geographic information system using satellite imagery. Results showed elevated fecal coliform concentrations in the Morgan Creek site immediately adjacent to the colony, though no samples exceeded the standard set for recreational water use. Ribotyping reconnaissance matched four Escherichia coli isolates from Morgan and Back Creeks to the monkeys, identifying the colony as one source of fecal coliform bacteria, though relative source loadings could not be quantified. Significant differences were not observed between ammonia or orthophosphate levels in Morgan Creek relative to the other creeks tested; and vegetation change analysis showed a 35% increase in canopy cover between 1979 and 1999. Overall, these results suggest that the rhesus colony’s environmental impacts are localized and minimal. Results from this study provide baseline data on Morgan Island and may be useful in management decisions regarding the future of the monkey colony.     

Determination of toxic elements in waters and sediments from River Subin in the Ashanti Region of Ghana

Waters and sediments of Subin River, which flows through the industrial and commercial areas of Kumasi in the Ashanti region of Ghana, were geochemically investigated to ascertain heavy metal pollution levels due to anthropogenic activities. The study shows preoccupying pollution levels that constitute a threat to public and ecological systems. The waters of Subin River are neutral to slightly basic, inferred from pH values of 6.89–7.65). Electric conductivity (EC) of the waters ranges from 822 to 1,821 μs/cm and the range of total dissolved solids (TDS) is from 409 to 913 mg/l. Toxic elements contents of sediments and waters from 10 sites along the river were analysed by instrumental neutron activation analysis (INAA), and Al, As, Cd, Cr, Cu and Zn were determined. The concentrations of Al, As, Cd, Cr, Cu and Zn in the waters range between 4.02–15.18, 0.007–0.16, 0.002–0.05, 0.001–0.019, 1.32–7.04 and 4.28–10.2 mg/l, respectively. The contamination factors (CF) computed for the elements indicate that with the exception of sampling site S10, the sediments are polluted with Cd. Chromium contamination in the sediments is observed at S6 and S7, where the CF values were 1.39 and 1.52, respectively. The pollution load indices (PLI) were low (<1) and ranged from 0.14 to 0.75, suggesting that the overall sediment column of the river is not polluted.     

Wet weather impact on trihalomethane formation potential in tributaries to drinking water reservoirs

During rain storm events, land surface runoff and resuspension of bottom sediments cause an increase in Trihalomethane (THM) precursors in rivers. These precursors, when chlorinated at water treatment facilities will lead to the formation of THMs and hence impact drinking water resources. In order to evaluate the wet weather impact on the potential formation of THMs, river samples were collected before, during and after three rain storms ranging from 15.2 to 24.9 mm precipitation. The samples were tested for THM formation potential and other indicators including UV254 absorbance, turbidity and volatile suspended solid (VSS). Average levels of THMs increased from 61 μg/l during dry weather to 131 μg/l during wet weather, and then went back to 81 μg/l after rain ended. Wet weather values of THM are well above the maximum contaminant level (MCL) 80 μg/l, set by EPA for drinking water. THM indicators also exhibited similar trends. Average levels increased from 0.6 to 1.8 abs; 2.6 to 6 ntu; and 7.5 to 15 mg/l respectively for UV254, turbidity and VSS. A positive correlation was observed between THM formation and THM indicators. The t-test of significance (p-value) was less than 0.05 for all indicators, and R values ranged from 0.85 to 0.92 between THMs and the indicators, and 0.72 to 0.9 among indicators themselves.