全文获取类型
收费全文 | 1123篇 |
免费 | 138篇 |
国内免费 | 863篇 |
专业分类
安全科学 | 99篇 |
废物处理 | 94篇 |
环保管理 | 119篇 |
综合类 | 1231篇 |
基础理论 | 267篇 |
污染及防治 | 236篇 |
评价与监测 | 61篇 |
社会与环境 | 17篇 |
出版年
2024年 | 9篇 |
2023年 | 27篇 |
2022年 | 49篇 |
2021年 | 80篇 |
2020年 | 59篇 |
2019年 | 81篇 |
2018年 | 76篇 |
2017年 | 82篇 |
2016年 | 74篇 |
2015年 | 95篇 |
2014年 | 97篇 |
2013年 | 148篇 |
2012年 | 131篇 |
2011年 | 128篇 |
2010年 | 99篇 |
2009年 | 100篇 |
2008年 | 85篇 |
2007年 | 121篇 |
2006年 | 103篇 |
2005年 | 75篇 |
2004年 | 73篇 |
2003年 | 70篇 |
2002年 | 36篇 |
2001年 | 39篇 |
2000年 | 24篇 |
1999年 | 24篇 |
1998年 | 16篇 |
1997年 | 29篇 |
1996年 | 22篇 |
1995年 | 18篇 |
1994年 | 14篇 |
1993年 | 3篇 |
1992年 | 2篇 |
1991年 | 3篇 |
1990年 | 3篇 |
1989年 | 5篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1984年 | 3篇 |
1983年 | 1篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1975年 | 1篇 |
1974年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有2124条查询结果,搜索用时 750 毫秒
31.
FieldmeasurementsofdisociationofammoniumnitrateataBeijingsiteShenJi,ZhaoQianxueResearchCenterforEcoEnvironmentalSciences,C... 相似文献
32.
33.
34.
Paul D. Bakke Marvin R. Pyles 《Journal of the American Water Resources Association》1997,33(4):897-906
ABSTRACT: Predictive models for nitrate in four streams in the Bull Run Watershed in the Cascade Mountains of Oregon were developed from a record of 17 years of nitrate samples. The models are time series regression models written in terms of Log(nitrate load). The independent variables are logarithm of 14-day mean daily stream discharge, current day's precipitation, logarithm of the previous day's precipitation, total precipitation for the previous seven days, a hydrograph position variable that indicates rising or falling limb, and average maximum air temperature for the preceding 14 days. The models describe annual cycle and seasonable trends and variations in nitrate load, but are unable to describe large day to day variations like those associated with hydrograph peaks. 相似文献
35.
硝酸甲胺反应过程的安全性研究 总被引:3,自引:3,他引:3
用反应量热仪(RC1e)对硝酸溶液与一甲胺溶液在反应过程中的热安定性进行初步研究,分别测试不同反应温度、加料速度和初始硝酸浓度下反应的放热情况。实验结果表明:该中和过程反应迅速,在室温就能进行;与反应温度、加料速度相比,起始硝酸浓度对反应安全性影响最大,且硝酸浓度越高,反应的速度和反应的完全程度也越高。实验还表明:RC1e是研究反应过程中热安定性情况的有效工具,能通过反应过程的热量变化体现反应速率,所得结果对硝酸甲胺的工业化生产具有重要的参考价值。 相似文献
36.
Davey L. Jones John F. Farrar Kevin K. Newsham 《Water, Air, & Soil Pollution: Focus》2004,4(6):169-175
Amino acids constitute one of the largest inputs of organic nitrogen (N) to most polar soils and have been hypothesized to be important in regulating vegetational succession and productivity in Arctic ecosystems. Our understanding of amino acid cycling in these soils, however, is poor. The aim of this study was to investigate the size and rate of turnover of the amino acid pool in a range of Arctic and Antarctic soils. Our results indicate that in polar soils with either high or low ornithogenic inputs the amino acid pool is small in comparison to the inorganic N pool (NO–3 and NH+4). The free amino acid pool constituted only a small proportion of the total dissolved organic nitrogen (DON) pool in these soils. Here we show that these low concentrations may be due to rapid use by the soil microbial community in both Arctic and Antarctic soils. The turnover of the amino acid pool in soil was extremely rapid, with a half-life ranging from 2 to 24 h, indicating that this N pool can be turned over many hundred times each summer when polar soils are frequently unfrozen. The implications of amino acids in N cycling and plant and microbial nutrition are discussed. 相似文献
37.
Ed Gidman Royston Goodacre Bridget Emmett Lucy J. Sheppard Ian D. Leith Dylan Gwynn-Jones 《Water, Air, & Soil Pollution: Focus》2004,4(6):251-258
The potential for metabolic fingerprinting via Fourier-transform infrared (FT-IR) spectroscopy to provide a novel approach for the detection of plant biochemical responses to N deposition is examined. An example of spectral analysis using shoot samples taken from an open top chamber (OTC) experiment simulating wet ammonium deposition is given. Sample preparation involved oven drying and homogenisation via mill grinding. Slurries of a consistent dilution were then prepared prior to FT-IR analysis. Spectra from control, 8 and 16 kg N ha–1 yr–1 treatments were then subjected to cross-validated discriminant function analysis. Ordination diagrams showed clear separation between the three N treatments examined. The potential for using Calluna vulgaris (L.) Hull as a bioindicator of N deposition is further evident from these results. The results also clearly demonstrate the power of FT-IR in discriminating between subtle phenotypic alterations in overall plant biochemistry as affected by ammonium pollution. 相似文献
38.
Impact of Land Use on Soluble Organic Nitrogen in Soil 总被引:5,自引:0,他引:5
Victoria B. Willett James J. Green Andrew J. Macdonald John A. Baddeley Georg Cadisch Steven M. J. Francis Keith W. T. Goulding Gary Saunders Elizabeth A. Stockdale Christine A. Watson David L. Jones 《Water, Air, & Soil Pollution: Focus》2004,4(6):53-60
Although it has been hypothesized that soluble organic nitrogen (SON) plays a central role in regulating productivity in some terrestrial ecosystems, the factors controlling the size of the SON pool in soil remain poorly understood. Therefore our principal aim in this work was to assess the impact of seven different land use systems (rough and managed grassland, deciduous and coniferous woodland, heathland, wetland and tilled land) on the size of the SON and inorganic N (NO
3
–
, NH
4
+
) pools in the surface soil layer (0–15 cm). After extraction with deionised water, we found that in most cases the size of the water extractable organic N (WEON) pool was similar in size to the inorganic N pool. In contrast, the KCl extractable organic N (KClEON) pool constituted the dominant form of soluble N in soils under all land uses, perhaps indicating that significant amounts were held on the soil exchange phase. In contrast to inorganic N, which varied significantly with land use, the size of the KClEON and WEON pool was similar for all land uses with the exception of KClEON in tilled land, where significantly lower amounts were observed. We conclude that SON constitutes an important soil N pool in a broad range of land uses, and that its role in microbial N assimilation, plant nutrition and ecosystem responses to atmospheric N deposition warrants further attention.
SAFRD, University of Newcastle, Newcastle-upon-Tyne, NE1 7RU, U.K. 相似文献
39.
Mohammad N. Almasri Jagath J. Kaluarachchi 《Journal of the American Water Resources Association》2004,40(1):165-186
ABSTRACT: This paper presents a modeling approach based on a geographic information system (GIS) to estimate the variability of on‐ground nitrogen loading and the corresponding nitrate leaching to ground water. The methodology integrates all point and nonpoint sources of nitrogen, the national land cover database, soil nitrogen transformations, and the uncertainty of key soil and land use‐related parameters to predict the nitrate mass leaching to ground water. The analysis considered 21 different land use classes with information derived from nitrogen sources such as fertilizer and dairy manure applications, dairy lagoons, septic systems, and dry and wet depositions. Simulations were performed at a temporal resolution of one month to capture seasonal trends. The model was applied to a large aquifer of 376 square miles in Washington State that serves more than 100,000 residents with drinking water. The results showed that dairy manure is the main source of nitrogen in the area followed by fertilizers. It was also seen that nitrate leaching is controlled by the recharge rate, and there can be a substantial buildup of soil nitrogen over long periods of time. Uncertainty analysis showed that denitrification rate is the most influential parameter on nitrate leaching. The results showed that combining management alternatives is a successful strategy, especially with the use of nitrification inhibitors. Also, change in the land use pattern has a noticeable impact on nitrate leaching. 相似文献
40.
农用改性硝酸铵拒爆机理及工业化可行性研究 总被引:1,自引:0,他引:1
对农用硝铵作改性处理,通过筛选和优化实验确定了改性硝酸铵配方。结果表明,当硝酸铵中添加3%的改性剂GXJ1,10%的改性剂GXJ2时,产品在1mm铁皮管约束下的雷管感度试验条件下具有拒爆特性。改性硝酸铵总养分与普通硝酸铵相当,并且颗粒强度高,不易粉化、结块和吸潮,具有优良的肥料品质。同时还利用X射线衍射分析、扫描电子显微镜分析对改性硝铵的拒爆机理作初步探讨。最终,建立了改性硝酸铵的脱水性能、流动性能、凝固性能、颗粒强度的评价方法,并进行了工业化可行性研究。 相似文献