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331.
The long-term water quality monitoring program implemented by the Massachusetts Water Resources Authority in 1992 is extensive
and has provide substantial understanding of the seasonality of the waters in both Boston Harbor and Massachusetts Bay and
the response to improvements in effluent quality and offshore transfer of the effluent in September 2000. The monitoring program
was designed with limited knowledge of spatial and temporal variability and long-term trends within the system. This led to
an extensive spatial and temporal sampling program. The data through 2003 showed high correlation within physical parameters
measured (e.g., salinity, dissolved oxygen) and in biological measures such as chlorophyll fluorescence. To address the potential
sampling redundancies in the measurement program, an assessment of the impact of reduced levels of monitoring on the ability
to make water quality decisions was completed. The optimization was conducted by applying statistical models that took into
account whether there was evidence of a seasonal pattern in the data. The optimization used model survey average readings
to identify temporal fixed effects, model survey-average-corrected individual station readings to identify spatial fixed effects,
corrected the individual station readings for temporal and spatial fixed effects and derived a correlation model for the corrected
data, and applied the correlation model to characterize the correlation of annual average readings from reduced monitoring
programs with true parameter levels. Reductions in the number of sampling stations were found less detrimental to the quality
of the data for annual decision-making than reductions in the number of surveys per year, although there is less of a difference
in this regard for dissolved oxygen than there is for chlorophyll. The analysis led to recommendations for a substantially
lower monitoring effort with minimal loss of information. The recommendation supported an annual budget savings of approximately
$183,000. Most of the savings was from fewer surveys as approximately $21,000 came from the reduction in the number of stations
monitored from 21 to 7 and associated laboratory analytical costs. 相似文献
332.
Majagi SH Vijaykumar K Vasanthkaumar B 《Environmental monitoring and assessment》2008,138(1-3):273-279
In this study, some heavy metals concentrations (Zn, Pb, Fe, Mn, Cu, Ni) and other physico-chemical parameters were studied
during October 2001 to September 2003 in Karanja reservoir, Bidar district. Water quality parameters were collected monthly
basis whereas heavy metals were analyzed by Atomic Adsorption Spectrometer (AAS). Heavy metals have shown within the permissible
limits, except Fe and Ni were recorded higher values in southwest monsoon, where as Mn has showed higher concentration in
northeast monsoon in and summer. All other physico-chemical parameters are with in the permissible limit. Water is moderately
hard and reservoir is productive. 相似文献
333.
May TW Fairchild JF Petty JD Walther MJ Lucero J Delvaux M Manring J Armbruster M 《Environmental monitoring and assessment》2008,137(1-3):213-232
The Solomon River Basin is located in north-central Kansas in an area underlain by marine geologic shales. Selenium is an
indigenous constituent of these shales and is readily leached into the surrounding groundwater. Portions of the Basin are
irrigated primarily through the pumping of selenium-contaminated groundwater from wells onto fields in agricultural production.
Water, sediment, macroinvertebrates, and fish were collected from various sites in the Basin in 1998 and analyzed for selenium.
Selenium concentrations were analyzed spatially and temporally and compared to reported selenium toxic effect thresholds for
specific ecosystem components: water, sediments, food-chain organisms, and wholebody fish. A selenium aquatic hazard assessment
for the Basin was determined based on protocol established by Lemly. Throughout the Basin, water, macroinvertebrate, and whole
fish samples exceeded levels suspected of causing reproductive impairment in fish. Population structures of several fish species
implied that successful reproduction was occurring; however, the influence of immigration of fish from low-selenium habitats
could not be discounted. Site-specific fish reproduction studies are needed to determine the true impact of selenium on fishery
resources in the Basin.
The U.S. Government’s right to retain a non-exclusive, royalty free license in and to any copyright is acknowledged. 相似文献
334.
大体积进样-气相色谱法测定水中多种痕量有机磷农药 总被引:1,自引:0,他引:1
建立了大体积进样气相色谱-火焰光度法检测水中多种痕量有机磷农药的方法.重点研究了程序升温汽化(PTV)进样条件的选择,通过对分流排空量、吹扫时间、PIV起始温度等PTV参数的选择,优化了测试条件,提高了检测灵敏度.水中9种有机磷农药的线性良好,10ml水样中三乙基偶磷硫酯的检出限为0.01μg/L,硫磷嗪、致螟磷、甲拌磷、乐果、乙拌磷、甲基对硫磷、对硫磷和氨磺磷的检出限可达0.001μg/L.水中添加多种有机磷农药准确度精密度试验,平均回收率为85.8%~108%,相对标准差在3.3%~11.4%之间.与常规方法相比,该方法前处理简单快速、分析成本低.灵敏度、准确度和精密度均符合地表水检测质量的要求,适用于水环境中多种农药残留的快速检测. 相似文献
335.
336.
固城湖春季水环境因子空间变异及其原因探讨 总被引:4,自引:1,他引:3
在现场采样数据的基础上,运用Arc GIS的地统计学组件分析了固城湖春季水环境因子空间变异规律,并从污粢源分布、水生植物密度差异方面探讨了水环境因子空间变异产生的原因.结果表明:(1)变异函教选择球状模型和高斯模型拟合水环境因子的变差曲线,从预测误差判断,拟合效果很好,因此,固城湖水环境因子的空同分布图比较真实地反映了固城湖水环境现状;(2)固城湖TN、NH4+-N基本上呈现从南到北逐渐升高的趋势,TN、NH4+-N、SD的空间变异主要是由人类活动引起,水革对TN、NH4+-N的吸收作用、SD的改善作用不明显;(3)太湖区TP基本上呈现从中西部向东逐渐升高的趋势,与大湖区水草密度的变化趋势相反;水革密度越大(大湖中南部)pH越高,而水草密度越小(航道、湖东部)pH越小;(4)中南部湖区围罔的全部拆除、港口河上游生活污水减少,都使得中南部湖区水质得到改善. 相似文献
337.
338.
339.
浊点萃取分离富集荧光光度法测定水中α - 萘酚 总被引:2,自引:1,他引:1
基于非离子表面活性剂Triton X-114,采用浊点萃取分离富集荧光光度法测定水中α-萘酚,优化了影响浊点萃取的各种因素,包括样品酸度、表面活性剂体积分数、氢氧化钠溶液浓度、平衡温度和时间等,讨论了常见无机离子和可能共存的有机物的干扰。方法在0.010 mg/L~0.400 mg/L范围内线性良好,检出限为3.0μg/L,标准溶液测定的RSD为4.8%,水样加标回收率为94.3%~103%。 相似文献
340.
水质生物毒性在线监测技术研究进展 总被引:5,自引:1,他引:4
从生物分子、细胞、个体、种群和群落水平,系统介绍了国内外研发的水质毒性在线监测技术,归纳分析了各种技术的特点及应用,并提出了其发展前景与趋势。 相似文献