中美燃煤火电厂空气污染物排放标准比较研究

本文对中美燃煤火电厂国家行业排放标准的内容设置、限值形式、监测、记录和报告规定,以及固定源排污许可证中如何执行排放标准进行了比较。相对于美国,中国燃煤火电厂国家行业排放标准文本内容过于简略,限值形式设置单一,主要采用全国统一的浓度限值而不是采用绩效限值;浓度限值的制定基于部分样本源而不是全部源的数据,很难体现行业的排放控制技术水平;达标判据不科学,也过于严格,小时均值的考核方式影响了火电厂的生产安排;排放标准中监测配套规定单薄,与环境监测的一般规定衔接性不佳,针对性差;记录和报告要求缺位,不能满足排污许可证管理的需求。建议参照美国行业排放标准的内容形式,排放限值采用绩效限值形式,并规定长平均周期的考核要求,将与之配套的监测、记录和报告要求纳入排放标准,以满足固定源排污许可证制度的需求。     

Diversity in sub-national EU implementation: the application of the EU Ambient Air Quality directive in 13 municipalities in the Netherlands

This paper offers an analysis of the implementation performance of the EU Ambient Air Quality directive in the Netherlands. It provides a systematic evaluation of the implementation of a procedural provision – the obligation to design air quality policy. It draws on original data on air quality policy measures that have been collected in 13 medium-sized Dutch municipalities. The analysis of differences in the implementation performance was performed using a novel three-dimensional conceptual framework. The findings illustrate great differences in the implementation performance between the municipalities. The focused comparison allowed establishing very precisely where the implementation performance is poor or even lacking, and which municipalities take their EU implementation task more seriously than others. Most puzzling, environmental problem pressure turned out not to act as a sufficient trigger for municipalities to take far-reaching air quality measures. In contrast to previous research, a more nuanced picture is painted when it comes to the concepts of ‘compliance’, ‘non-compliance’ and ‘over-compliance’. A careful dissection of the implementation performance based on the aspects of the conceptual framework produces hands-on recommendations to municipalities seeking to improve their air quality policy.     

Constructing meaningful environmental indices: A nonparametric frontier approach

Environmental information disclosure programs seek to motivate firms to reduce their environmental impact. A variety of environmental impacts are reported in these programs and often this information is aggregated into a composite environmental index (CEI) for easier communication. The challenge is to create a meaningful index that allows environmental performance to be compared over time and space without ambiguity. In this paper, we argue that it is important to develop a cardinally meaningful and standardized CEI and use a nonparametric frontier approach to constructing such an index. This approach has the advantage to handle issues associated with data irregularity and the mixed measurability of underlying variables. We apply this approach to constructing a CEI for evaluating the environmental performance of manufacturing facilities in different industrial sectors in Los Angeles based on data from the toxic release inventory. We show how the CEI can be used to improve facility-level environmental performance. A sensitivity analysis is conducted with respect to the uncertainty in data accuracy, which demonstrates the robustness of the nonparametric frontier approach in constructing meaningful environmental indices.     

灌浆套筒连接预制拼装桥墩抗剪性能对比试验研究

灌浆套筒连接预制拼装桥墩抗弯性能得到了广泛研究,但抗剪性能研究较少.为对比分析灌浆套筒连接预制拼装桥墩抗剪性能,制作了2个相同缩尺比的现浇和预制拼装桥墩模型.通过拟静力方式测到了两类结构极限承载力、变形和耗能能力等抗震性能指标.对比分析结果表明,预制桥墩与现浇桥墩破坏模式存在显著差异,但是预制桥墩具备与现浇桥墩相近的耗...     

拉萨站线缆材料短期试验性能分析

分析了线缆材料在拉萨自然环境试验站中1～2年的短周期试验性能变化。线缆高分子材料在土壤环境中性能变化较小,而在大气环境中力学性能有所下降,HDPE耐环境性能、应力开裂性能下降26％;金属在土壤环境中腐蚀较轻。拉萨大气与土壤自然环境对材料的短期腐蚀（老化）作用比较轻微。     

Performance Evaluation of the SLEUTH Model in the Shenyang Metropolitan Area of Northeastern China

Performance evaluation is crucial for the development and improvement of an urban cellular automata model, such as SLEUTH. In this paper, we employed multiple methods for map comparison and model validation to evaluate the simulation performance of the SLEUTH urban growth model in the Shenyang metropolitan area of China. These multiple methods included the relative operating characteristic (ROC) curve statistic, multiple-resolutions error budget, and landscape metrics. They were used to quantitatively examine model performance in terms of the amount and spatial location of urban development, urban spatial pattern and prediction ability. The assessment results showed that SLEUTH performed well in the way of the quantitative simulation of urban growth for this case study. Similar to other urban growth models, however, the simulation accuracy for spatial location of new development at the pixel scale and urban spatial pattern still needs to be improved greatly. These inaccuracies might be attributed to the structure and nature of SLEUTH, local urban development characteristics, and the temporal and spatial scale of its application. Finally, many valuable suggestions had been put forward to improve simulation performance of SLEUTH model for spatial location of urban development in the Shenyang metropolitan area.     

高效液相色谱法测定地表水中硝基苯类化合物

建立了液相色谱法直接测定水中的10种硝基苯类化合物的方法,C18色谱柱为分离柱,检测波长为254 nm,以甲醇和水为流动相,前处理过程水和甲醇以9∶1的体积比混合,水样过微孔滤膜后直接进液相色谱分析。该法分析10种硝基苯类化合物的检出限为4.3~5.5μg/L,加标回收率为79%~136%,精密度为6.8%~13%,符合监测要求。     

高效液相色谱-电感耦合等离子体质谱联用测水中有机汞

建立了高效液相色谱-电感耦合等离子体质谱联用技术(HPLC-ICP-MS)测定水样中甲基汞、乙基汞、苯基汞等3种有机汞的分析方法。采用醋酸铵-L-半胱氨酸缓冲盐及甲醇体系组成的流动相按一定比例进行梯度洗脱,Agilent Zorbax Plus C18柱分离,经前处理的水样在液相色谱中分离后,进入电感耦合等离子体质谱检测其甲基汞、乙基汞、苯基汞的浓度。3种有机汞化合物均在0.50~50.0μg/L范围内呈良好的线性关系,线性相关系数均大于0.999 5。仪器检出限为0.09~0.12μg/L,方法检出限为0.4×10-6~0.6×10-6mg/L,3种有机汞样品加标的RSD均小于11.3%,2个水平的加标回收率为74.4%~83.2%。     

醛类化合物检测方法中腙类物质的衍生条件

通过对醛类化合物的DNPH衍生化酸度、摩尔比、时间条件的研究和衍生化结果的验证获得了过量DNPH条件下制备15种醛的腙标准溶液制备方法。实验结果表明,其共同衍生化条件为1.0~2.0 mol/L盐酸溶液中DNPH/醛类摩尔比不小于2∶1条件下,醛类物质与DNPH可充分衍生化。     

超高效液相色谱-串联质谱法测定水中痕量双酚A

采用超高效液相色谱-串联质谱法测定水中痕量双酚A,水样经预处理后,以BEH C18超高效液相色谱柱分离,在质谱电喷雾离子源负离子多反应监测模式下测定.方法在0.200μg/L～10.0μg/L范围内线性良好,相关系数r为0.9992,方法检出限为0.06μg/L,空白及实际样品加标回收率为87.4% ～114%,RSD为3.6% ～7.4%.