Land-based sources of marine pollution: organochlorine pesticides in stream systems

BACKGROUND: Organochlorine pesticides (OCPs) have been dispersed ubiquitously in the environment. Bottom sediments act as sinks for these compounds and their concentrations often reflect the degree of anthropogenic pollution. This study was designed to evaluate the occurrence and distribution of OCPs in superficial streambed sediments and their relation to land use in two creeks that contribute to the coastal pollution of the southeastern region of Argentina. METHODS: Sampling sites were selected by a combination of land use and stream type. Las Brusquitas creek, which passes through vast agricultural areas, and La Tapera creek which originates in a natural wetland and passes through horticultural farming and urban areas. OCPs quantification was carried out by GC-ECD. RESULTS AND DISCUSSION: Results showed similar total OCP concentrations in sediments from both creeks in the range of 6-25 ng/g dry wt. However, when OCPs were expressed in ng/g total organic carbon (TOC), La Tapera creek presented 4-fold higher total levels as a consequence of a higher OCP input during the recent past in that watershed. La Tapera outfall showed 4-fold higher levels than that seen in Las Brusquitas, although both values were below the sediment quality criteria demanded to protect wildlife. Sigmaendosulfans, sigmaDDTs and sigmachlordanes were the main OCP group in all samples, with Endosulfan sulfate being the most frequent and abundant compound. The predominance of metabolites with respect to parent compounds suggests a contamination mainly by runoff from aged and weathered agricultural soils. CONCLUSIONS: Despite OCPs being banned, they still exist in creek sediments from the studied region, representing continuous contributions of land-based source contaminants to the marine environment. OUTLOOK: Future research on OCP levels in suspended sediments is recommended in order to determine the total OCP concentrations in the selected stream systems.     

A Knowledge-Based Approach to the Assessment of Watershed Condition

The Ecosystem Management Decision Support (EMDS) system is an application framework for knowledge-based decision support of ecological assessments. EMDS integrates geographic information system and knowledge base system technologies to provide an analytical tool for environmental assessment and monitoring. The basic objective of EMDS is to improve the quality and completeness of environmental assessments and the efficiency with which they are performed. The USDA Forest Service and the U.S. Environmental Protection Agency have cooperatively developed an EMDS knowledge base for watershed condition assessment. Specifically, this knowledge base evaluates watershed processes, patterns, general effects of human activity, and fisheries habitat suitability. Such assessments are based on spatially explicit input data concerning current conditions and reference conditions which are subsequently interpreted by user-defined "fuzzy" membership functions. In this paper we describe basic components of our knowledge base for assessing watershed condition and illustrate its application within northern Idaho and northwestern Montana.     

Prospects and Constraints of Desert Agriculture: Lessons from West Omdurman

Sudan is the largest country in Africa with an area of about 2.5 million km²; the country hosts a population of about 31 million people. About two-thirds of the country area is located within arid and semi-arid regions. Recently, especially during the last half of the previous century, these regions were subject to various forms of land degradation. This paper discusses the general prospects and constraints of desert agriculture. It also presents a detailed case study of West Omdurman, which is located in a semi-desert climatic zone. The ambitious plans to utilise the area for agricultural production were initiated because of the relatively fertile soil, availability of water and the proximity of the area to marketing and export centres. The paper discusses the different land use systems experienced in the area, reasons for failure are identified and possible remedies discussed. In addition, constraints facing the proposed West Omdurman Canal Project are also discussed. Finally, the paper reviews the major research findings of Rawakeeb Dryland Research Center with regard to promoting agricultural productivity.     

Monitoring Long-Term Ecological Changes Through the Ecological Monitoring and Assessment Network: Science-Based and Policy Relevant

Ecological monitoring and its associated research programshave often provided answers to various environmental management issues. In the face of changing environmental conditions, ecological monitoring provides decision-makers with reliable information as they grapple with maintaining a sustainable economy and healthy environment. The EcologicalMonitoring and Assessment Network (EMAN) is a national ecological monitoring network consisting of (1) about 100 casestudy sites across the country characterized by long-term multi-disciplinary environmental work conducted by a multitudeof agencies (142 partners and counting); (2) a variety of lesscomprehensive yet more extensive monitoring sites; (3) a network where core monitoring variables of ecosystem change aremeasured; and (4) geo-referenced environmental observations. Environment Canada is the co-ordinating partner for the network through the EMAN Co-ordinating Office. EMAN's mission is to focus a scientifically-sound, policy-relevant ecosystem monitoring and research network based on (a) stabilizing a network of case-study sites operated by a varietyof partners, and (b) developing a number of cooperative dispersedmonitoring initiatives in order to deliver unique and needed goods and services. These goods and services include: (1) an efficient and cost-effective early warning system which detects,describes and reports on changes in Canadian ecosystems at a national or ecozone scale; and (2) cross-disciplinary and cross-jurisdictional assessments of ecosystem status, trends and processes. The early warning system and assessments of ecosystem status, trends and processes provide Environment Canada and partner organizations with timely information thatfacilitates increasingly adaptive policies and priority setting. Canadians are also informed of changes and trends occurring in Canadian ecosystems and, as a result, are betterable to make decisions related to conservation and sustainability.     

Linking on-farm dairy management practices to storm-flow fecal coliform loading for California coastal watersheds

How and where to improve water quality within an agricultural watershed requires data at a spatial scale that corresponds with individual management decision units on an agricultural operation. This is particularly true in the context of water quality regulations, such as Total Maximum Daily Loads (TMDLs), that identify agriculture as one source of non-point source pollution through larger tributary watershed scale and above and below water quality investigations. We have conducted a systems approach study of 10 coastal dairies and ranches to document fecal coliform concentration and loading to surface waters at the management decision unit scale. Water quality samples were collected on a storm event basis from loading units that included: manure management systems; gutters; storm drains; pastures; and corrals and lots. In addition, in-stream samples were collected above and below the dairy facilities and from a control watershed, managed for light grazing and without a dairy facility or human residence and corresponding septic system. Samples were analyzed for fecal coliform concentration by membrane filtration. Instantaneous discharge was measured for each collected sample. Storm runoff was also calculated using the curve number method (SCS, 1985). Results for a representative dairy as well as the entire 10 dairy data set are presented. Fecal coliform concentrations demonstrate high variability both within and between loading units. Fecal coliform concentrations for pastures range from 206 to 2,288,888 cfu/100 ml and for lots from 1,933 to 166,105,000 cfu/100 ml. Mean concentrations for pastures and lots are 121,298 (SE=62,222) and 3,155,584 (SE=1,902,713) cfu/100 ml, respectively. Fecal coliform load from units of concentrated animals and manure are significantly more than units such as pastures while storm flow amounts were significantly less. Compared with results from earlier tributary scale studies in the watershed, this systems approach has generatedwater quality data that is beneficial for management decisions because of its scale and representation of current management activities. These results are facilitating on-farm changes through the cooperative efforts of dairy managers, regulatory agency staff, and sources of technical and financial assistance.     

极谱法测定海水中的镉、铅含量

利用极谱二电极系统测定海水中的镉、铅，测定结果的精密度、准确度均符合分析要求。     

Continuous integration in urban social-ecological systems science needs to allow for spacing co-existence: This article belongs to Ambio’s 50th Anniversary Collection. Theme: Urbanization

Urbanization brings benefits and burdens to both humans and nature. Cities are key systems for integrated social-ecological research and the interdisciplinary journal of Ambio has published ground-breaking contributions in this field. This reflection piece identifies and discusses integration of the human and natural spheres in urban social-ecological research using the following foundational papers as important milestones: Folke et al. (1997), Ernstson et al. (2010) and Andersson et al. (2014). These papers each take unique approaches that aim to uncover core properties—processes, structures, and actors—of urban systems and set them into mutual relationship. This piece will end with a forward-looking vision for the coming 50 years of urban sustainability and resilience study in Ambio.     

Long-range transport potential of semivolatile organic chemicals in coupled air-water systems

Ongoing deliberations on the regulation of semivolatile organic chemicals require the assessment of chemical transport in atmospheric and marine systems. The characteristic travel distance was proposed as a measure for the transport potential in air and water. However, the existing definition treats the transport processes separately. It is shown that combined transport in coupled air-ocean systems can accelerate the overall transport into remote regions. Concentration ratios in air and water change with distance from sources depending on the initial concentration ratio and on the difference between the transport velocities. A measure is suggested facilitating the chemical screening with respect to transport potentials in such air-ocean systems. A case study for alpha and gamma-hexachlorocyclohexane shows that the suggested measure qualitatively reveals the transport potentials of these chemicals and exemplifies possible concentration patterns.     

INTERPRETATION OF THE DUAL PROGRAM FOR OPTIMAL GROUNDWATER HYDRAULIC CONTROL1

ABSTRACT: Optimization formulations for hydraulic control that take the form of linear programs possess a corresponding dual linear program. The economic and physical interpretations of the dual linear program are examined for formulations in which hydraulic head in groundwater systems is constiained. In each case it is shown that the dual linear program has a physically meaningful interpretation. For a hydraulic gradient control formulation used for remedial analysis it is shown that the dual variable can be interpreted as the remedial benefit due to each gradient control constraint. The dual linear program maximizes the remedial benefit. The value of the dual variable can be used to compute such useful properties as the total remedial benefit of pumping at a specific location. For a formulation that optimizes aquifer yield while constraining drawdown the dual variable can be used to measure the total cost of drawdown capacity consumption per unit of pumping at a specific location. The dual program minimizes the cost of drawdown capacity consumption. By examining the meaning of the dual linear program an alternate statement of the problem under study is revealed. Quantities arising from the dual program add to the value of the optimization approach. Significant new information can be derived from existing linear optimization formulations with minimal additional computational effort.     

Safety rules: procedural freedom or action constraint?

The paper presents a partial classification of safety rules as constraints imposed from outside on the freedom of choice of individuals or companies. The classification is linked to the Reason model of skill-, rule-, and knowledge-based behaviour. The imposition of constraints is related to a number of criteria concerning the context and use of the rules to arrive at proposals for when and where to apply what type of rule. To illustrate the principles discussed an example is given of the rule from the Dutch Working Environment legislation concerning the requirement to use “current state of the art in prevention” in companies. The paper proposes providing procedural rule support to companies on how to meet the rule, in the form of a data bank of practicable solutions to health and safety problems.