NOx存在条件下相对湿度对甲苯氧化产物的影响

利用流动管反应器模拟甲苯与氧化剂×OH在NO_x存在条件下的反应,定量测定了不同相对湿度条件下（17.5%、35%、50%、70%）反应生成的部分气相产物和颗粒相产物,计算了不同相中产物产率,测量了不同相对湿度下的颗粒相有机碳（OC）产率,推导了相对湿度对甲苯氧化反应的影响机制.结果表明,相对湿度不仅对甲苯与×OH反应途径比例有影响,还对产物的产率及氧化程度有影响.     

郑州市氧化铝工业炉窑污染物及源谱特征

采用稀释通道采样法对郑州市一家拜耳法氧化铝企业及一家α-氧化铝企业的PM_2.5、PM₁₀样品进行采集,利用烟气分析仪检测SO₂和NO_x气体的质量浓度.对颗粒物样品中的38种化学组分进行分析,构建相应的源成分谱,运用分歧系数（CD）和组分差异权重分布函数R/U对其特征进行对比研究.结果表明：α-氧化铝源谱中以Cl^-为主（质量分数18.29%~25.21%）,拜耳法氧化铝源谱中以OC和NO₃^-为主（质量分数9.01%~41.87%）.源谱间的分歧系数（CD）显示,同一种生产工艺两种粒径间的源谱比较相似,相同粒径的两种生产工艺之间的源谱差异较大.R/U值对比结果显示,EC、Ca、F^-和Cl^- 4种元素可作为区分两种氧化铝生产工艺的标识组分.     

低温等离子体协同催化降解废气污染物的研究进展

阐述了低温等离子体协同催化工艺流程与反应机理,探讨了反应温度、废气进口组分、废气中水蒸气含量、气体流速、气溶胶等因素对降解效果的影响。分析认为:一段式低温等离子体协同催化可改变低温等离子体特征及催化剂催化特性,但尚未解决尾气臭氧逃逸、副产物产生及放电稳定性等问题;两段式低温等离子体协同催化可提高污染物分子降解效率并减少尾气臭氧逃逸,但未能有效利用等离子体的能量,气体中的水蒸气、粉尘及反应过程中产生的气溶胶均能影响后置催化剂的催化性能;两段式低温等离子体协同催化已具备工程应用条件,还需配套高效预处理单元以降低废气中水蒸气、粉尘等对催化剂的影响。     

油气集输管道内防腐技术应用进展

针对油气田集输管道的内腐蚀问题,分别介绍了耐蚀材料、衬里技术、涂镀层技术与药剂防腐技术等管道内防腐技术及其现场应用效果,指出了耐蚀金属材料防腐效果显著,但存在经济效益差的缺点。为降低成本,选用双金属复合管替代耐蚀金属材料,但其焊缝位置腐蚀失效频发,成为制约其应用的薄弱环节。耐蚀非金属材料防腐效果显著,但耐高温性能与力学性能较差,受温度、压力与CO_2、H_2S、固体颗粒等介质成分的影响,衬里技术与涂镀层技术的应用范围受到限制。药剂防腐技术的防护效果与药剂类型、加药工艺密切相关,需要根据腐蚀工况监测结果进行实时调整。针对上述内防腐技术存在的问题,提出了未来内防腐技术的发展方向为改进现有内防腐技术存在的不足,提升其防护效果。同时,应开发防腐效果显著、经济成本低、施工简便、易于推广应用的防腐材料与防腐工艺技术。     

Determination of organophosphorus pesticides and related compounds in water samples by membrane extraction and gas chromatography

A membrane extraction-gas chromatography method was developed fordetermination of organophosphorus pesticides and related compounds including methamidophos, DDVP, dimethoate, methyl parathion, parathion, thiophosphoric acid trimethyl ester, and thiophosphoramidic acid dimethyl ester in water samples. In thismethod, surface-modified acetic cellulose membranes were used to extract the target analytes in water samples, the extracted analytes were back-extracted into a small amount of methanol, andgas chromatography with pulsed flame photometric detector (GC-PFPD) was used to determine the concentrations of targetanalytes in the extracts. The recoveries obtained for thetarget analytes spiked into the water samples ranged from 66to 94%. The method detection limit for each target analyte was 0.05 g L^-1. The method developed in this study had shown the advantages of being cheap, simple, fast, and reliable. It had been used successfully to determine the concentrations of target analytes in river water samples.     

Monitoring of Butter and Ghee (Clarified Butter Fat) for Pesticidal Contamination from Cotton Belt of Haryana, India

Butter (45) and ghee (55) samples were collected from rural and urban areas of cotton growing belt of Haryana and analysed for detecting the residues of organochlorine, synthetic pyrethroid and organophosphate insecticides. The estimation was carried out by using multi residue analytical technique employing GC-ECD and GC-NPD systems equipped with capillary columns. Butter samples were comparatively more contaminated (97%) than ghee (94%), showing more contamination with organochlorine insecticides from urban samples. About 11% samples of butter showed endosulfan residues above MRL value and 2% samples had residues of synthetic pyrethroids and organophosphates each above their respective MRL values. In ghee, residues of HCH & DDT both and of endosulfan exceeded the MRL values in 5 and 20% samples, respectively. Among organophosphates, only chlorpyriphos was detected with 9% samples showing its residue above MRL value. Irrespective of contamination levels, residues above the MRL values were more in ghee. More extensive study covering other agricultural regions/zones of Haryana has been suggested to know the overall scenario of contamination of milk products.     

乌鲁木齐市汽车尾气排污现状及防治对策探讨

对乌鲁木齐市在用车辆进行了路抽检调查，通过大量数据分析，得出乌鲁木齐市目前汽车尾气排放情况仍令人担忧，治理工作不容忽视。     

Formation and Emission of N2O and CH4 from Compost Heaps of Organic Household Waster

Composting can be a source of N₂O andCH₄ production. In this investigation, differentcompost heaps of organic household waste weremonitored with the focus on potential formation ofCH₄ and N₂O in the heaps and emission ofthese gases from the heaps. The studied compost heapshad different compost ages, turning intervals andcompost sizes. The analysed compost gases containedbetween 1–3421 L of N₂O-N L^-1 and 0–470 mL of CH₄ L^-1. The emission rates ofN₂O and CH₄ from the compost heaps werebetween 1–1464 mg N₂O m^-2 day^-1 and0–119 000 mg CH₄ m^-2 day^-1. These verylarge differences in compost gas composition andemission indicate the importance of compostmanagement. The results also give an understanding ofwhere in the composting process an increasing emissionof N₂O and CH₄ can occur.     

梅梁湖的富营养化状况及治理对策讨论

监测结果表明，梅梁湖水体ＴＰ，ＴＮ含量分别为０．１ｍｇ／Ｌ和３．４ｍｇ／Ｌ藻类生物量达９－１３亿个细胞／Ｌ，富营养化相当严重，污染的主要原因，工农业，渔业，畜牧业和生活污水的直接排放，使水全营养盐含量较高，藻类大量繁殖，可采用“控源截汛”，“清除淤泥”，“调水搞活”及生物治理等综合性措施，对梅梁湖的富营养化进行了治理。     

乌鲁木齐市汽车尾气污染状况调查

对乌鲁木齐市主要街道受汽车尾气污染的调查和综合分析得到CO、NOx、HC的污染规律,主要街道路中心空气中CO、NOx日均值已超出国家大气环境质量二级标准,市区主要街道的人行道空气中NOx含量已超出二级标准,Ⅱ、Ⅲ类道路人行道空气中CO含量已超标;在三类街道中,Ⅰ类街道车流量最大,Ⅱ类次之,Ⅲ类最少,而汽车排放尾气对街道空气污染状况为Ⅲ类最重、Ⅱ类次之、Ⅰ类最轻。