DPX快速萃取程序升温大体积进样GC/MS法测定水中19种多溴联苯化合物

建立DPX快速吸附萃取、程序升温(PTV)大体积进样与气相色谱/质谱(GC/MS)联用,SIM模式同时测定水中19种多溴联苯(PBBs)单体的方法。该方法在PBBs质量浓度1~50μg/L范围内线性良好,19种PBBs单体检出限为0.147~0.230μg/L,相对标准偏差为6.61%~10.5%,加标回收率为61.5%~82.6%。     

Optimal Expansion Strategy for a Sewer System under Uncertainty

Because of fast urban sprawl, land use competition, and the gap in available funds and needed funds, municipal decision makers and planners are looking for more cost-effective and sustainable ways to improve their sewer infrastructure systems. The dominant approaches have turned to planning the sanitary sewer systems within a regional context, while the decentralized and on-site/cluster wastewater systems have not overcome the application barriers. But regionalization policy confers uncertainties and risks upon cities while planning for future events. Following the philosophy of smart growth, this paper presents several optimal expansion schemes for a fast-growing city in the US/Mexico borderlands—the city of Pharr in Texas under uncertainty. The waste stream generated in Pharr is divided into three distinct sewer sheds within the city limit, including south region, central region, and north region. The options available include routing the wastewater to a neighboring municipality (i.e., McAllen) for treatment and reuse, expanding the existing wastewater treatment plant (WWTP) in the south sewer shed, and constructing a new WWTP in the north sewer shed. Traditional deterministic least-cost optimization applied in the first stage can provide a cost-effective and technology-based decision without respect to associated uncertainties system wide. As the model is primarily driven by the fees charged for wastewater transfer, sensitivity analysis was emphasized by the inclusion of varying flat-rate fees for adjustable transfer schemes before contracting process that may support the assessment of fiscal benefits to all parties involved. Yet uncertainties might arise from wastewater generation, wastewater reuse, and cost increase in constructing and operating the new wastewater treatment plant simultaneously. When dealing with multiple sources of uncertainty, the grey mixed integer programming (GIP) model, formulated in the second stage, can further allow all sources of uncertainties to propagate throughout the optimization context, simultaneously leading to determine a wealth of optimal decisions within a reasonable range. Both models ran for three 5-year periods beginning in 2005 and ending in 2020. The dynamic outputs of this analysis reflect the systematic concerns about integrative uncertainties within this decision analysis, which enable decision makers and stakeholders to make all-inclusive decisions for sanitary sewer system expansion in an economically growing region.     

Multi-stand Forest Management under a Climatic Risk: Do Time and Risk Preferences Matter?

We propose a stochastic dynamic programming framework to model the management of a multi-stand forest under climate risk (strong wind occurrence). The preferences of the forest-owner are specified by a non-expected utility in order to separately analyze intertemporal substitution and risk aversion effects. A numerical method is developed to characterize the optimal forest management policies and the optimal consumption-saving strategy. The stochastic dynamic programming framework is applied to a non-industrial private forest-owner located in North-East of France. We show that the optimal decisions both depend upon risk and time preferences. The authors would like to thank participants at the international conference on Economics of Sustainable Forest Management in Toronto, at the PARIS 1 seminar on Environmental and Natural Resource Economics, at the 2004 Applied Microeconomics Conference in Lille and at the 13th annual conference of the European Association of Environmental and Resource Economists at Budapest.     

A Model for Landscape Planning Under Complex Spatial Conditions

We present a new mathematical programming framework that is adaptable to a variety of spatially explicit landscape problems in environmental investment, conservation, and land-use planning, transport planning, and agriculture. As part of capturing spatial interdependencies, the framework considers decision variables at two levels, finely spaced grid cells and landholdings. We applied the framework to an environmental investment problem using objective functions representing biodiversity and carbon sequestration. We also tested the model to optimize the path of a road through part of the landscape. Using the Nambucca case study in eastern Australia, we applied a hybrid greedy randomised adaptive search procedure (GRASP) to find solutions to the model.     

剑麻纤维基多孔炭材料的制备及其吸附氯苯的研究

以剑麻纤维为原料,通过简易的一步炭化活化法制备了一系列多孔炭材料,分别探究了3种温和的金属盐活化剂、活化剂与剑麻纤维的质量比和活化温度对炭材料的氯苯吸附量的影响,并通过BET、SEM、XRD、Raman、FT-IR、元素分析等手段表征其物理化学性质.结果表明,当采用CuCl₂为活化剂、CuCl₂与剑麻纤维的质量比为10∶1及活化温度为800℃时,制备得到的剑麻纤维基多孔炭(PCC)吸附性能最佳,其在氯苯浓度为1560 mg·m^-3时,吸附量达到856 mg·g^-1,而未经CuCl₂活化的炭材料(PC)的氯苯吸附量仅为15 mg·g^-1.氯苯吸附性能的提升主要归因于比表面积、孔容、无序性和表面含氧官能团的增加.此外,采用巨正则系综蒙特卡洛(GCMC)方法模拟氯苯分子在制备的多孔炭材料中的吸附行为,结果表明,该材料中孔径为0.5 nm的孔对氯苯分子的吸附能力最强,且对氯苯吸附起主导作用的为苯环中心和Cl原子与炭材料上连接含氧官能团的H原子之间的静电作用力.     

交通事故动态分析法在肇事逃逸案件侦查中的研究与实践

针对传统交通事故动态分析法在交通肇事逃逸案件侦查中投入高、效率低、精度差的缺点,笔者在信息主导警务理念的指导下,综合运用逻辑学、系统科学、社会学、心理学、情报科学相关原理,动态分析交通事故现场的痕迹、车辆行驶轨迹、道路交通环境、警情综合信息、驾驶人行为与逃逸心理,以及受害者损伤特征,准确掌握车辆或驾驶人局部特征,从而为侦破交通肇事逃逸案件提供精确的查缉信息,使警务行动实现精确用警、快速反应和精确打击的目标。笔者给出了利用动态分析法侦破交通肇事逃逸案件的流程和步骤;指出提高办案水平,迫切需要加强警务信息和社会信息的有效融合,研发专门系统,强化信息研判。     

COMPARISON OF RESERVOIR LINEAR OPERATION RULES USING LINEAR AND DYNAMIC PROGRAMMING1

ABSTRACT: Mathematical optimization techniques are used to study the operation and design of a single, multi-purpose reservoir system. Optimal monthly release policies are derived for Hoover Reservoir, located in Central Ohio, using chance-constrained linear programming and dynamic programming-regression methodologies. Important characteristics of the former approach are derived, discussed, and graphically illustrated using Hoover Reservoir as a case example. Simulation procedures are used to examine and compare the overall performance of the optimal monthly reservoir release policies derived under the two approaches. Results indicate that, for the mean detention time and the corresponding safe yield target water supply release under existing design of Hoover Reservoir, the dynamic programming policies produce lower average annual losses (as defined by a two-sided quadratic loss function) while achieving at least as high reliability levels when compared to policies derived under the chance-constrained linear programming method. In making this comparison, the reservoir release policies, although not identical, are assumed to be linear. This restricted form of the release policy is necessary to make the chance-constrained programming method mathematically tractable.     

MULTICRITERION ANALYSIS OF FOREST WATERSHED MANAGEMENT ALTERNATIVES1

ABSTRACT: The impacts of alternative forest watershed management practices are examined from a multicriterion viewpoint in order to select the most satisfactory management scheme. The selection process is carried out using two types of multicriterion decision making techniques: the outranking types of ELECTRE I and II, and the distance-based type of compromise programming (CP). The process is illustrated using the U.S. Forest Service Beaver Creek Experimental Watershed in the Salt-Verde River Basin of Arizona as an example. The desired objectives of the experimental study and the alternative forest watershed resources management schemes are transformed into an evaluation matrix of alternatives versus criteria array. Analyses of the matrix using the aforementioned techniques result in a complete preference ordering of the feasible alternatives in the cases of ELECTRE LI and CP and a partial ordering when ELECTRE I is used. In addition, some sensitivity analyses have been performed and showed ELECTRE II and CP to be fairly robust with respect to parameter changes, while ELECTRE I being highly sensitive to changes in threshold levels. Overall the three techniques pointed out that 65 percent vegetation cut is the best management scheme, while the next best is shown to be 50 percent vegetation cut.     

WATER POLICIES FOR ENERGY DEVELOPMENT1

ABSTRACF: Examination of a series of studies of the economically efficient water allocations in the Upper Colorado River, Yellowstone River, and Great Basins indicate that water is not a serious general physical constraint on the development of energy resources, so long as public institutions do not hinder the exchange of water rights in markets. Energy development will cause limited impacts on other water-using sectors, principally agriculture. There appears to be little reason to develop large-scale water storage facilities, even during periods of reduced water production. Water storage developments appear to be necessary only when institutional constraints severely restrict water rights markets and transfers.