煤与瓦斯突出冲击波及瓦斯气流所致伤害研究

为揭示煤与瓦斯突出过程中冲击波及瓦斯气流传播特性,针对这种突出做功随瓦斯压力、煤的普氏系数和煤的放散初速度变化的特征,运用气体动力学理论,建立冲击波超压、冲击瓦斯流速度与传播距离以及煤层瓦斯压力等参数的关系,计算不同超压下瓦斯气流传播伤害的范围。理论计算与现场测试结果表明,突出冲击波属惰性弱冲击波;波阵面上的超压传播伤害距离与突出时瓦斯膨胀的强度、巷道断面及巷道壁面的摩擦力和局部阻力等因素有关;冲击产生的高压瓦斯气流是造成巷道内大量人员窒息伤亡的主要诱因;突出能量瞬间释放没有补给,冲击波及瓦斯气流会在巷道阻力等因素作用下迅速衰减。     

Dynamic pressure induced by a methane–air explosion in a coal mine

The hazardous effect of dynamic pressure and strong gas flows induced by a methane–air mixture explosion in underground coal mines is studied. The dynamic pressure effect of a methane–air explosion was analyzed by numerical simulation, in a duct and tunnel. Compared to the overpressure generated by an explosion that can act on a body, the dynamic pressure caused by the high-speed flow of the gaseous combustion products can cause serious damage as well. At the structural opening of a coal mine, the destruction caused by the dynamic pressure induced by a methane–air explosion is more serious than the overpressure. For a tube or tunnel partially filled by a methane–air mixture, the dynamic pressure is lower than the overpressure in the region occupied by the flammable mixture. Beyond the premixed region, the dynamic pressure is of the same order of magnitude as the overpressure.     

深孔预裂爆破对含坚硬顶板高瓦斯煤层的综合作用研究

为研究深孔预裂爆破技术在含坚硬顶板高瓦斯煤层开采中的应用,以顾桥矿1123(1)工作面坚硬顶板为研究对象,基于小挠度理论建立了坚硬顶板垮落力学模型,导出了初次来压步距计算式;综合考虑瓦斯抽采需要,对深孔预裂爆破孔进行了优化设计,并在工作面顶板中开展了现场试验研究。结果表明:在工作面推进至27.3m时出现垮落,爆破后钻孔瓦斯流量显著增加,部分提高至30倍以上,瓦斯抽采量提高了3.5倍,初采期间安全回采煤炭25万吨,实现了坚硬顶板控制和卸压增透双重作用。     

Effects of release pressure on the transportation characteristics in pipeline and the diffusion behaviors in enclosure space of typical gas extinguishing agent

Reducing the release pressure of fire extinguishing systems can decrease potential safety hazards in large transport airplanes. To explore whether reducing the release pressure can achieve the release effect required by the airworthiness standards or not, the transportation characteristics in the pipeline and diffusion behaviors in the enclosure space of a typical fire extinguishing agent (Halon 1301) were investigated under five release pressures in the present study. The effects of the release pressure on the degree of superheat, injection duration, jet structure, and concentration distribution of Halon 1301 were analyzed. The results show that both of the degree of superheat and the injection duration decrease with an increase in the release pressure. The supplement of bubble expansion in the fire extinguishing agent can slow down the pressure decrease in the vessel. Both of the maximum and mean values of the pipeline differential pressure increase with an increase in release pressure. The maximum value of the jet angle decreases linearly with the increase in release pressure, and the jet deflects upward owing to the effects of buoyancy. The maximum concentration value decreases with an increase in the distance from the nozzle. The maximum concentration values in the near field from the nozzle increase with an increase in the release pressure. Under five release pressures, the concentration and holding time (duration above 6% volume concentration) of Halon 1301 on the centerline of the jet meet the requirements of airworthiness provisions.     

瓦斯压力对卸荷原煤力学特性及能量特征的影响

运用自主研制的含瓦斯煤热流固耦合三轴伺服渗流试验装置,以原煤煤样作为研究对象,进行了含瓦斯煤固定轴向压力、卸围压的渗流试验,研究了卸围压过程中瓦斯压力对煤样力学特性和能量特征的影响。结果表明:在轴压加载阶段,煤样的变形模量基本不变,泊松比逐渐减小;在定轴压卸围压阶段,煤样的变形模量先小幅度增加,然后逐渐减小,泊松比则逐渐增大。瓦斯压力越高,煤样的承载能力越低,煤样发生破坏时相应的轴向应变和围压卸荷量百分比越小,而煤样破坏时的径向变形和扩容量越大。各应变围压柔量Δεi与瓦斯压力呈线性关系且线性相关性良好。随瓦斯压力升高,轴向应变的围压敏感性降低,径向应变和体积应变的围压敏感性显著升高。随瓦斯压力升高,煤样发生破坏时存储的弹性应变能Ue减小,而总能量U、耗散能Ud和耗散能比例Ud/U都增大。     

以氢气为主要成分的其他可燃气体对低浓度甲烷爆炸特性的影响

为研究矿井火区中一氧化碳(CO)、氢气(H_2)、乙烯(C_2H_4)和乙烷(C_2H_6)等其他可燃气体对甲烷(CH_4)爆炸特性的影响,利用可视球形气体爆炸系统开展了多元可燃气体爆炸压力特性试验,观察并分析了峰值爆炸压力、最大爆炸压力上升速率及其相应时间。通过高速摄影系统拍摄了视窗范围内爆炸火焰传播图像,基于边缘检测方法确定了火焰前锋位置,继而得到最大火焰传播速度。分析了以氢气为主要成分的其他可燃气体对低浓度CH_4-空气混合物压力特性和火焰传播行为的影响。结果表明,多元可燃气体的存在增加了低浓度CH_4-空气混合物的爆炸危险性。随混合气体体积分数增加,低浓度CH_4-空气混合物的峰值爆炸压力、最大爆炸压力上升速率和最大火焰传播速度非线性增加;此外,到达峰值爆炸压力、最大爆炸压力上升速率的时间显著缩短。     

表面活性剂在甲烷氧化菌降解煤体甲烷中的适用性研究

甲烷氧化菌液在进入煤储层后会产生较高的毛管压力,且随着甲烷氧化菌降解煤层瓦斯的进行,毛管压力逐渐增大,容易引起水锁伤害。采取向甲烷氧化菌菌液加入复配表面活性剂以期减缓菌液造成的水锁伤害,通过测试所选表面活性剂十二烷基苯磺酸钠（SDBS）与椰子油脂肪酸二乙醇酰胺（CDEA）对菌液表面张力的降低程度来了解表面活性剂与菌液的配伍比例,并对含复配表面活性剂的甲烷氧化菌对煤层甲烷的降解进行研究。研究结果表明:表面活性剂与菌液最佳配伍比例为SDBS∶CDEA为1∶4,最佳配伍浓度为0.5％,且表面活性剂在菌液中稳定性较好;菌液中添加复配表活剂20 mL,在混合气体压力为2 MPa、氧浓度为 1％、温度为 30 ℃时,添加复配表面活剂菌液的甲烷最终降解率为51.65％,比未添加复配表面活剂菌液高出11％左右。因此,向甲烷氧化菌菌液中添加复配表面活性剂具有很好的适用性。     

Theoretical pressure prediction of confined hydrogen explosion considering flame instabilities

In order to ensure the safe utilization of hydrogen energy, the explosion pressure behavior is extremely important to design chemical equipment and evaluate explosion accident consequence. This paper is aimed at establishing a theoretical method of predicting explosion pressure behavior in the confined chamber by considering flame instabilities. The tendency of flame wrinkling factor in the pressure-buildup stage is firstly evaluated using large eddy simulation and the compensation theory. The limiting value of flame wrinkling factor during entire explosion process is calculated using the fractal theory. Finally, the dynamic model of flame wrinkling factor is implemented into the smooth flame model. The results demonstrated that the flame wrinkling factor in the pressure-buildup stage almost increases linearly with time. The limiting value of flame wrinkling factor is 2.4649. The explosion pressure will be underestimated using the smooth flame model, and the calculated explosion pressure in the isothermal condition is smaller than that in the adiabatic condition. When the fully turbulent flame is considered, the explosion pressure will be overpredicted significantly. By changing the confined chamber size, the explosion pressure could be reproduced relatively satisfactorily when the flame wrinkling factor is assumed to increase exponentially. The explosion pressure prediction must consider the effect of adiabatic compression and flame instabilities on burning rate.     

低压离子色谱法测定水和酸雨样品中的Li~+,Na~+,NH_4~+,K~+,Ca~(2+)和Mg~(2+)离子

本文介绍了低压离子色谱仪测定水样(井水、湖水、矿泉水、自来水)和酸雨中锂、钠、铵、钙、钾和镁离子的方法、欲测阳离子在阳离子交换柱上被分离,分别用1.4mmol·1~(-1)HNO_3和0.6mmol·1~(-1)乙二胺+1.2mmol·1~(-1)HNO_3溶液作流动相,流速为1.6ml·min~(-1).各离子的流分用电导检测.进样量为10μl时,Li~+,Na~+,NH_4~+,K~+,Ca~(2+)和Mg~(2+)离子的检出限(2倍噪音比),分别为0.020,0.050,0.100,0.250,2.5和1.0μg·ml~(-1).     

氯气压力自动检测调节新技术在氯气系统的应用

氯碱生产中,氯气系统压力不易控制,容易发生泄漏爆炸事故。为解决这一难题,保证安全生产,金川公司化工厂于１９９６年设计并安装了一套氯气压力自动检测调节系统,经过两年的实际使用,达到了稳定氯气系统压力的良好效果。