新型溴系阻燃剂环境污染现状研究进展

新型溴系阻燃剂(NBFRs,novel brominated flame retardants)作为传统溴系阻燃剂的替代品已广泛应用于电子产品、纺织品、家具等商品中,随着这些商品的生产、使用和处置,NBFRs不可避免地释放到环境中,给环境和人体带来潜在的危害.部分NBFRs可通过摄食和呼吸作用进入人体对人体产生一定危害...     

四溴双酚A在土壤中的降解转化及残留研究进展

四溴双酚A(tetrabromobisphenol A,TBBPA)是全球生产量最大的溴代阻燃剂,广泛应用于电子产品和塑料等高分子材料的生产中.由于高的亲脂性及环境稳定性,TBBPA在土壤中易于累积.土壤作为污染物主要的汇之一,污染物在土壤中的环境过程和归趋对正确评价污染物的环境风险至关重要.本文综述了土壤中TBBPA...     

球形障碍物对瓦斯爆燃火焰影响试验研究

为进一步开发煤矿井下瓦斯爆炸事故的隔抑爆技术装备,利用截面为0.2 m×0.2 m的方形管道、纹影仪和高速摄像机,开展无障碍物时和球形障碍物存在情况下的瓦斯爆燃传播试验.研究发现,无障碍物时,密闭管道内爆燃火焰的结构和传播速度受反射压力波的影响很大,湍流火焰、化学反应作用能力与反射压力波的相互作用是造成火焰传播速度变化...     

氢氧化镁/红磷对硅橡胶/黏土纳米复合物阻燃性能的研究

选用甲基乙烯基硅橡胶(MVMQ)和十六烷基三甲基溴化铵(C16BrN)改性的蒙脱土(OMMT)纳米复合材料为原料,以氢氧化镁/微胶囊化红磷(MH/MRP)为阻燃剂,以气相法白炭黑为补强剂,用熔融共混法制备了无卤阻燃MVMQ纳米复合材料。笔者采用XRD表征制备的MVMQ/OMMT纳米复合物的结构,用机械性能测试研究气相法白炭黑和OMMT对MVMQ的协效补强作用,通过极限氧指数、UL94 V垂直燃烧法、环境扫描电镜(ESEM)和热重分析(TG)等分析测试手段研究其燃烧性能和热性能,结合材料宏观燃烧性能的改变,推断OMMT和MH/MRP对MVMQ的阻燃作用机理。     

鄱阳湖枯水水位及流速时空分布模拟

大型通江湖泊鄱阳湖水文节律独特,水位和流速是其生态系统功能维持的关键因子。为探究其水位和流速时空特征,基于EFDC(Environmental Fluid Dynamics Code)模型,利用五河及湖口水文数据、气象数据及湖底高程作为输入条件,模拟出鄱阳湖的枯水水文统计年(2010-07-01~2011-06-30)水位和流速时空变化过程。模拟结果表明:(1)星子等4个站点拟合程度较好(r20.85),达到了复杂湖库水动力模拟的精度。(2)高水位期,湖区水位空间分布无明显差异,水深直接受湖底高程影响,自上游至下游呈逐级递增;低水位期,鄱阳湖水位在空间上出现明显差异,湖区外缘水位至入江水道逐级递减,水深分布空间差异不大,仅入江水道处水深明显高于其他水域。(3)流速也包括一系列时空变化特征,如高水位时期流速小于低水位时期;除大水面时期外,深水道流速大于主湖区;高水位时期上游流速略高于下游,但其他月份,北部入江水道流速均大于南部湖区等。(4)流速与水位关系密切,且不同水位对应流速大小及分布有所差异。鄱阳湖枯水水位和流速模拟分析可为大型湖库枯水水情管理提供科学参考和辅助决策支持。     

Remove cooking fume using catalytic combustion over Pt/La-Al2O3

Five monolithic catalysts with low noble metal content were prepared by irnmerge method （Pt/γ=Al2O3, Pt/La-Al2O3, Pt/YSZ-AI203, Pt＋Pd/La-Al2O3 and Pd/La-Al2O3） and their activity measurements were carried out in a conventional fixed-bed flow reactor. The results show that La-Al2O3 can promote activity of the prepared catalysts and can decrease the complete conversion temperature of cooking fume. The Pt/La-Al2O3 catalyst has the highest activity and can be applied in wide range of gas hourly space velocity （GHSV）. Some characterizations （XRD, TPR） were carried out with the objective to explain differences in catalytic behaviors. The prepared catalyst showed a great potential for application.     

Environmental impacts and use of brominated flame retardants in electrical and electronic equipment

Management of waste electrical and electronic equipment (WEEE) or e-waste is becoming a major issue as around 20–50 million tons of such waste is generated worldwide and increasing at a higher rate than other solid waste streams. Electrical and electronic equipment (EEE) contains over 1,000 materials of which brominated flame retardants (BFRs) such as polybrominated biphenyls (PBBs) and polybrominated diphenyl ethers (PBDEs) have been the target of the regulators forcing manufacturers to adopt halogen-free flame retardants. As far as these alternatives are concerned, key consideration should be its performance during the whole life cycle through design, use and end-of-life management. The global halogen-free flame retardant movement has reached a point of no return. The most important issue as far as the environment is concerned, for which the transformation to halogen-free retardants was initially targeted, is to make sure that life span of the EEE using the alternatives to BFRs is not shortened thereby resulting in unforeseen increases in e-waste to deal with. The aim of this article is to investigate the environmental issues and current developments related to the use of BFRs in EEE manufacture. It describes the sources, toxicity and human exposure of BFRs, EOL management such as recycling and thermal treatments, exposure of BFRs from e-waste processing facilities and the environment around them and examines the developments and feasibility of the alternatives to BFR in EEE manufacture.     

速度场常数及其自动检测装置

通过对烟道“速度场常数”的研究,提出利用速度场常数监测烟道烟气平均流速的方法,同时研制出速度场常数自动检测装置。解决烟道烟气平均流速自动监测的技术难题。     

Carrousel氧化沟单个表曝机流态的模型试验和分析比较

对仅安装1个倒伞形表面曝气机(简称表曝机)的Carrousel氧化沟模型进行了水力学测定,通过颗粒动态分析仪(PDA)系统分析流出和流入表曝机一侧的液体流动速度、沉降速度,以及固体含量分布.结果表明,流出表曝机一侧,距表曝机较近的x轴位置流速较大;沉降速度沿y轴有个转折点,位于沟壁与挡板的中间;远离单个表曝机,固体含量逐渐增大.并将单个表曝机的测量结果与氧化沟内安装2个表曝机的流动试验进行比较,发现2个表曝机所产生的流场与单个表曝机产生的流场差别较大,且2个表曝机所产生的流场更稳定.      

袋式除尘用滤料集尘性能的冷态测定及分析

对袋式除尘常用的针刺毡、基布覆膜、梯度针刺毡三类滤料进行集尘状况下压力损失冷态实验测试。结果表明:清洁滤料压力损失由大到小分别为基布覆膜滤料、梯度针刺毡、常规针刺毡;清洁滤料的压力损失与过滤速度呈正比线性变化关系,集尘后与过滤时间、粉尘负荷呈正比二次方变化关系,并通过分析给出滤料在不同集尘负荷下阻力与过滤风速、粉尘负荷间的计算关系。