污水处理厂设备维护管理优化研究

以JL污水处理厂设备管理优化过程为例,充分吸取LCC,TPM中的先进思想,以设备运行可靠性及设备维护经济性为追求目标,建立了设备管理优化体系。流程体系上,通过建立作业指导文件,建立标准化维修程序,对于操作过程及时进行记录,建立可视化、可追溯的管理方法;指标体系上,根据设备重要性及运行状况,确定设备风险指数,分级管理;建立控制指标,并动态调整;管控体系上,建立设备“户口”,对设备的维护、保养、使用等信息进行全面登记;考核设备维护的全面性、及时性、可靠性、合规性;重视设备维护的预计与预警;技术体系上,通过设备监测仪器的使用,对设备运行状况定量化。通过不断推进设备预防性维护工作,设备完好率不断提升,仪表完好率从2016年的97.34%,96.55%水平,分别提升至99.08%,98.72%;维护费用也保持在较低水平,检修费与资产比例在实施的前两年分别降至1.49%,0.85%,实现了污水处理厂节能降耗及运行可靠性的强化。     

交联剂TAIC反应风险评估分析

利用全自动反应量热仪和绝热加速量热仪等相关实验仪器检测出TAIC(三烯丙基异氰尿酸酯)合成反应的反应热、比热容及热稳定性等数据,依据绝热温升、工艺温度、技术最高温度、最大反应速率到达时间及失控体系可能达到的最高温度这5个温度参数按照评估标准从分解热、严重度、可能性、矩阵、工艺危险度这5个方面分别进行评估。通过对热参数及实验过程进行分析提出降低工艺危险等级的工艺优化方法。根据最终评估结果对TAIC生产装置的安全性进行评价,提出相应的整改措施及建议。     

走向工作面贯通上山与支架快速回撤技术

针对走向工作面停采线与上山之间的护巷煤柱造成煤炭损失,支架回撤工艺复杂、巷道掘进量大等问题,提出走向工作面贯通上山与支架快速回撤技术。工作面贯通采区上山,利用上山回撤支架。在贯通前,利用压力拱模型分析剩余煤柱应力变化规律,并结合极限平衡区公式,确定让压煤柱为8 m;对贯通前基本顶合理断裂位置、让压调节机制、末采阶段采高进行了分析确定,并采取上山巷内补强支护及挂绳铺网措施。贯通上山后,首先利用支架对上山留巷,完成留巷后,利用上山回撤支架,先将上部端头3架逆时针旋转90°作为掩护架,在对剩余支架逐架回撤时,3个掩护架呈现台阶型。提出的技术取消了护巷煤柱及回撤通道,提高了煤炭采出率,减少了巷道掘进量,简化了回撤工艺。     

基于改进模体方法的国家应急组织合作网络基元比较

为分析和比较应对非常规突发事件过程中,由不同类型组织个体及其不同频次合作关系构成的应急复杂组织网络的微观结构特征,研究运用表征个体差异和关系强弱的改进模体分析方法,以中国和美国国家应急组织合作网络为例,比较分析其基元同构与异构特征。结果表明:中美应急组织系统不同类型的应急主导和支持组织构成的主要合作模式具有同构性,但子图结构数量分布具有异构性;考虑个体间关系频次差异,中美应急组织网络基元合作模式具有形式同构但相对数量分布异构的特征;比较而言,美国合作网络为分布式、分权化和关系型基元构型,中国合作网络具有集中式、集权化和契约型基元特征。     

Inherent thermal runaway hazard evaluation method of chemical process based on fire and explosion index

Thermal runaway hazard assessment provides the basis for comparing the hazard levels of different chemical processes. To make an overall evaluation, hazard of materials and reactions should be considered. However, most existing methods didn't take the both into account simultaneously, which may lead the assessment to a deviation from the actual hazard. Therefore, an integrated approach called Inherent Thermal-runaway Hazard Index (ITHI) was developed in this paper. Similar to Dow Fire and Explosion Index(F&EI) function, thermal runaway hazard of chemical process in ITHI was the product of material factor (MF) and risk index (RI) of reaction. MF was an indicator of material thermal hazards, which can be determined by initial reaction temperature and maximum power density. RI, which was the product of probability and severity, indicated the risk of thermal runaway during the reaction stage. Time to maximum rate under adiabatic conditions and criticality classes of scenario were used to indicate the runaway probability of the chemical process. Adiabatic temperature rise and heat of the desired reaction and secondary reaction were used to determine the severity of runaway reaction. Finally, predefined hazard classification criteria was used to classify and interpret the results obtained by this method. Moreover, the method was validated by case studies.     

Systematic review on the implementation methodologies of inherent safety in chemical process

The accomplishments of inherent safety in the field of loss prevention thus far are impressive due to its scientific philosophy: reducing risks at source rather than adding engineered and procedural protections. Generally, the implementation of inherent safety can be done through a cohesive set of fourteen principles elucidated by Kletz and Amyotte. This work, guided by the fourteen principles, presents a systematic review on the implementation methodologies of inherent safety. Firstly, PRISMA procedure was adopted to select eligible literatures according to inclusive and exclusive criteria. After obtaining the selected literatures, the preference, level of application, and gaps in using these principles were critically analyzed. Of the fourteen principles, intensification, substitution, attenuation, simplification, limitation of effects, and avoidance of knock-on effects are preferable to implementing inherent safety in chemical process. Although the remaining principles are also potentially useful, they are not commonly used due to their costs and complexities of implementation. Overall, this work presents a complete spectrum to look across the implementation methodologies of inherent safety and concludes with some holistic and inclusive approaches as future research recommendations.     

Misoperation monitoring and early warning during startup and shutdown of petrochemical units

Most petrochemical units run under extreme conditions, such as high temperatures, pressures, and speeds. Consequently, the equipment operators may commit errors because the startup and shutdown processes usually involve complicated operation steps; moreover, the operators may lack experience in handling abnormal situations. Misoperation can lead to accidents, including fires and explosions. Thus, risk analysis for process operations and the development of preventive measures have become an effective means of avoiding misoperation-related accidents. However, it is challenging to ensure the comprehensiveness of risk-analysis results. In this paper, we present a method for misoperation monitoring and early warning in the startup and shutdown processes of petrochemical units. The mechanisms of misoperation occurrence are summarized based on investigations of serious accidents in the recent past. Knowledge regarding the mechanisms of misoperation is crucial for the risk analysis of petrochemical units. The potential risk information, such as causes, adverse consequences, key monitoring parameters, and prevention control solutions, should be acquired and be employed to construct an early-warning knowledge database. Furthermore, misoperation judgment rules need to be formulated to identify misoperations. The data obtained from the monitoring module, misoperation judgment rules, and analysis results can aid in developing schemes to avoid possible abnormal situations. This paper reports a misoperation monitoring and early-warning system for a hydrogenation unit. As demonstrated, conducting risk analysis to determine the potential operational risks and formulating misoperation judgment rules to analyze the process data are essential for enabling early warning. The application of this method will contribute to operational guidance, economic loss reduction, and accident avoidance.     

某处理厂CASS池改造工艺选择及运行效果

随着污水处理厂排到受纳水体标准的不断提高及区域污染物排放限值的要求,已建的污水处理厂需要提标改造提高排放标准。本文所提工程对现有的CASS池进行改造,通过投加悬浮填料形成CASS+MBBR工艺,其中TN污染物的去除率可提高到8%~15%间,其它污染物也能达到预期的设计标准。     

生物柴油产业链分析

生物柴油是指由植物油、动物油脂等制备得到的单烷烃酯类。它是一种环境友好、清洁排放的燃料,因此是非常理想的石油柴油替代燃料。本文从生物柴油产业链中的原料来源、生产工艺、产品应用以及其效益等方面对这种新型的清洁燃料进行了简单介绍。总之,生物柴油是一种很有发展前景的生物质燃料。     

大气环境监测全过程质量控制研究

我国经济飞快的发展速度,不但丰富了人们的生活内容、方便了人们的生活,而且还在人们生活中产生了一些负面影响,大气污染问题已经引起了国家政府以及我国民众的一致关注,国家还为此制定并颁布了相关的整顿治理措施,在大气环境治理方面,大气监测是重要手段,本文对大气环境监测全过程质量控制问题展开分析研究。