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61.
鄂尔多斯盆地高含水输油管道内壁腐蚀减薄现象普遍,腐蚀穿孔频次逐年上升,管道安全防护管理成为难题。为了识别输油管道内壁腐蚀减薄原因,作者在分析含水率、地层水水型、溶解氧对管道内腐蚀影响的基础上选择特征试验管段,基于X射线光电子能谱技术开展管道内壁厚度变化、金相组织、腐蚀产物特性、边缘腐蚀状态研究。结果表明:高含水输油管道内壁腐蚀减薄类型为Cl+O2+H2O环境下的垢下腐蚀,以溶解氧(O2)腐蚀为主,氯离子(Cl-)腐蚀为辅;内壁腐蚀减薄原因为原油含水率过高、水中氯离子含量过高、水中含有溶解氧和介质流速偏低。 相似文献
62.
G. Rangel-Porras J.B. García-Magno M.P. González-Muñoz J. A. Reyes-Aguilera 《Chemistry and Ecology》2014,30(4):350-363
Anthropogenic activities induce changes in a series of soil features. For example, continuous contact between soil and municipal solid waste leachates can encourage weathering processes as well as other mineral transformation reactions; consequently, the soil loses the function of environmental protection. Pollution-induced changes in the surface properties and morphology of soils have been rarely studied. In this work, the surface characteristics of calcareous soil located at a municipal solid waste disposal site in central Mexico were studied. Soil characterisation was carried out to determine the mesoporous size, particle surface area and crystallinity of collected samples. Comparison of these characteristics was made between soil in continuous contact with leachate flow and soil not in contact with leachate. The characterisation was carried out using X-ray diffraction, thermal analysis and nitrogen adsorption at 77 K. The presence of Pb, Cd, Zn, Ni and Cr was examined in both soils. Leachates in contact with this soil showed characteristics typical of liquid produced by the decomposition of municipal solid waste (pH, dissolved oxygen, redox potential and alkalinity). 相似文献
63.
64.
介绍了声屏障顶部结构衍射的评价标准和计算方法。给出了具有T型、橄榄型、弧型、L型等4种不同顶端式样声屏障的衍射声场有限元分析,以及使用脉冲方法得到的各种顶端式样在隔声屏障铺设吸声材料和不铺设吸声材料两种情况下插入损失的计算结果。 相似文献
65.
由于目前对炭基脱硫剂的活性吸附位缺乏一致认识,采用傅立叶红外光谱和X射线衍射技术研究了活性焦脱除烟气中SO2的活性位。结果表明:SO2在非载铜活性焦上的活性吸附位有C-O官能团、苯基与不饱和基团。而载铜活性焦除此3种活性位外,铜的存在可能促进C=O发生还原转化为C-O而增强其活性,并作为一种活性位参与脱硫反应形成硫酸铜。 相似文献
66.
Anne Straczek Dariusz Wegrzynek Ernesto Chinea-Cano Jacques Navez 《Journal of environmental radioactivity》2010,101(3):258-266
Accumulation and distribution of uranium in roots and shoots of four plants species differing in their cation exchange capacity of roots (CECR) was investigated. After exposure in hydroponics for seven days to 100 μmol U L−1, distribution of uranium in roots was investigated through chemical extraction of roots. Higher U concentrations were measured in roots of dicots which showed a higher CECR than monocot species. Chemical extractions indicated that uranium is mostly located in the apoplasm of roots of monocots but that it is predominantly located in the symplasm of roots of dicots. Translocation of U to shoot was not significantly affected by the CECR or distribution of U between symplasm and apoplasm. Distribution of uranium in roots was investigated through chemical extraction of roots for all species. Additionally, longitudinal and radial distribution of U in roots of maize and Indian mustard, respectively showing the lowest and the highest translocation, was studied following X-ray fluorescence (XRF) analysis of specific root sections. Chemical analysis and XRF analysis of roots of maize and Indian mustard clearly indicated a higher longitudinal and radial transport of uranium in roots of Indian mustard than in roots of maize, where uranium mostly accumulated in root tips. These results showed that even if CECR could partly explain U accumulation in roots, other mechanisms like radial and longitudinal transport are implied in the translocation of U to the shoot. 相似文献
67.
Lead toxicity, defense strategies and associated indicative biomarkers in Talinum triangulare grown hydroponically 总被引:2,自引:0,他引:2
Talinum species have been used to investigate a variety of environmental problems for e.g. determination of metal pollution index and total petroleum hydrocarbons in roadside soils, stabilization and reclamation of heavy metals (HMs) in dump sites, removal of HMs from storm water-runoff and green roof leachates. Species of Talinum are popular leaf vegetables having nutrient antinutrient properties. In this study, Talinum triangulare (Jacq.) Willd (Ceylon spinach) grown hydroponically were exposed to different concentrations of lead (Pb) (0, 0.25, 0.5, 0.75, 1.0 and 1.25 mM) to investigate the biomarkers of toxicity and tolerance mechanisms. Relative water content, cell death, photosynthetic pigments, sulphoquinovosyldiacylglycerol (SQDG), anthocyanins, α-tocopherol, malondialdehyde (MDA), reactive oxygen species (ROS) glutathione (GSH and GSSG) and elemental analysis have been investigated. The results showed that Pb in roots and shoots gradually increased as the function of Pb exposure; however Pb concentration in leaves was below detectable level. Chlorophylls and SQDG contents increased at 0.25 mM of Pb treatment in comparison to control at all treated durations, thereafter decreased. Levels of carotenoid, anthocyanins, α-tocopherol, and lipid peroxidation increased in Pb treated plants compared to control. Water content, cells death and elemental analysis suggested the damage of transport system interfering with nutrient transport causing cell death. The present study also explained that Pb imposed indirect oxidative stress in leaves is characterized by decreases in GSH/GSSG ratio with increased doses of Pb treatment. Lead-induced oxidative stress was alleviated by carotenoids, anthocyanins, α-tocopherol and glutathione suggesting that these defense responses as potential biomarkers for detecting Pb toxicity. 相似文献
68.
X射线荧光光谱分析空气滤膜颗粒物中多种元素 总被引:2,自引:0,他引:2
采用X射线荧光光谱分析空气滤膜采集悬浮颗粒物中的多种元素,样品不需要前处理,不使用试剂,测量1个样品中40余种元素约耗时1 h。重复测量10次NIST SRM 2783空气滤膜标准样品,多数元素的测量值与标准值基本一致,测量值的标准偏差较小;测量20个空气滤膜实际样品,并与ICP-MS法作比对,大多数元素两种方法测量结果的相对偏差较小,测量值基本一致。 相似文献
69.
研究以单元素标准膜为基础,结合NIST SRM 2783颗粒物滤膜标准样品,建立了波长色散-X射线荧光光谱法测定PM2.5中23种无机元素的测定方法,优化了测试条件,测量一个样品耗时约15 min,计算了各元素的方法检出限。对NIST SRM 2783滤膜标准品在一周内重复测定10次来计算方法的准确度与精密度,测定结果显示大多数元素的测量值在给出的参考值范围内,且测量标准偏差一般在10%以内。对比了石英与聚四氟乙烯材质(Teflon)滤膜的空白值,石英滤膜中Si、Fe、Na、Mg、Al、K、Ca等元素的背景值较高,Teflon滤膜的背景值较低,推荐选用Teflon滤膜作为PM2.5组分分析采样滤膜。分别用波长色散-X射线荧光光谱法及酸消解-ICP-MS法测定了样品膜中的元素组分,得到的测定结果基本一致。 相似文献
70.
对方法标准验证实验中测量数据进行合格性审核,对于后续方法精密度计算是一个重要环节。文献中识别离群值的Grubbs法、Dixon法等经典方法有时不能满足要求。探讨了用稳健统计法识别离群值的可行性。基于2套文献数据和XRF方法标准验证实验精密度测量数据,对Grubbs法、Dixon法、Mandel h检验法、质控指标法和稳健统计法(四分位法、迭代法、合格数据范围判定法)进行了比较。结果表明:稳健统计法可有效识别离群值。但四分位法存在过度"检出"现象。综合考虑多种方法识别结果有利于提高离群值判定结论的可靠性。对于个别难以判断的情形,可借助质控指标、技术要求以及数据是否剔除对实验室间标准偏差的影响进行取舍。 相似文献