Leaching experiments of rebuilt soil columns with two simulated acid rain solutions (pH 4.6–3.8) were conducted for two natural
soils and two artificial contaminated soils from Hunan, south-central China, to study effects of acid rain on competitive
releases of soil Cd, Cu, and Zn. Distilled water was used in comparison. The results showed that the total releases were Zn>Cu>Cd
for the natural soils and Cd>Zn≫Cu for the contaminated soils, which reflected sensitivity of these metals to acid rain. Leached
with different acid rain, about 26–76% of external Cd and 11–68% external Zn were released, but more than 99% of external
Cu was adsorbed by the soils, and therefore Cu had a different sorption and desorption pattern from Cd and Zn. Metal releases
were obviously correlated with releases of TOC in the leachates, which could be described as an exponential equation. Compared
with the natural soils, acid rain not only led to changes in total metal contents, but also in metal fraction distributions
in the contaminated soils. More acidified soils had a lower sorption capacity to metals, mostly related to soil properties
such as pH, organic matter, soil particles, adsorbed SO42−, exchangeable Al3+ and H+, and contents of Fe2O3 and Al2O3. 相似文献
This paper describes the results from a series of fire tests that were carried out to measure the effect of defects in thermal protection systems on fire engulfed propane pressure vessels.
In North America thermal protection is used to protect dangerous goods rail tank-cars from accidental fire impingement. They are designed so that a tank-car will not rupture for 100 min in a defined engulfing fire, or 30 min in a defined torching fire. One common system includes a 13 mm blanket of high-temperature ceramic fibre thermal insulation covered with a 3 mm steel jacket. Recent inspections have shown that some tanks have significant defects in these thermal protection systems. This work was done to establish what levels of defect are acceptable from a safety standpoint.
The tests were conducted using 1890 l (500 US gallon) ASME code propane pressure vessels (commonly called tanks in the propane industry). The defects tested covered 8% and 15% of the tank surface. The tanks were 25% engulfed in a fire that simulated a hydrocarbon pool fire with an effective blackbody temperature of 870 °C.
The fire testing showed that even relatively small defects can result in tank rupture if the defect area is engulfed in a severe fire, and the defect area is not wetted by liquid from the inside. A wall failure prediction technique based on uniaxial high-temperature stress rupture test data has been developed and agrees well with the observed failure times. 相似文献
Because they cause burns that are difficult to heal, acids are dangerous, and steps should be taken to ensure that the human skin does not come into contact with them. For this purpose safety gloves are generally used by workers who have to handle acids. Such gloves need to be tested to ensure that they are acid resistant. Standard EN 374 (European Committee for Standardization [CEN], 1993c) specifies a method of testing the permeation of liquid chemicals, on a molecular level, through glove material, but it may be difficult to ensure the fitness of the joints of a two-compartment cell, when gloves are lined with jersey. To deal with this a simple pH-meter method to test the permeation of acid and alkali solutions through safety gloves has been developed. The permeation of H2S04, HCI, HN03, and CH3COOH through gloves made from neoprene, nitrile, and PVC was tested. This method seems to be simple and economical. 相似文献
The study concerns the moderating role of two variables—hardiness and social support—in the relation between job stressors and well-being. It was checked if there is a connection between hardiness and social support, and if these variables are directly related to the level of well-being. It was also hypothesized that hardiness and social support buffer the negative influence of stressors on well-being. The fact that social support and well-being are multidimensional variables was taken into account.The cross-sectional study was conducted on a group of 200 women employed as office workers. The results showed that hardiness correlates with the indexes of emotional support as well as practical support coming from supervisors. The connection, however, was not strong. Hardiness and social support were directly connected with the level of well-being. Interaction of these two independent variables played a marginal role. As far as the buffering role of these variables was concerned, the results have shown that hardiness did not play a buffering role and social support did to a limited degree only.The results of the study proved that it is justifiable to treat social support and well-being as multidimensional variables. 相似文献
For wearers of protective clothing in radiation environments there are no quantitative guidelines available for the effect of a radiative heat load on heat exchange. Under the European Union funded project ThermProtect an analytical effort was defined to address the issue of radiative heat load while wearing protective clothing. As within the ThermProtect project much information has become available from thermal manikin experiments in thermal radiation environments, these sets of experimental data are used to verify the analytical approach. The analytical approach provided a good prediction of the heat loss in the manikin experiments, 95% of the variance was explained by the model. The model has not yet been validated at high radiative heat loads and neglects some physical properties of the radiation emissivity. Still, the analytical approach provides a pragmatic approach and may be useful for practical implementation in protective clothing standards for moderate thermal radiation environments. 相似文献
Child protection is an area of police work which has expanded in the last decade, leading to an increase in the number of police officers working in departments which specialise in investigating cases of child abuse. Police officers in this field may be at greater risk of experiencing secondary traumatic stress but there remains a paucity of research in this area of policing. Analogies can be drawn to existing research in policing and with social service workers involved in child protection. The paper finishes off with implications for police forces to ensure safe working environments and appropriate counselling for employees. 相似文献
The primary objective of this study was to investigate the relationship of work stress, consisting of role stressors and job insecurity, with safety compliance at work. A secondary objective was to test for the possible moderating effect of individual employees’ coping behaviour between experienced work stress and job insecurity, and their safety compliance. A cross-sectional survey design was used (n?=?771). An electronic survey, with a biographical questionnaire and scales on role conflict, role ambiguity, role overload, job insecurity, coping and safety compliance at work, was administered. The results indicated that specific aspects of work stress, notably role conflict, role ambiguity and quantitative job insecurity, and of coping, namely an avoidance style and changing the situation, were important in understanding safety compliance. A moderating effect of avoidance coping was also found. 相似文献
Purpose. The aim of this article was to check whether mindfulness-based stress reduction (MBSR) is an effective intervention in reducing work-related stress in the case of workers in a copper mine. Methods. Sixty six employees were randomized to the experimental group (32 participants) or to the control group (34 participants). Work-related stress was measured using the job content questionnaire (JCQ) and mental health was measured using the general health questionnaire (GHQ-28) Experimental manipulation was 40-h MBSR training. Results. Multivariate repeated-measures analysis of variance revealed a significant increase of JCQ decision latitude (F?=?17.36, p?<?0.001) and social support (supervisor F?=?9.00, p?<?0.004; coworker F?=?5.61, p?<?0.020), and a significant decrease in GHQ-28 anxiety (F?=?5.28, p?<?0.079) and depression (F?=?3.95, p?<?0.048) due to the intervention. Conclusions. The study confirms that MBSR can be effective in reducing stress resulting from the external risk (and/or imagined fear) of losing one’s health or life. The use of MBSR could be recommended in health and safety activities in difficult and dangerous work conditions, such as mining, to promote workers’ well-being. 相似文献