Dynamic pressure induced by a methane–air explosion in a coal mine

The hazardous effect of dynamic pressure and strong gas flows induced by a methane–air mixture explosion in underground coal mines is studied. The dynamic pressure effect of a methane–air explosion was analyzed by numerical simulation, in a duct and tunnel. Compared to the overpressure generated by an explosion that can act on a body, the dynamic pressure caused by the high-speed flow of the gaseous combustion products can cause serious damage as well. At the structural opening of a coal mine, the destruction caused by the dynamic pressure induced by a methane–air explosion is more serious than the overpressure. For a tube or tunnel partially filled by a methane–air mixture, the dynamic pressure is lower than the overpressure in the region occupied by the flammable mixture. Beyond the premixed region, the dynamic pressure is of the same order of magnitude as the overpressure.     

火焰原子吸收法测定苹果中波尔多液的农药残留

通过原子吸收法测定苹果果皮、果肉上波尔多液的农药残留铜的含量,结果表明:喷洒了波尔多液的苹果果皮上铜含量明显大于果肉,在果皮上有一定的农药残留;而未喷洒波尔多液的苹果果皮和果肉中铜的含量的差异很小。     

Minimum ignition energy of LDPE dust/ethylene hybrid mixture

An experimental device for evaluating the minimum ignition energy (MIE) of LDPE dust/ethylene hybrid mixture was built with the innovative mixing mode. The MIE of the hybrid mixture that contained ethylene below its lower explosive limit (LEL) was studied. The result indicated that adding a small amount of ethylene significantly reduced the MIE of the original dust cloud. All the MIEs with five different particle sizes were found to show similar trends of exponential attenuation with the increase of ethylene concentration; such attenuating effect grew as the dust particle size rose. When ethylene concentration increased and approached to its LEL, the reaction mechanism dominated by combustible dust turned into one dominated by combustible gas. The MIE decreased first and then increased with the dust mass and increased with the dust particle size. A multifactor mathematical correlation model of the MIE with the dust particle size and ethylene concentration was developed.     

烟台夹河河口海水混合过程的地球化学特征研究

海(咸)水混入是河口河水重要的地质过程,深刻地影响河水地球化学过程。本文系统采集夹河河口水样,分析海淡水混合过程的地球化学特征。结果表明,远离河口段(J10~J14)为淡水性质,主要受水-岩作用及人类活动等影响;近河口段(J1~J8)海水混入严重,F~-、Cl~-、Br~-、SO~(2-)_4、Na~+、K~+、Mg~(2+)、Ca~(2+)、盐度等明显较高,主要受海水混入影响。近河口段存在Na-Ca离子交换过程,约占Na~+总量的0.9%~1.5%,离子交换量随海水混入比例增加而增加,Na~+离子交换量与K~+,Ca~(2+)、Mg~(2+)、Br~-、F~-、SO~(2-)_4离子交换量相关,且河水离子含量与盐度回归系数略低于与盐度、Na~+交换量回归系数,表明河口段河水离子交换影响河水地球化学特征。     

混合二元酸中戊二酸的分离提纯

采用溶剂溶解和气泡结晶的方法从混合二元酸中分离、提纯戊二酸。考察了溶解温度、溶剂用量和结晶过程对戊二酸纯度和收率的影响 ,并确定了分离与提纯的最佳工艺条件。分离过程 :溶解温度 5 5℃、溶剂与二元酸用量比 30mL∶10g ;提纯过程 :结晶气速 5× 10 -6～ 8× 10 -6m3 /s、降温速率 1/ 3℃ /min、降温终点 2 0℃、结晶保温时间 2 0min、升温速率 1/ 2℃ /min、发汗终温 6 5℃、发汗保留时间 10min。在最佳工艺条件下分离、提纯得到的戊二酸纯度为 99 36 % ,戊二酸的回收率为 70 16 %。     

Biological removal of air loaded with a hydrogen sulfide and ammonia mixture

The nuisance impact of air pollutant emissions from wastewater pumping stations is a major issue of concern to China. Hydrogen sulfide and ammonia are commonly the primary odor and are important targets for removal. An alternative control technology, biofiltration, was studied. The aim of this study is to investigate the potential of unit systems packed with compost in terms of ammonia and hydrogen sulfide emissions treatment, and to establish optimal operating conditions for a full-scale conceptual design. The laboratory scale biofilter packed with compost was continuously supplied with hydrogen sulfide and ammonia gas mixtures. A volumetric load of less than 150 gH2S/(m^3.d) and 230 gNH3/(m^3.d) was applied for about fifteen weeks. Hydrogen sulfide and ammonia elimination occurred in the biofilter simultaneously. The removal efficiency, removal capacity and removal kinetics in the biofilter were studied. The hydrogen sulfide removal efficiency reached was very high above 99%, and ammonia removal efficiency was about 80%. Hydrogen sulfide was oxidized into sulphate. The ammonia oxidation products were nitrite and nitrate. Ammonia in the biofilter was mainly removed by adsorption onto the carrier material and by absorption into the water fraction of the carrier material. High percentages of hydrogen sulfide or ammonia were oxidized in the first section of the column. Through kinetics analysis, the presence of ammonia did not hinder the hydrogen sulfide removal. According to the relationship between pressure drop and gas velocity for the biofilter and Reynolds number, non-Darcy flow can be assumed to represent the flow in the medium.     

基于PBPK模型的大鼠体内镉分布的比较:联合暴露及单独暴露

环境中同时存在着多种重金属元素,联合暴露与单独暴露时,重金属在体内的蓄积分布情况也可能有所差异。为探究重金属元素(汞、铬、砷、铅)对镉(Cd)在体内分布的影响,建立了大鼠在Cd暴露下的药代动力学(PBPK)模型,并进行了包括Cd在内5种重金属的联合毒性实验,比较了Cd单独给药与重金属混合物给药2种方式下大鼠肝脏、肾脏中的Cd浓度水平。结果表明,联合暴露高(Hg Cl23.67 mg·kg~(-1),NaAsO_2 3.67 mg·kg~(-1),CdCl_2 10.55 mg·kg~(-1),K_2Cr_2O_7 6.40 mg·kg~(-1),Pb(OOCCH_3)_2·3H_2O 133.33 mg·kg~(-1))、中(HgCl_20.367 mg·kg~(-1),NaAsO_2 0.367 mg·kg~(-1),CdCl_2 1.055 mg·kg~(-1),K2Cr2O70.640 mg·kg~(-1),Pb(OOCCH_3)_2·3H_2O 13.333 mg·kg~(-1))、低(HgCl_2 0.0367 mg·kg~(-1),Na As O20.0367 mg·kg~(-1),Cd Cl20.1055 mg·kg~(-1),K_2Cr_2O_7 0.0640 mg·kg~(-1),Pb(OOCCH3)2·3H2O 1.3333 mg·kg~(-1))剂量组大鼠肝脏中Cd浓度分别为13.37、0.78和0.06μg·g~(-1);肾脏中Cd浓度分别为14.41、1.64和0.15μg·g~(-1)。与对照组相比,暴露组中Cd浓度有显著升高,且不同剂量组之间均有显著性差异。同剂量Cd单独暴露的PBPK模拟结果显示,肝脏及肾脏中的Cd浓度水平落在联合毒性实验结果的浓度范围内,初步推断其他4种重金属的联合暴露并没有影响Cd在大鼠肾脏和肝脏中的浓度分布。     

基于PLIF的混合气温度和浓度测量及其应用

缸内混合气温度和浓度分布,对发动机稳定运行,保障行车安全、避免发生路上人身伤亡或财物损失有重要影响。为了测量发动机缸内混合气的温度和浓度分布,建立了利用单波长激光诱导双示踪剂产生双荧光的测试系统,并拍摄了不同混合气温度、压力和浓度下的荧光图像,获得了不同示踪剂的荧光强度及其比值随温度、压力和浓度的变化关系,并将标定结果用于光学发动机缸内混合气的温度和浓度测量。结果表明,荧光强度及荧光比值均受到环境的压力、温度和混合气浓度的影响。利用PLIF方法得到的片光源穿过的缸内水平截面内的平均温度与用气缸压力计算的同一曲轴转角下的缸内平均温度变化趋势相同,两者之间的差值随着活塞上行而逐步减小。     

Limiting explosible concentration of hydrogen–oxygen–helium mixtures related to the practical operational case

This paper presents data on the limiting (minimum) concentrations of hydrogen in oxygen, in the presence of added helium, at elevated temperature and pressure related to the practical operational case. A 5 L explosion vessel, an ignition sub-system and a transient pressure measurement sub-system were used. Through a series of experiments carried out using this system, the limiting concentrations of hydrogen in oxygen and helium at different initial pressures and temperatures for the practical operational case were studied, and the influence of ignition energy and initial temperature on the limiting concentration of hydrogen in oxygen and helium was analyzed and discussed. The variation of ignition energy within the studied range is found to have a significant effect on the limiting concentration of hydrogen in oxygen and helium at lower initial temperature. However, when the ignition energy is higher than 32 mJ, the limiting hydrogen concentration remains almost changeless as the initial temperature increases from 21 °C to 90 °C. The limiting explosible concentration of hydrogen–oxygen–helium mixture decreases as the ignition energy increases when the initial temperature is lower. When the initial temperature is higher, the ignition energy has little effect on the limiting hydrogen concentration of hydrogen–oxygen–helium mixtures. When the initial temperature reaches 90 °C, the limiting hydrogen concentration remains almost changeless with an increase in ignition energy. The limiting explosible concentration of hydrogen in the mixtures, at the initial temperature of 21 °C and the ignition energy of 0.5 mJ, is 8.5% and that of oxygen is 11.25%.     

太湖水体中5种有机磷农药混合物生态风险评价

有机磷农药是一类广泛分布于我国水环境中的污染物,即使在水体中的污染水平处于规定“安全标准”之下,其联合暴露产生的风险仍有可能威胁水生生态安全。采用基于浓度加和模型与生物敏感度分布曲线的混合物风险商法,评价了太湖水体中敌敌畏、对硫磷、甲基对硫磷、马拉硫磷和乐果5种有机磷农药混合物产生的生态风险。结果表明：2003～2004年期间3个不同时期太湖水体中5种有机磷农药的混合物生态风险商(RQ_m )均大于1,有机磷农药混合物在2003～2004年期间对太湖水生生物构成了一定威胁。