城市间PM2.5源的碳成分谱比较

为了解我国不同城市PM_2.5源的碳成分谱特征和地域差异,采集沈阳市、十堰市和乌鲁木齐市的燃煤源、柴油车尾气源、汽油车尾气源和餐饮源样品,使用热光透射法分析PM_2.5中的总碳（TC）、有机碳（OC）和元素碳（EC）,以及细分的8种碳组分（OC1,OC2,OC3,OC4,EC1,EC2,EC3和OPC_T）,构建各类污染源碳成分谱.结果表明：3个城市4类源TC/PM_2.5从高到低分别为：餐饮源（65.1%±8.4%）、柴油车尾气源（46.2%±9.5%）、汽油车尾气源（37.7%±3.5%）和燃煤源（17.3%±8.0%）;OC/TC在餐饮源中最高（98.0%±0.5%）,EC/TC在柴油车尾气源中最高（38.6%±8.5%）.3个城市同类源的碳组分含量受污染源细分后的不同类型影响有一定差异,但归一化处理后总体仍表现为燃煤源中OC2（14%~30%）和OC3（13%~23%）含量最高,柴油车尾气源中EC2（22%~56%）含量最高,汽油车尾气源中OC2（24%~41%）、OC1（16%~42%）和OC3（12%~26%）含量最高,餐饮源中OC2（21%~43%）和OC3（23%~49%）含量最高.不同污染源的OC/EC值为燃煤源在0.4~7.6之间,柴油车尾气源在0.2~5.6之间,汽油车尾气源在1.1~38.5之间,餐饮源在6.4~170.2之间.分歧系数结果显示3个城市不同源的碳成分谱具有差异性,同类源的碳成分谱具有相似性.将3个城市同类源碳成分谱合并后利用化学质量平衡灵敏度矩阵得到OC2,OC3,OC4,EC1和OPC_T可共同作为燃煤源的标识组分;EC2是柴油车尾气源的标识组分;OC1,OC2和OC3可共同作为汽油车尾气源的标识组分;OC2和OC3可共同作为餐饮源的标识组分.沈阳市、十堰市和乌鲁木齐市相同污染源相似的碳成分谱和一致的标识碳组分可为国内其他城市相关研究提供数据参考.     

水质毒性检测方法的对比研究

随着环境污染加剧,需要在水环境污染物监测方面有一种快速、灵敏、低廉的监测方法,以确保水资源的环境安全。本文选取国内比较常用的五种方法——发光细菌毒性实验法、斑马鱼毒性实验法、大型蚤类毒性实验法、藻类急性毒性实验法、蚕豆根尖微核法,以重铬酸钾（K2Cr2O7）配制成待测溶液测定水质毒性,通过实验比较了各种方法的灵敏性、准确性、可靠性。分析比较了这几种方法的优缺点和研究概况,并对存在的问题给出了建议,为加速国内水质检测应用提供了思路。     

污水处理厂水质在线监测数据可靠性研究

水质在线自动监测系统近年已经开始应用于污水处理厂,在线监测数据的可靠性是污水处理厂推广和应用水质在线监测系统的前提和基础。以广州市某污水厂水质在线监测系统为研究对象,采用对比实验的方法并应用数理统计原理对实验结果进行分析,探讨水质在线监测系统数据的可靠性。经实验及结果分析,污水处理厂水质在线监测系统测得的数据真实可靠,可以用于对污水厂的监督和运行指导。     

连续流动分析仪法快速测定水中挥发酚的研究

通过连续流动分析仪测定水中挥发酚并与传统手工比色法进行一系列的对比实验研究，结果表明连续流动分析仪测定水中挥发酚具有高灵敏度、高精密度、高准确度、分析速度快、不使用大量有机试剂的特点，并且在实际环境样品的分析中也得到了满意的测定结果，能满足大批量的环境样品的快速分析。     

大坝截流前后金沙江观音岩水电站鱼类群落功能多样性的变化

人类活动通过对非生物因素和生物多样性的作用从而对生态系统功能产生了巨大的影响。大量的理论和实验研究表明,物种功能性状在连接群落组成改变和生态系统进程转变中起着重要作用。由于物种功能性状的差异,栖息环境改变后,群落中容易适应新环境的物种占据优势,难以适应的物种数量减少甚至消失,从而导致整个群落结构发生改变,进而使整个生态系统进程发生转变。通过评价金沙江观音岩水电站大坝截流前后鱼类群落组成情况,结合不同种类功能性状的差异,采用生物多样性评估方法和功能多样性指数分析方法两种不同手段,对比分析截流前后大坝下游鱼类群落结构和功能多样性的变化,从而分析大坝建设的生态效应。结果表明:Bray-Curtis相异指数前后差异较大,辛普森指数无明显变化;功能多样性指数的变化表明大坝截流对水体中体型较大,口下位,食谱宽度较窄的鱼类生存和活动造成了一定的破坏,导致拥有这些特征的鱼类数量减少甚至消失,降低了下游鱼类群落的功能多样性,进而对该区域整个生态系统功能产生影响。     

国内外环境空气质量标准对比分析

2012年2月,国务院发布新修订GB 3095-2012《环境空气质量标准》,该标准突显较大的进步,对比美国、欧盟、日本、中国香港等国家、地区和组织现行的环境空气质量标准,结果表明,SO2、CO、NO2、O3、PM10和Pb等仍是各国的重点控制污染项目,PM2.5也已经成为各国重点控制项目;中国新标准中一级标准的污染物浓度限值已接近世界大多数发达国家的控制标准,但二级标准还有很大的空间进行更加严格的修订;中国的环境空气质量标准目前采用分级制度进行管理,阻碍了地区控制污染物的均衡发展,建议逐步取消质量标准分级制度。     

浙江北部一次爆发式发展重度大气污染的气象特点和成因

基于全国空气质量指数和PM_(2.5)监测、常规气象观测、浙江省6种主要大气污染物和自动气象监测、宁波镇海激光雷达、美国国家环境预报中心GDAS和欧洲中期天气预报中心ERA-interim再分析等多种资料,对2017年12月30日―2018年1月1日浙江北部一次爆发式发展大气污染事件气象特点及成因进行分析,应用HYSPLIT4模式进行粒子后向轨迹分析.结果表明:PM_(10)和PM_(2.5)质量浓度在浙江省表现出明显的爆发性增长和自西北向东南传输的特征,污染程度自浙北向浙中、浙南逐渐减轻,重度污染时浙北大范围出现2000 m以下的重度霾,污染粒子主要来自上游的安徽和江苏省.大气污染爆发式发展与冷空气有关,1000 m以下边界层内冷空气偏弱,但足以将盛行风改变为西北风,是污染物粒子输送的动力条件,污染粒子集中在该层内,层内没有下沉运动,因此水平风场对污染事件爆发有决定性作用;1000 m以上层次冷平流表现明显,且伴有下沉运动,抑制了边界层粒子的垂直扩散,对污染事件的发展和维持有间接影响.激光雷达的消光系数变化不仅与污染物粒子浓度变化有关,还与气象条件密切相关.污染物粒子质量浓度通量散度的变化对预报粒子浓度的增减有较好的参考作用.     

Fate of pharmaceuticals--photodegradation by simulated solar UV-light

The fate of pharmaceuticals in surface waters under solar irradiation was investigated. Photodegradation of pharmaceuticals caused by sun irradiation may be of major significance in the natural elimination process. Based on a data compilation from the literature, the lipid lowering agent metabolite clofibric acid, the iodinated X-ray contrast media iomeprol, which contribute to the adsorbable organic halogen compounds, and the antiepileptic drug carbamazepine were selected. The irradiation experiments were carried out in batch experiments with simulated UV–sunlight. The photodegradation of the pharmaceuticals showed a pseudo-first-order kinetics. The objective of this investigation was to demonstrate that the extent of photoinduced degradation of pharmaceuticals can vary significantly for the different pharmaceuticals and it strongly depends on the water constituents present in solution. The influences of different initial pharmaceutical concentrations, the presence of other pharmaceuticals like carbamazepine or clofibric acid and the presence of natural organic matter on the photochemical degradation rate of pharmaceuticals in aqueous solutions were investigated. Analyses of the pharmaceuticals and their photodegradation products were carried out by high performance liquid chromatography with diode-array and fluorescence detection.     

渭河上游两次致洪暴雨过程的对比分析

对渭河支流上游两次致洪暴雨过程进行了对比分析,结果表明:在泾河上游,两次大暴雨的落区相差在100km以内;两次暴雨过程均给当地和渭河下游造成了严重的洪涝灾害;洪水过程的洪峰特点分别属于缓型洪水和陡型洪水;500hPa天气分型虽然一次为西南气流型,一次为西风槽型,但700hPa的直接影响系统基本相同.物理量诊断对比分析表明:在暴雨出现前12h,低层辐合、高层辐散的垂直结构已基本形成,到暴雨出现临近辐合辐散迅速加强,为暴雨形成和维持提供了非常有利的动力条件.     

Risk assessment of an oil depot using the improved multi-sensor fusion approach based on the cloud model and the belief Jensen-Shannon divergence

At present, enterprises have introduced the Internet of Things (IoT) technology to monitor and evaluate the safety status of oil depots, allowing for the collection of a substantial amount of multi-source monitoring data from factories. However, sensor monitoring data is often inaccurate and fuzzy. To improve the reliability of risk prevention and control based on multi-source sensor data, this study proposed a CM-BJS-DS model based on the cloud model (CM), the Belief Jensen-Shannon (BJS) divergence and Dempster-Shafer(D-S) evidence theory. First, the relevant evaluation factors of the accident and their threshold intervals of different risk levels were determined, and the fuzzy cloud membership functions (FCMFs) corresponding to different risk levels were constructed. Then, the sensor monitoring data were processed using the correlation measurement of the FCMF, and basic probability assignments (BPAs) were generated under the risk assessment frame of discernment. Finally, the BPAs were pre-processed by the improved evidence fusion model and the accident risk level was evaluated. Based on the monitoring data, a case study was performed to assess the risk level of vapor cloud explosion (VCE) accidents due to liquid petroleum gas (LPG) tank leaks. The results show that the proposed method presents the following characteristics: (i) The BPAs were constructed based on the monitoring data, which reduced the subjectivity of the construction process; (ii) Compared with single sensors, the multiple sensor fusion evaluation yielded more specific results; (iii) When dealing with highly conflicting evidence, the evaluation results of the proposed method exhibited a higher belief degree. This method can be used as a decision-making tool to detect potential risks and identify critical risk spots to improve the specificity and efficiency of emergency response.