Enhanced cyanogen chloride formation after UV/PS and UV/H2O2 pre-oxidation and chlorination in natural river water

Ultraviolet/persulfate (UV/PS) and Ultraviolet/hydrogen peroxide (UV/H₂O₂) have attracted much attention in recent years as advanced oxidation processes for water treatment. However, it is not all clear how these two methods affect the formation of cyanogen chloride (CNCl) in the subsequent water chlorination process. In this study, it was found that both UV/H₂O₂ and UV/PS pre-oxidation promoted the formation of CNCl in six actual water samples collected from urban rivers. Glycine, uric acid, arginine and histidine were investigated as the model compounds to explore the effects of different methods on the production of CNCl. The results showed that compared with chlorination alone, pre-oxidation by UV/H₂O₂ and UV/PS can reduce the production of CNCl for glycine and uric acid by up to 95% during post-chlorination process. However, they can greatly promote the formation of CNCl for arginine and histidine by up to 120-fold. In a more detailed investigation, pre-oxidation of histidine formed highly reactive intermediates to chlorine, leading to increased CNCl formation and chlorine consumption. The results showed that the precursors of CNCl was altered after pre-oxidation, and need to be re-evaluated.     

气相色谱法测定二硫化碳和甲硫醚

利用气相色谱(配火焰光度检测器,采用3mxφ2mm玻璃填充柱分离)对CS2和甲硫醚(DMS)两种含硫化合物进行了分离检测。该方法具有较高的灵敏度和良好的线性关系。结果表明:该分析对含硫气体的最小检测浓度在mg/m3级,在柱温为70℃,检测器温度为180℃,气化室温度为150℃,氮气流速为50mL/min时,CS2的回收率为98.66%,变异系数为2.12%;甲硫醚的回收率为98.66%,变异系数为1.56%。     

脉冲电晕等离子体脱硫脱氮与除尘技术

脉冲电晕放电是产生等离子体的方法之一，目前已达到工业性试验阶段，该文对脉冲电晕等离子脱硫脱氮与除尘技术的形成过程进行了回顾，对其理论作了分析，并简介了工艺流程，还指出了目前存在的主要问题和需研究的关键技术。     

Developing Canada's National Forest Carbon Monitoring, Accounting and Reporting System to Meet the Reporting Requirements of the Kyoto Protocol

The rate of carbon accumulation in the atmosphere can be reduced by decreasing emissions from the burning of fossil fuels and by increasing the net uptake (or reducing the net loss) of carbon in terrestrial (and aquatic) ecosystems. The Kyoto Protocol addresses both the release and uptake of carbon. Canada is developing a National Forest Carbon Monitoring, Accounting and Reporting System in support of its international obligations to report greenhouse gas sources and sinks. This system employs forest-inventory data, growth and yield information, and statistics on natural disturbances, management actions and land-use change to estimate forest carbon stocks, changes in carbon stocks, and emissions of non-CO₂ greenhouse gases. A key component of the system is the Carbon Budget Model of the Canadian Forest Sector (CBM-CFS). The model is undergoing extensive revisions to enable analyses at four spatial scales (national, provincial, forest management unit and stand) and in annual time steps. The model and the supporting databases can be used to assess carbon-stock changes between 1990 and the present, and to predict future carbon-stock changes based on scenarios of future disturbance rates and management actions.     

沸石在水处理中的应用

本文介绍了中国沸石的种类及其分布概况，以产自甘肃省白银市的斜发沸石为研究对象，对其化学组成及分子晶格形式作了较为详尽的阐述，经实验室检测出其化学组成及物化指标，且对沸石作为吸附剂、离子交换剂、催化剂处理废水的作用机理进行了深入的探讨，对于天然沸石改性进行了实验研究，得出采用氯化钠溶液对天然沸石改性的效果比较理想，改性溶液的最佳浓度为0．9mol/L。研究沸石在沸水处理领域中的应用，分析了沸石处理各类废水的机理，并对沸石处理废水的前景进行了展望。     

Carbon Dioxide Balance of Wood Substitution: Comparing Concrete- and Wood-Framed Buildings

In this study a method is suggested to compare the net carbon dioxide (CO₂) emission from the construction of concrete- and wood-framed buildings. The method is then applied to two buildings in Sweden and Finland constructed with wood frames, compared with functionally equivalent buildings constructed with concrete frames. Carbon accounting includes: emissions due to fossil fuel use in the production of building materials; the replacement of fossil fuels by biomass residues from logging, wood processing, construction and demolition; carbon stock changes in forests and buildings; and cement process reactions. The results show that wood-framed construction requires less energy, and emits less CO₂ to the atmosphere, than concrete-framed construction. The lifecycle emission difference between the wood- and concrete-framed buildings ranges from 30 to 130 kg C per m² of floor area. Hence, a net reduction of CO₂ emission can be obtained by increasing the proportion of wood-based building materials, relative to concrete materials. The benefits would be greatest if the biomass residues resulting from the production of the wood building materials were fully used in energy supply systems. The carbon mitigation efficiency, expressed in terms of biomass used per unit of reduced carbon emission, is considerably better if the wood is used to replace concrete building material than if the wood is used directly as biofuel.     

采取多种手段综合整治圆明园防渗工程

圆明园是北京市享誉中外的世界文化遗产公园，园内有140hm^2湖面，因湖水渗漏严重，每年要进行大量补水。为此圆明园管理处投资数千万，进行了湖底铺膜防渗工程，2005年4月份，接近完工的防渗工程被国家环保总局紧急停止。该项工程如何走出困境，本文从湖底开孔建渗水井，引进中水，以及湖水活化等多方面，提出一些合理化建议，希望以此构建一个水资源节约利用，而且可持续发展的湖区水生生态系统和一个和谐的园区人文景观。     

聚合氯化铝铁检验方法研究

聚合氯化铝铁是一种新型净水剂,它结合铝系和铁系净水剂的优点,有助于减少水中铅含量。利用《水处理剂聚合氯化铅(GB15892-1995)》和《净化剂聚合氯化铁(GB14591-93)》的方法,对聚合氯化铅铁主要技术指标的检验做了探索。经反复实验,取得了较好的效果。     

黄陵至延安高速公路k295+750-k296+050段滑坡稳定性分析与治理

在介绍黄陵至延安高速公路k295+750～k296+050滑坡工程地质情况的基础上,对滑坡的成因和机制进行了分析,并且进行了稳定性计算与评价。最后结合工程实际特点提出了以路肩挡墙作为支挡工程,并辅以刷方减重和地表排水相结合的合理处治方案。     

On-line optical determination of floc size of Fe(Ⅲ) coagulants

This study investigated the floc aggregation, average floc size, floc size variance and floc growth velocity when ferric chloride （FeCl3） and polyferric chloride （PFC） were used to treat the simulated water samples. The factors including coagulant dose, ionic strength and solution pH, which affect the floc aggregation, were studied. Experiments were carried out in a bench-scale reactor using photometric dispersion analyzer （ PDA）. Results showed that there were great differences between the floc aggregation of PFC and FeCl3. The average floc size and fioc growth velocity of PFC were much larger than those of FeCl3. Compared with FeCl3, PFC gave a better coagulation performance in wider range of pH, dosage and ionic strength. It was also found that the coagulation efficiency of PFC did not depend on average floc size but on floc growth velocity.