UV-catalytic treatment of spent caustic from ethene plant with hydrogen peroxide and ozone oxidation

The performance of UV/H2O2, UV/O3 and UV/H2O2/O3 oxidation systems for treating spent caustic from an ethylene plant was investigated, in UV/H2O2 system, with the increase of H202 dosage, removal efficiencies of COD and the ratio of biochemical oxygen demand(BOD) to chemical oxygen demand(COD) of the effluent were increased and a better performance was obtained than the H2O2 system alone. In UV/H2O2 system, removal efficiency of COD reach 68% under the optimum condition, and BOD/COD ratio was significantly increased from 0.22 to 0.52. In UV/O3 system, with the increase of O3 dosage, removal efficiency of COD and BOD/COD ratio were increased, and a better performance was obtained than the O3 system alone. Under the optimum condition, removal efficiency of COD was 54%, and BOD/COD ratio was significantly increased from 0.22 to 0.48. In UV/H2O2/O3 system, COD removal efficiency was found to be 22.0% higher than UV/O3 system.     

Remote sensing of the urban heat island and its changes in Xiamen City of SE China

World-wide urbanization has significantly modified the landscape, which has important climatic implications across all scales due to the simultaneous removal of natural land cover and introduction of urban materials. This resulted in a phenomenon known as an urban heat island(UHI). A study on the UHI in Xiamen of China was carried out using remote sensing technology. Satellite thermal infrared images were used to determine surface radiant temperatures. Thermal remote sensing data were obtained from band 6 of two Landsat TM/ETM^ images of 1989 and 2000 to observe the UHI changes over l l-year period. The thermal infrared bands were processed through several image enhancement technologies. This generated two 3-dimension-perspective images of Xiamen‘s urban heat island in 1989 and 2000, respectively, and revealed heat characteristics and spatial distribution features of the UHI. To find out the change of the UHI between 1989 and 2000, the two thermal images were first normalized and scaled to seven grades to reduce seasonal difference and then overlaid to produce a difference image by subtracting corresponding pixels. The difference image showed an evident development of the urban heat island in the 11 years. This change was due largely to the urban expansion with a consequent alteration in the ratio of sensible heat flux to latent heat flux. To quantitatively compare UHI, an index called Urban-Heat-Island Ratio Index(URI) was created. It can reveal the intensity of the UHI within the urban area. The calculation of the index was based on the ratio of UHI area to urban area. The greater the index, the more intense the UHI was. The calculation of the index for the Xiamen City indicated that the ratio of UHI area to urban area in 2000 was less than that in 1989. High temperatures in several areas in 1989 were reduced or just disappeared, such as those in old downtown area and Gulangyu lsland. For the potential mitigation of the UHI in Xiamen, a long-term heat island reduction strategy of planting shade trees and using light-colored, highly reflective roof and paving materials should be included in the plans of the city planers, environmental managers and other decision-makers to improve the overall urban environment in the future.     

色拉油废水处理工程设计

色拉油废水COD、动植物油、氨、氮、磷浓度都很高。采用预处理除油 倒A2 O 接触氧化 化学除磷组合工艺处理 ,效果明显 ,出水各项指标 (特别是磷酸盐 )均能达《污水综合排放标准》(GB8978 1 996 )中的一级排放标准     

金堆城超大型钼矿床水-岩δD-δ~(18)O同位素交换体系理论模型及成矿流体来源

基于水-岩δD-δ18O同位素交换体系理论模型的建立和计算，对金堆城超大型斑岩钼矿四个不同成矿期中成矿流体的演化和来源进行了研究，发现在成矿前期和早期，成矿流体为岩浆水与围岩在较低水／岩比值（0．1W／R＞0．001）和中、高温（t=250～500℃）条件下反应后的残余流体，而主成矿期和成矿晚期的成矿流作为大气降水在相对较高水／岩比值（0．5＞W／R0．1）和中、低温（t＝150～310℃）条件下与围岩反应后的残留流体。大气降水在金堆城钼矿成矿过程中起了重要作用。在主成矿期水／岩比值达到最高。     

The curve of ion exchange ratio(%)-pH of the interaction between suspended particles with Cd(II) in the Yellow River

The curve of ion exchange ratio(%)-pH of the interactionbetween suspended particles with Cd(II) in the Yellow River wasstudied. The effects of lysine on this curve have been alsoinvestigated. The results showed that (1) Cadmium in Cd(OH)+ formin the suspended particles exchanges with the cations.The exchangeratio of Cd2+ is nearly at its greatest value in the range of pH(8.0-8.5) in natural aquatic system; (2) Ion exchange ratiodecreases as the concentration of Cd2+ raises from 8.9×10-6 mol/L to 2x8.9 x 10-6mol/L; (3) At the lysine concentration of 6.8x10-6 mol/L, it can promote the ion exchange ratio; (4) Adsorption of thesuspended particles to cadmium is weaker in seawater and Jin ShaRiver than in the Yellow River.     

黑色岩系中贵金属富集层的成因:来自固定铵的佐证

对湘黔地区（遵义、大庸）下寒武统牛蹄塘组黑色岩系的部分样品进行了Au、Ag、PGE、固定铵的分析，综合前人的资料进行了数据的对比和讨论，首次应用其中的固定铵来讨论了贵金属富集层的成因。     

生产固化剂A废水的COD_(Mn)与COD_(cr)相关性的探讨

分别用重铬酸钾法和高锰酸钾法测定了生产固化剂Ａ废水的化学需氧量ＣＯＤｃｒ和ＣＯＤＭｎ，得到了ＣＯＤｃｒ和ＣＯＤＭｎ的相关性方程，线性相关较好     

上海市大气中NMHC,NOx,O3和SO2变化规律

通过对上海市大气中光化学主要污染物如ＮＭＨＣ、ＮＯｘ、Ｏ３及ＳＯ２等的日变化监测，发现ＮＯｘ、Ｏ３的日浓度变化与气象条件密切相关，高浓度Ｏ３多出现在晴朗少云，气温较高的大气条件下同步监测发现，Ｏ３与ＮＯｘ呈负相关，相关系数ｒ＝－０．７８５；ｄｍｊ ＳＯ２ｇｎ ＮＭＨＣｅ ｔｖｅ ｖｂ ｒ ｇｈｄ ｓｈ ｕｄ ，ｓｈ ｕｄ ｔｘｉ ｏｖｔ ｒ＝     

提高A/O法处理生活污水脱氮效率探究

将A/O(厌氧/好氧)法处理生活污水设施的好氧生物滤池出口的硝化液回流到厌氧生物滤池进行反硝化生物脱氮,经过生产运行的实践证明:改进后的出水水质稳定,TN(总氮)去除率由原来的13.2%提高到54.6%,同时COD、BOD5、SS的去除率也分别由原来的83%、92.1%、89.2%提高到85.5%、95.2%、90%,且设施改进投资及运行费用省,对提高污水脱氮效果有应用价值。     

利用混合C9重芳烃回收磺酸盐装置的技术经济分析

介绍了回收磺酸盐生产工艺 ,对其装置的产品成本进行了测算 ,并对盈亏平衡及其敏感性进行了分析 ,进而确定了主要经济指标。