辛硫磷降解菌X-1的分离鉴定及降解性状的初步研究

通过富集培养从南京周围土壤中分离到-株辛硫磷降解菌X-1，X-1能以辛硫磷为唯一碳源生长，初步鉴定为邻单胞菌属（Plesiomonas sp.）X-1有广泛的碳、氮源利用谱，在25-30℃长势较好，最适生长pH是7.0,X-1能在24h内，使辛硫磷降解96%，质粒检测发现有两条大的质粒条带。     

热成像测量技术在锅炉检验中的应用探讨

热成像技术是当前应用于锅炉设备故障检验的一种检测技术,在设备故障检测过程中发挥着重要作用,在实践中显示利用红外线进行热成像检测,能够更好的应用于锅炉本身状态的检测,对其各个方面展开详细的检测,能够更好的控制其运行情况,同时热成像技术还可以对锅炉运行的安全环境和能源方面达到有效的保障,因此在实践中发挥着非常重要的作用。在实际应用于过程中,这种技术通常做出的是早期判断,因此为了提高锅炉运行的安全率,必须要进行数据测量和收集,从而更好的应用于锅炉检验工作过程中。     

Photocatalytic degradation of Rhodamine B bymicrowave-assisted hydrothermal synthesized N-doped titanate nanotubes

Microwave-induced nitrogen-doped titanate nanotubes（NTNTs） were characterized by transmission electron microscopy（TEM）, X-ray diffraction（XRD）, X-ray photoelectron spectroscopy（XPS）, Fourier transform infrared spectroscopy（FT-IR）, Zeta potential analysis,specific surface area（SBET）, and UV-Visible spectroscopy. TEM results indicate that NTNTs retain a tubular structure with a crystalline multiwall and have a length of several hundred nanometers after nitrogen doping. XRD findings demonstrate that the crystalline structure of NTNTs was dominated by anatase, which is favored for photocatalytic application. The Ti-O-N linkage observed in the XPS N 1s spectrum is mainly responsible for narrowing the band gap and eventually enhancing the visible light photoactivity. FT-IR results demonstrated the existence of H3O＋, which could be excited by photo-generated holes to form hydroxyl radicals and degrade environmental pollutants. After sintering at 350°C, the UV-Vis absorbance edges of NTNTs significantly shift to the visible-light region, which indicates N atom doping into the nanotubes. Photocatalytic degradation of Rhodamine B（RhB） via NTNTs show good efficiency, with pseudo first-order kinetic model rate constants of 3.7 × 10-3, 2.4 × 10-3and 8.0 × 10-4sec-1at pH 3, 7, and 11, respectively.     

Sulfur evolution in chemical looping combustion of coal with MnFe2O4 oxygen carrier

Chemical looping combustion （CLC） of coal has gained increasing attention as a novel combustion technology for its advantages in CO2 capture. Sulfur evolution from coal causes great harm from either the CLC operational or environmental perspective. In this research, a combined MnFe2O4 oxygen carrier （OC） was synthesized and its reaction with a typical Chinese high sulfur coal, Liuzhi （LZ） bituminous coal, was performed in a thermogravimetric analyzer （TGA）-Fourier transform infrared （FT-IR） spectrometer. Evolution of sulfur species during reaction of LZ coal with MnFeaO40C was systematically investigated through experimental means combined with thermodynamic simulation. TGA-FTIR analysis of the LZ reaction with MnFe2O4 indicated MnFe2O4 exhibited the desired superior reactivity compared to the single reference oxides Mn304 or Fe203, and SO2 produced was mainly related to oxidization of H2S by MnFe2O4. Experimental analysis of the LZ coal reaction with MnFe2O4, including X-ray diffraction and X-ray photoelectron spectroscopy analysis, verified that the main reduced counterparts of MnFe2O4 were Fe304 and MnO, in good agreement with the related thermodynamic simulation. The obtained MnO was beneficial to stabilize the reduced MnFe2O4 and avoid serious sintering, although the oxygen in MnO was not fully utilized. Meanwhile, most sulfur present in LZ coal was converted to solid MnS during LZ reaction with MnFe2O4, which was further oxidized to MnSO4. Finally, the formation of both MnS and such manganese silicates as Mn2SiO4 and MnSiO3 should be addressed to ensure the full regeneration of the reduced MnFe2O4.     

垂序商陆叶细胞壁结合锰机制研究

垂序商陆是一种典型的锰超积累植物,细胞壁在其累积解毒锰的过程中起了一定的作用.通过细胞壁吸附实验,研究不同p H和不同锰浓度对细胞壁吸附锰的影响,并采用傅立叶红外光谱及同步辐射X-射线吸收光谱技术探讨了其吸附机制.结果表明,垂序商陆叶细胞壁吸附锰的最适p H值为5~6;其吸附行为可用Langmuir模型较好地描述(R2=0.978 5),并计算得其最大吸附量为62.50μmol·g-1.细胞壁上的羟基(—OH)和羰基(—CO)是结合锰的主要位点;锰周围第一配层为氧原子,其配位数为6.3,Mn—O键长为0.216 nm,细胞壁与锰主要以内配层模式相结合.     

Complete catalytic oxidation of o-xylene over CeO2 nanocubes

The activities of CeO2 nanocubes calcined at di erent temperatures were tested for catalytic oxidation of o-xylene. Using CeO2 nanocubes as catalysts, complete catalytic oxidation of o-xylene was achieved below 210°C. The CeO2 nanomaterials were characterized by means of BET, X-ray di raction (XRD), transmission electron microscopy (TEM), and high-resolution transmission electron microscopy (HRTEM). From the TEM images, all CeO2 nanocubes displayed cubic morphology irrespective of calcination temperature. The HRTEM images revealed that these nanocubes were enclosed by reactive f001g planes, which may contribute to the intrinsically catalytic property of o-xylene oxidation. The higher activity of CeO2 nanocubes calcined at 550°C than those calcined at above 550°C was attributed to their smaller crystallite size and larger surface area. The influences of reaction conditions were also studied, which found that a higher reaction temperature was necessary for complete catalytic oxidation of o-xylene at higher weight hourly space velocity (WHSV) and o-xylene concentration.     

环境因素对X80管线钢在NS4溶液中腐蚀性的影响

通过动电位极化方法研究了温度、溶解氧、pH值等环境因素对X80管线钢在NS4溶液中腐蚀性的影响,并将三者对X80钢腐蚀速率的影响程度进行了灰关联分析.动电位极化曲线试验结果表明:随着NS4溶液中溶解氧含量的减少,X80钢的腐蚀电流密度(icorr)降低,耐腐蚀性增加;随着溶液温度升高和溶液pH值降低,X80钢的腐蚀电流密度增加,耐腐蚀性下降;灰关联分析结果表明:根据关联度的大小,环境因素对X80钢腐蚀速率影响大小的顺序为溶解氧、溶液pH值、温度.     

用逐次逼近法计算γ射线装置屏蔽层厚度

目前半价层厚度是比较常见的计算射线装置屏蔽层厚度的方法,但该方法存在着精度低的缺点,在精密度要求不高的工程上可以应用.但在产品设计和装置的审批过程中,上述方法难以满足需要,因此需采用逐次逼近法反复运算,最后达到工程要求的精度.     

基于正交法X形密封圈力学性能研究

为研究X形（星形）密封圈在静、动密封工作时的力学性能,通过拟合实验数据得到橡胶Mooney-Rivilin模型参数,利用ABAQUS软件建立X形密封圈仿真模型,采用正交试验方法研究了预压缩量、介质压力、硬度、温度对密封圈静密封的影响,以及速度、摩擦系数对其动密封力学性能的影响。结果表明:密封圈在有介质压力时的应力分布更不均匀;在静密封过程中,影响密封圈最大Von Mises应力的因素主次顺序为:介质压力>预压缩量>温度>硬度,影响主密封面上最大接触应力的因素主次顺序为:介质压力>硬度>预压缩量>温度;在动密封过程中,内行程速度、摩擦系数对密封圈应力的影响更加显著。     

涡流热成像动态检测模式的缺陷信号重构方法研究

在涡流热成像检测中,缺陷信号重构可以有效评定结构的安全性和可靠性,及时预防生产中安全事故的发生,目前大多数信号重构方法都不适用于动态模式的涡流热成像检测。为了对动态模式涡流热成像检测的信号进行重构,提出了1种基于区域扫描的方法,选定区域大小及划分准则,在每帧图像相同位置划分区域,对各个区域内的温度数据进行相应的运算处理并提取结果,以此作为每个区域的重构温度,进而重构出包含所有缺陷温度信息的热像图。结果表明:该方法可以对动态模式下的涡流热成像温度信号进行重构,并能在一定程度上消除噪声,有利于后续的图像处理。