超低沸点挥发性有机物测定中的要点分析

采用大气浓缩仪-气相色谱法测定超低沸点挥发性有机物乙烷、乙烯、丙烷、丙烯、乙炔,选用PLOT-Q柱分析,控制真空罐内相对湿度约50%,通过优化测定条件使方法线性良好,5种低沸点化合物的检出限为0.08 nmol/mol～0.2 nmol/mol,样品保存时间不超过10 d。用该方法测定某地区环境空气中VOCs,结果检出率均为100%。     

Effects of fuel reactivity and injection timing on diesel engine combustion and emissions

Recent strategies for simultaneously reducing NOx and soot emissions have focused on achieving nearly premixed, low-temperature combustion (LTC) in diesel engines. A promising approach in this regard is to vary fuel reactivity in order to control the ignition delay and optimize the level of premixing and reduce emissions. The present study examines such a strategy by performing 3-D simulations in a single-cylinder of a diesel engine. Simulations employ the state-of-the-art two-phase models and a validated semi-detailed reaction mechanism. The fuel reactivity is varied by using a blend of n-heptane and iso-octane, which represent surrogates for gasoline and diesel fuels, respectively. Results indicate that the fuel reactivity strongly influences ignition delay and combustion phasing, whereas the start of injection (SOI) affects combustion phasing. As fuel reactivity is reduced, the ignition delay is increased and the combustion phasing is retarded. The longer ignition delay provides additional time for mixing, and reduces equivalence ratio stratification. Consequently, the premixed combustion is enhanced relative to diffusion combustion, and thus the soot emission is reduced. NO_x emission is also reduced due to reduced diffusion combustion and lower peak temperatures caused by delayed combustion phasing. An operability range is observed in terms of fuel reactivity and SOI, beyond which the mixture may not be sufficiently well mixed, or compression ignited. The study demonstrates the possibility of finding an optimum range of fuel reactivity, SOI, and EGR for significantly reducing engine out emissions for a given load and speed.     

氟化物对酸浸取沸腾炉渣中铝的影响

采用酸浸取法、加入助溶剂浸取沸腾炉渣中的铝,考察了各种因素对铝浸出率的影响。实验结果表明：在球磨时间为30min、固液比（沸腾炉渣质量与酸体积之比）为1：7、硫酸浓度为4mol／L、浸取温度为107℃、浸取时间为120min的条件下,铝浸出率最高（为29．72％）;KF,NH4F,NaF,CaF2等作助溶剂可明显提高铝浸出率,且助溶剂为CaF：时的铝浸出率最高,CaF2与沸腾炉渣的质量比为0．08时的铝浸出率大于75％。     

Experimental study and prediction of liquid nitrogen pool evaporation process on concrete surface

The vaporization rate of pool boiling process of a liquid nitrogen spilled on concrete surface was investigated by a visual experiment platform. The boiling curve for liquid nitrogen on concrete cooling process was obtained. The shapes of bubbles in three typical boiling regimes were observed. Based on the experimental results, the coefficients of the empirical formulas for nuclear boiling and film boiling are modified, and the empirical formulas for boiling of liquid nitrogen-concrete surfaces are obtained. Combined with the calculation formula of the non-steady-state semi-infinite one-dimensional heat conduction temperature, a coupled calculation model for the heat transfer and vaporization process of liquid pool on the liquid nitrogen-concrete surface is proposed. Application of this model can better predict the quality of liquid nitrogen vaporization.     

大城市无信号控制人行横道行人过街延误分析

从心理学角度,以大城市无信号控制人行横道过街行人为研究对象,对行人过街延误进行定量分析研究。以北京市两个典型无信号控制人行横道为实例进行交通调查分析,计算行人的临界穿越间隙,安全穿越间隙出现的概率,及行人穿越该处的总延误时间。计算结果表明:观测路段车流中提供的安全穿越间隙的概率比较低;行人强行穿越的重要原因是行人过街延误超出了行人等待心理极限;验证了模型的精度;找出了观测路段交通秩序混乱的原因。针对大城市无信号控制人行横道的分析结果,提出了具体的改进建议和交通改善措施,为国内大城市行人交通安全管理提供了决策依据和有益参考。     

点火延迟时间对粉尘最大爆炸压力测定影响的研究

根据粉尘云形成时颗粒分散及沉降的时间效应,指出目前国际通行的球型爆炸装置采用固定点火延迟时间测定粉尘最大爆炸压力的方法具有不确定性,并以煤粉为介质在20 L标准爆炸球装置上进行系列爆炸实验,研究装置点火延迟时间对粉尘爆炸压力的影响。结果表明:点火延迟时间对粉尘爆炸压力测定有十分显著的影响,不同粒径粉尘的最大爆炸压力有不同点火延迟时间,目前仅以气相湍流度所确定的固定点火延迟时间下,所测粉尘最大爆炸压力可能严重偏离实际。     

冷连轧机动态过程的数值模拟

在计算机上采用数值分析方法研究轧制过程的动态特性 ,是轧钢智能发展的重要趋势。本套软件开发采用C++语言 ,对冷连轧动态过程进行数值模拟 ,给出在出现干扰量(如来料厚度波动 )及控制量 (如辊缝波动 )时 ,主要工艺参数 (如轧制压力、张力 )及厚度延时仿真结果 ,对过程自动控制系统具有十分重要的意义。     

保护层一次爆除技术在船闸开挖中的应用

在贵港航运枢纽工程船闸开挖中，采用了孔间微差和宽孔距小梯段孔底设柔性保护层的一次钻爆技术，确保了基岩的完整性。     

基于系统动力学的企业安全经济效益分析 —以安全教育经济效益子系统为例

为达到企业安全经济效益最大化的目标,运用系统动力学的方法对企业安全经济效益系统进行建模,并对其中的安全教育经济效益子系统进行仿真模拟。实验结果表明:改变系统中的影响因素,安全教育经济效益并没有立即发生变化,而存在一段“延迟阶段”。同时也证明了安全培训人员能力在安全教育经济效益系统中具有最大的影响效果。     

基于三星定位的卫星干扰源定位TDOA参数估计方法的研究

定位是通过对某一个或几个参数进行估计来实现的,因此参数估计方法是定位问题的关键。卫星干扰源三星定位算法需要测得一对TDOA的值,因此TDOA估计算法是解决问题的关键。本文介绍了经典的基于最小均方误差的自适应时延算法（LMSTDE）原理,并在此基础上加入四阶累积量的概念,改进了LMSTDE在相关高斯噪声背景下不适用的缺点...