流动注射分光光度法测定水中六价铬的研究

研究建立了测定水中六价铬的流动注射光度分析方法,探讨了利用抗坏血酸的还原性扣除水样中轻度色度或浊度干扰的可行性.本方法线性关系好,检出限低,精密度和准确度高,对地表水、地下水、生活污水、工业废水等实样的测定获得了令人满意的结果.与传统的二苯基碳酰二肼分光光度法相比,具有方法简单、灵敏度高、分析速度快等优点,适用于环境监测的分析工作.     

新疆阜康冶炼厂无污染工艺及环境治理

介绍了阜康冶炼厂无污染新工艺和环境治理的有关情况 ,从理论上阐述了无污染工艺和污水治理的技术原理 ,对有色金属冶炼工业逐步采用湿法精炼清洁工艺有一定的指导作用     

Effect of Trivalent and Hexavalent Chromium on Carbohydrate Metabolism of a Freshwater Field Crab, Barytelphusa guerini

The in vivo toxic impact of chromium in its two forms(trivalent and hexavalent) on glycogen metabolism in the tissuesof freshwater field crab Barytelphusa guerini was studied.In a sublethal long-term exposure of 30, 60 and 90 days, thedepletion of glycogen and glucose levels reflected in theactivity of glycogenphosphorylases `a' and `ab'. A tissuespecific and time-dependent variation in tissue glucose reservesparelleled the progressive accumulation of haemolymph sugars.Trivalent and hexavalent chromium induced alterations in metabolite levels and in enzyme activities in the tissues. Themagnitude of responses were found more in the hexavalent formthan in trivalent form.     

Synthesis of hydrogarnet from molten slag and its hydrogen chloride fixation performance at high temperature

Hydrogarnet was synthesized hydrothermally below 200°C using molten slag obtained from municipal solid waste. For comparison, it was also synthesized using pure-phase CaO–Al₂O₃–SiO₂–H₂O, as reported previously. The structural and textural properties of this material were investigated using various analytical and spectroscopic techniques such as X-ray diffraction, X-ray fluorescence spectrometry, atomic absorption spectrometry (AAS), thermogravimetry/differential thermal analysis, Fourier transform infrared spectroscopy, and scanning electron microscopy. The Cl⁻ fixation ability of hydrogarnet was investigated in the temperature range 500–800°C in a fixed-bed flow reactor using a HCl concentration (1000 p.p.m.v.) similar to that of incinerator exhaust gas. Under these experimental conditions, the hydrogarnet was capable of reducing the HCl gas level to less than 1 p.p.m.v. Analysis of the spent catalyst revealed that the hydrogarnet was being transformed into wadalite and CaCl₂ at high temperatures. The elution test for chromium ions in hydrogarnet obtained from slag was also used, and it was found that chromium ions were not eluted from hydrogarnet. Received: January 27, 2001 / Accepted: October 11, 2001     

城市土地资产经营新思路探讨

自1996年上海市成立第一家土地收购储备机构——土地发展中心后，全国各大城市已纷纷效仿它的成功经验。截止2001年8月不完全统计，全国已有大小不同的土地收购储备机构669家。实践证明，土地收购储备机制在盘活城市存量土地，促进土地集约利用，保障城市土地资产的保值增值等方面成绩卓著。然而，实践过程中，土地收购储备机制的运作也暴露出不少问题。本文通过对这些问题的分析，提出了引进公司制度完善土地收购储备机制，合理运营城市土地资产的新思路。     

Bioremediation of Chromate by Sulfate-Reducing Bacteria, Cytochromes c3 and hydrogenases

The treatment of soils and ground waters polluted by heavy metals is of economical and environmental interest. Reduction of Cr(VI) to the less toxic Cr(III) associated to its precipitation is a potentially useful process for bioremediation. In order to develop ecological processes using micro-organisms, we have compared various sulfate-reducing bacteria for enzymatic reduction of chromate. The best Cr(VI) reductase activity was obtained with Desulfomicrobium norvegicum. Despite morphological changes induced by the presence of chromate, this strain can grow in the presence of up to 500 M Cr(VI) and can decontaminate waters polluted by Cr(VI) when seeded in bioreactors. We have demonstrated the ability of several metalloenzymes (cytochromes c ₃ and hydrogenases) to reduce chromate. Biophysical investigations of the chromate/protein interaction in order to get further informations on the mechanism of metal reduction by cytochromes c ₃ are under the way.     

氯离子选择性电极法测定钻井废水氯离子含量

利用氯离子选择性电极测定钻井废水中的氯离子含量，分别用两种方法对钻井废水进行了预处理，氯离子在0-250mg/L的范围内线形关系良好，相关系数为0.9968,并且重现性和选择性良好、精密度与准确度较理想。     

THE IMPACT OF URBANIZATION ON THE DISTRIBUTION OF HEAVY METALS IN BOTTOM SEDIMENTS OF THE SADDLE RIVER1

ABSTRACT: A three-year study has been conducted on a 4.6 mile stretch of the Saddle River near Lodi, New Jersey. The primary objectives of this investigation were (1) to provide baseline information on the concentration and distribution of heavy metals in bottom sediments of the Saddle River; (2) to qualitatively evaluate which parameters affect this distribution; and (3) to determine the effect of urbanization on the concentration and distribution of these materials. Significant enrichments of several heavy metals were observed in bottom sediments of the lower Saddle River near Lodi, New Jersey, as compared to the upper Saddle River. Attempts to correlate metal concentrations in bottom sediments with chemical-oxygen demand were not successful in demonstrating a relationship between these two factors. Metal concentrations were found to be strongly dependent upon particle size. In general, metal concentrations in bottom sediments increased with decreasing partical diameter. However, metals enrichment was observed to be considerably greater in the larger sediment fractions studied (>420μ) than the smaller sediment fractions as one proceeded downstream through the urban area. Since the larger sediment fractions are least effected by scour and transport they may best reflect the effect of urbanization on the distribution of heavy metals over an extended period of time at a given location.     

Biodegradability of Quaternized, Crosslinked Sugarcane Bagasse

Quaternized, crosslinked sugarcane bagasse can adsorb anionic dyes from textile wastewater. Disposal of dye-saturated adsorbent by composting or land application would require that modifications made to the bagasse do not interfere with its decomposition. The impact of quaternization and crosslinking on bagasse biodegradability was examined. Bagasse in varying states of modification was mixed with soil and monitored for carbon dioxide evolution for four weeks at 27°C. After subtracting the amount of carbon evolved from control soil samples, the net carbon evolved from the bagasse samples was determined and used as a measure of their extent of biodegradation. Biodegradability decreased in the order: bagasse (approx. 60% degraded after four weeks) > quaternized bagasse > quaternized, epichlorohydrin-crosslinked bagasse > quaternized, methylene-bis-acrylamide-crosslinked bagasse > epichlorohydrin-crosslinked bagasse (less than 5% degraded). Crosslinking severely impacted biodegration, probably by preventing the penetration of (hemi)cellulytic and lignolytic enzymes into the interior of the modified bagasse particles. It is concluded that the biodegradability of quaternized, crosslinked bagasse is too low for composting or land application.     

Pomegranate husk as an adsorbent in the removal of toxic chromium from wastewater

The use of a new sorbent developed from the husk of pomegranate, a famous fruit in Egypt, for the removal of toxic chromium from aqueous solution has been investigated. The batch experiment was conducted to determine the adsorption capacity of the pomegranate husk. The effects of initial metal concentration (25 and 50 mg l^-1), pH, contact time, and sorbent concentration (2-6 g l^-1) have been studied at room temperature. A strong dependence of the adsorption capacity on pH was observed, the capacity increased as the pH decreased, and the optimum pH value was pH 1.0. Adsorption equilibrium and kinetics were studied with different sorbent and metal concentrations. The adsorption process was fast, and equilibrium was reached within 3 h. The maximum removal was 100% for 25 mg l^-1 of Cr⁶⁺ concentration on 5 g l^-1 pomegranate husk concentration, and the maximum adsorption capacity was 10.59 mg g^-1. The kinetic data were analysed using various kinetic models—pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion equations—and the equilibrium data were tested using several isotherm models, Langmuir, Freundlich, Tempkin, Dubinin-Radushkevich, and Generalized isotherm equations. The Elovich and pseudo-second-order equations provided the greatest accuracy for the kinetic data, while Langmuir and Generalized isotherm models were the closest fit for the equilibrium data. The activation energy of sorption has also been evaluated as 0.236 and 0.707 kJ mol^-1 for 25 and 50 mg l^-1 chromium concentration, respectively.