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101.
Thermal and mechanical properties of poly(lactic Acid) and poly(ethylene/butylene Succinate) blends 总被引:2,自引:0,他引:2
In this study, blends of poly (lactic acid) (PLA) with poly(ethylene/butylene succinate) (Bionolle) have been investigated
for their thermal and mechanical properties as a function of the concentration of Bionolle. Differential scanning calorimetry
(DSC), dynamic mechanical analysis (DMA), and tensile tests were used to characterize the blends. From the results of the
DMA and DSC, it was found that this blend system was not miscible within the compositions studied. DSC results showed that
adding Bionolle aids in crystallization of PLA. It was observed that increasing the Bionolle concentration led to a slight
increase in the strain-at-break of the blends but a decrease in the Young’s modulus and ultimate tensile strength. Biaxially
oriented films showed an increase in tensile strength, modulus, and strain-at-break. 相似文献
102.
Synthesis of poly(hydroxyalkanoate) from hydrolyzed linseed oil 总被引:3,自引:0,他引:3
Elena Casini Theo C. de Rijk Pieter de Waard Gerrit Eggink 《Journal of Polymers and the Environment》1997,5(3):153-158
Pseudomonas putida was grown on a mixture of long-chain fatty acids obtained by hydrolysis of linseed oil. A poly(3-hydroxyalkanoate) containing
51.2% of unsaturated monomers was obtained. A considerable percentage (13.6%) was constituted by C14 and C16 monomers containing three double-bonds in the side chains. The polymer showed a high tendency to crosslink when it was kept
in presence of air. In the crosslinked polymer no polyunsaturated monomers could be detected. 相似文献
103.
针对仪化热电厂将循环水用作冲灰水,导致浓缩倍率只有1.6,以及凝汽器铜管腐蚀结垢严重等问题,提出了隔断循环水与冲灰水的直接联系,实现闲路循环,对凝汽器铜管进行酸洗,并对循环水实施加缓蚀阻垢荆、杀菌剂和旁流过滤等办法,全部实施后产生了很好的效益,值得借鉴。 相似文献
104.
楼静 《中国环境管理干部学院学报》2004,14(3):38-39
利用由O2和Fenton试剂组成的类Fenton系统处理对氨基苯磺酸废水,取得了很好的降解效果.当FeSO4(10g/L)投加量为1.2mL、H2O2(3%)投加量为3mL时,COD去除率可达到70%. 相似文献
105.
Nugraha E. Suyatma Alain Copinet Lan Tighzert Veronique Coma 《Journal of Polymers and the Environment》2004,12(1):1-6
Biodegradable film blends of chitosan with poly(lactic acid) (PLA) were prepared by solution mixing and film casting. The main goal of these blends is to improve the water vapor barrier of chitosan by blending it with a hydrophobic biodegradable polymer from renewable resources. Mechanical properties of obtained films were assessed by tensile test. Thermal properties, water barrier properties, and water sensitivity were studied by differential scanning calorimeter analysis, water vapor permeability measurements, and surface-angle contact tests, respectively. The incorporation of PLA to chitosan improved the water barrier properties and decreased the water sensitivity of chitosan film. However, the tensile strength and elastic modulus of chitosan decreased with the addition of PLA. Mechanical and thermal properties revealed that chitosan and PLA blends are incompatible, consistent with the results of Fourier transform infrared (FTIR) analysis that showed the absence of specific interaction between chitosan and PLA. 相似文献
106.
超声-双氧水和亚铁离子体系处理含酚废水研究 总被引:3,自引:2,他引:3
在实验装置上对超声-双氧水和亚铁离子体系联合处理含酚废水进行了实验研究。主要考察了废水初始pH值、初始双氧水浓度、超声功率、反应时间等因素对酚去除率的影响。实验结果表明:超声辐射可以在双氧水和亚铁离子体系氧化过程中起加速反应的作用,而且随着超声功率的增大,加速反应的能力增强;实验条件下废水初始pH值为4~6.8,初始双氧水浓度为140mg/L时酚去除效果最佳;超声-双氧水和亚铁离子体系处理含酚废水过程中苯酚的降解规律符合表现一级反应。 相似文献
107.
本文分析了金沙江对硫酸的缓冲特征,建立了江水的缓冲曲线方程,并且验证了此方程的有效性,证明用此方程预测硫酸进入金沙江后江水pH值的变化情况,其预测准确度在0.2个pH单位内。 相似文献
108.
109.
Industrial firms that kill and process chickens generate wastewater that contains fat, oil, and grease (FOG). The FOGs are located in the fatty waste that is collected by floatation in grease traps. Chemical and physical characterisation of FOGs would provide useful information that would help in the development of methods designed to decrease the extent of pollution caused by disposal of the waste and to utilise commercially some of its lipid constituents. Employing these methods would enhance the profitability and competitive potential of these commercial organisations. Samples of grease trap waste from 14 firms in central Thailand have been examined. Due to the very different schemes of waste management employed by these firms, the physical appearance of their fatty wastes showed considerable variation. The chemical and physical properties of the FOGs present in these wastes showed considerable variation also. Large amounts of free fatty acids (10–70% as oleic acid) were detected in most of the 14 wastes and palmitic, cis-9-oleic, cis,cis-9,12-linoleic, stearic, and palmitoleic acids were the predominant species of free and esterified acids. Most of the FOGs were solid at temperatures below 40 °C. Many of them contained traces of heavy metals (Cu and Pb) and some contained traces of the pesticides dimethoate and cypermethrin. The content of these potentially hazardous substances would have to be considered very carefully before discarding the fatty wastes and during the development of methods designed to isolate their potentially profitable lipid constituents. 相似文献
110.