引入化学反应的600MW机组SCR脱硝系统模拟

以600MW火电机组SCR脱硝装置为研究对象,应用CFD软件完成建立模型、划分网格、选择数学模型、设置边界条件、模拟计算等工作,最终得出SCR脱硝系统流速分布及Cv值、压力损失、NH3分布及逃逸浓度等结果。结果表明,SCR脱硝系统流速分布均匀、偏差符合设计要求,NH3与烟气混合均匀,氨逃逸浓度低。     

端部开口受限空间汽油蒸气爆燃超压特性研究

基于实验研究了端部开口半受限空间内汽油蒸气泄放爆燃特性,获得了受限空间 内外爆燃超压的变化规律。研究结果表明:受限空间内部超压随时间变化分为点火孕育 期、加速泄流期、外部爆燃期、波动振荡期、衰弱恢复期,爆燃过程中出现多超压峰值 现象且伴随有强烈的压力振荡;随着初始油气浓度的增大,受限空间外部爆燃超压先增 大后减小,外部爆燃超压最大浓度为1.70%;随着比例距离的增加,受限空间外部超压 值呈负指数规律衰减,且横向衰减速率要大于轴向衰减速率。     

基于LSSVM的石灰石浆液制取电耗优化

提出了基于最小二乘支持向量机(LSSVM)构造以球磨机制浆速度作为目标优化模型,并采用遗传算法实现了给料量、给水量、漩流器入口压力等运行参数的寻优,获得了优化制浆速度的调整方式。以此方式的相应参数作为当前负荷下的基准值,能很好地解决制浆工况下运行参数基准的确定问题。通过现场试验证明:按此基准值运行,可以提高制浆速度,降低电耗。     

重金属对2-氯酚厌氧降解的抑制动力学研究

考察了Cu2+、Cd2+、Ni2+、Fe2+4种重金属离子对2-氯酚(2-CP)厌氧降解速率的影响,并通过描述金属离子抑制作用的修正方程对实验进行拟合,研究了其动力学特征.结果表明,在0~500mg/L投加浓度范围内,Fe2+对2-CP的厌氧降解过程基本不抑制,Ni2+、Cu2+、Cd2+则存在明显抑制,抑制程度Cu2+﹥Ni2+﹥Cd2+.相同的抑制强度下,抑制浓度CIP-Cu﹤CIP-Ni﹤CIP-Cd.修正方程能较好地表征金属离子的抑制作用与该离子对降解速率的最大抑制浓度(I*)以及投加浓度之间的定量关系.由该方程拟合结果可得到Cu2+、Cd2+、Ni2+对25mg/L 2-CP降解的I*值分别为458.7,1693.5,1528.5mg/L,I*及指数m值的大小表明金属离子对2-CP厌氧降解的抑制Cu2+﹥Ni2+﹥Cd2+.     

Ultrasound-assisted emulsification solidified floating organic drop microextraction for the determination of trace amounts of copper in water samples

A simple and efficient liquid-phase microextraction (LPME) technique was developed using ultrasound-assisted emulsification solidified floating organic drop microextraction (USAE-SFODME) combined with flame atomic absorption spectrometry, for the extraction and determination of trace copper in water samples. 1-(2-Pyridylazo)-2-naphthol (PAN) was used as chelating agent. Microextraction efficiency factors (including extraction solvent type, extraction volume, time, temperature, and pH), the amount of the chelating agent, and salt effect were investigated and optimized. Under the optimum extraction conditions, figures of merit of the proposed method were evaluated. The calibration graph was linear in the range of 20–600 mg·L⁻¹ with a detection limit of 0.76 mg·L⁻¹. The relative standard deviation (R.S.D) for ten replicate measurements of 20 and 400 mg·L⁻¹ of copper was 3.83% and 2.65%, respectively. Finally, the proposed method was applied to tap water, river water, and sea water, and accuracy was assessed through the analysis of certified reference water or recovery experiments.     

地壳垂直形变场与强震关系研究

根据不同时期的地壳垂直形变速度,研究了中国大陆地壳的垂直演变特征,结合1965~2005年中国大陆地区M≥7级的大震,研究了垂直形变演变与强震活跃时间段和相对平静时段的关系。并且依据1951~1990年中国大陆垂直形变速率图计算分析了垂直形变速率梯度,研究了高梯度带与大震的分布关系。中国大陆垂直形变速度的演变表明,在中国大陆出现NWW向的上升带和下降带相间分布,而且以上升为主,西部呈现“南升北降”等形变特点时,中国大陆的大震活动也相对活跃,当大面积下降变化为主,尤其是青藏高原表现为下降时,大震相对平静。M≥7级的地震绝大多数发生在水准网控制的高梯度带上,发生在不同高梯度带的交汇部位,转折部位、或者局部变化较突出的附近地带。     

Thermo-kinetic modelling of dust explosions

The guidelines for protection and mitigation against hazard coming from dust explosion require the knowledge and then the evaluation either experimentally or theoretically of the thermo-kinetic parameters (i.e. K_St, P_max). We developed a numerical tool for the evaluation of the thermo-kinetic parameters of dust explosion. This model is based on the simulations of the combustion reaction by means of a detailed reaction mechanism assuming that the pyrolysis/devolatilization step is very fast and then gas combustion is controlling dust explosion. The model allows then the determination of the most conservative values of K_St, S_l, P_max. In the present paper we calculated the deflagration index and the laminar burning velocity for dusts utilized in various process industries (i.e. cornstarch, polyethylene, cellulose) as function of dust concentration. The obtained data were successfully compared with the available experimental results.     

End-of-life vehicle recycling and automobile shredder residue management in Japan

The Japanese Government introduced the Law on Recycling of End-of-Life Vehicles (ELV Recycling Law) in 2002. This law requires manufacturers to retrieve chlorofluorocarbons (CFCs), airbags, and automobile shredder residue (ASR) from ELVs and to properly recycle the remaining materials. This framework is compared with European ELV directives. Pilot-scale incineration plant testing has revealed a greater formation of by-product persistent organic pollutants (POPs) during the primary combustion of ASR compared to normal municipal solid waste. This may be attributed to the abundance of chlorine, Cu, and Fe in ASR, as Cu and Fe have been found to catalyze the formation of POPs under certain conditions. However, most by-product POPs were destroyed by the secondary combustion, and almost all were removed after flue gas treatment. The direct melting system is a shaft-type gasification and melting technology that has proved effective in many municipal solid waste applications. This system can be applied to ASR recycling for effective decomposition of brominated flame retardants and polybrominated dioxins.     

小型管道中瓦斯爆炸火焰传播特性的实验研究

自行设计了内径88mm、壁厚6mm、总长1600mm、点火孔20mm的小型瓦斯爆炸实验管道,结构简单、操作方便,具有可观察性。采用高速摄录分析系统,对不同浓度瓦斯爆炸初期火焰传播特性进行了实验研究。结果表明:瓦斯爆炸初始阶段,火源引爆瓦斯到形成明显的、大强度的火焰传播的时间约为10~30ms;随着瓦斯浓度增大,爆炸感应期逐渐变短;瓦斯爆炸的火焰传播有一个突变过程,瓦斯浓度越大,达到突变的时间越短;当燃烧波在开始移动到5~10倍巷道宽度距离后,便开始明显加速,达到爆燃;当瓦斯爆炸火焰冲出管道时,爆炸火焰速度又一次加快。实验结果验证了该实验台研究瓦斯爆炸是可行的。     

偏振分析法计算震中方位角的精度分析

震中方位角是地震研究人员研究的经典课题,偏振分析法可以有效地提高方位角的计算精度.但是国内对此方法的研究并不充分,故本文分析了大量强震记录的震中方位角的计算结果,回答了何种地震数据能算出精度最高的震中方位角、最合适的时间窗口长度在什么范围内、误差有什么样的特征这三个问题.本文建立了偏振椭球的立体几何模型,改进了视方位角与震中方位角转化关系的表示方法,使其更符合实际需求.由于数据计算依赖MATLAB程序,故编写了计算震中方位角的脚本M文件和三个供调用的函数M文件.地震研究者可调用这些函数完成读取数据、速度和位移的仿真.