锅炉烟尘监测的质量控制

通过对影响锅炉烟尘监测每一个环节的分析,才能做到对烟尘监测的质量控制。     

高炉出铁口烟尘捕集技术浅析

介绍了高炉出铁口烟尘捕集的重要性和困难性,分析和比较了三种主要大型高炉出铁口烟尘捕集方式的特点,指出了其发展趋势。     

艾比湖干涸湖底化学组成及盐尘的风运堆积

选择亚洲中部典型干涸尾闾湖——艾比湖干涸湖底及其下风向约200km的范围为研究区,并把研究区分为干涸湖底风蚀区和盐尘扩散堆积区两个子区.通过对两子区连续多年野外实地观测、采样分析、定点试验等手段,研究了干涸湖底表层沉积物的化学组成、湖底风蚀动态和盐尘的扩散堆积规律.结果表明,艾比湖干涸湖底不同地表形态(结晶盐壳、盐-淤泥-黏土壳、风蚀堆积壳)间可溶性盐含量差异显著,盐类混合物中以硫酸盐和氯化物为主,二者基本占全部可溶性盐的90%,碳酸盐含量甚微.春秋两季是湖底风蚀和盐碱尘暴的高发期,盐分堆积动态与风期变化一致,春、秋两季大风期,降尘中盐通量最高;冬、夏两季降尘中盐通量较低.干涸湖底下风向盐尘的堆积强度以精河为中心分别向西北和东北方向递减,盐尘在风运过程中表现出显著的分异规律,硫酸盐比氯化物具有更远距离的迁移能力.     

Element and mineral characterization of dust emission from the saline land at Songnen Plain, Northeastern China

Recent observations of Asian dust storms show an eastern expansion of the source area to degraded lands, where dust emissions have been little studied. The dust concentrations over the saline land of the western Songnen Plain (SSL), Northeastern China, are circumstantially higher than those from the northwestern Chinese deserts. These concentrations are sensitive to the surface soil conditions and wind velocity on the ground. The dust samples collected during dust storm events on the SSL contain abundant Na, Mg, Al, K, Ca, Fe and Ti, as well as toxic elements such as Cu, V, Zn and Ba. Individual particle analysis reveals that fine saline particles (< 10 μm in diameter) on the saline land, consisting largely of carbonate, halite and sulfate together with lithogenic minerals such as SiO₂ and aluminosilicate, are eventually uplifted during the interval from spring to autumn. The predominantly fine saline particles uplifted from the SSL are likely transported eastward by the winter monsoon circulation and westerlies. Recent degradation of saline lands in Northeastern China would not only increase the frequency of dust storm events in the downwind area, but also might change the chemical composition of the Asian dust emissions.     

关于改进麻石水膜除尘脱硫技术的探讨

锅炉除尘技术很多,近年来麻石水膜式除尘器得到了广泛的应用,同时麻石水膜除尘器技术也不断得到进步,从技术方案创新和工艺改进方面都取得了很大的成绩,值得我们去总结和探讨。     

对选矿厂生产性粉尘的治理措施

本文介绍了某钢选矿厂破碎车间治理粉尘污染所采用的密闭、加湿机械除尘、改造除尘器、高压静电除尘及湿式除尘等方法收到的效果,     

Size distribution and di use pollution impacts of PAHs in street dust in urban streams in the Yangtze River Delta

Particles of dust washed o streets by stormwater are an important pathway of polyaromatic hydrocarbons (PAHs) into urban streams. This article presented a comprehensive assessment of the size distribution of PAHs in street dust particles, the potential risks of the particles in urban streams, and the sources and sinks of PAHs in the stream network. This assessment was based on measurements of 16 PAHs from the USEPA priority list in street dust particles and river sediments in Xincheng, China. The content of total PAHs ranged from 1629 to 8986 g/kg in street dust particles, where smaller particles have a higher concentrations. Approximately 55% of the total PAHs were associated with particles less than 250 m which accounted for 40% of the total mass of street dust. The PAH quantities increased from 2.41 to 46.86 g/m2 in the sequence of new residential, rising through main roads, old town residential, commercial and industrial areas. The sediments in stream reaches in town were found to be sinks for street dust particle PAHs. The research findings suggested that particle size, land use and the hydrological conditions in the stream network were the factors which most influenced the total loads of PAH in the receiving water bodies.     

复合型水雾抑尘剂作用机理与优选方法研究*

为有效提高水雾综合除尘性能,基于水雾捕尘过程及抑尘作用机理,从复合抑尘剂润湿、吸湿、黏结作用组分出发,讨论不同性质粉尘与抑尘剂各组分间匹配协同关系,进而研究复合型水雾抑尘剂优选方法。结果表明:湿润组分优选疏水端含有碳碳双键、醚基或链间存在氢键的表面活性剂;通过改变疏水基链长、不饱和度和支链数等方法,使湿润组分亲水、亲油性与粉尘相匹配。吸湿组分优选体心立方晶胞结构、溶解度相对较小的无机盐或混合配方无机盐,或者含极性强、能形成氢键的基团且空间结构复杂的有机吸湿剂。黏结组分优选溶液黏度高、交联网状、结构复杂的高分子聚合物。在上述组分优选的基础上,通过抑尘剂复配性能实验合理确定各组分的最优配比。     

湿式除尘器氢气爆炸事故控制研究*

为降低铝合金湿式除尘系统发生氢气爆炸事故的风险,提出1种氢气抑制的方法用来降低铝合金湿式除尘系统发生氢气爆炸事故的可能性。选取柠檬酸钠作为抑制剂开展抑氢实验研究,得到不同浓度的柠檬酸钠溶液随时间变化的抑氢曲线。当柠檬酸钠溶液浓度为0.4~4 g/L时,能有效抑制铝合金粉尘与水的反应。通过扫描电子显微镜(scanning electron microscope,SEM)和能量色散谱（energy dispersive spectroscopy,EDS)分析对铝合金粉与柠檬酸钠溶液反应后的产物进行表征。最后,对本文提出的抑氢方法的经济性进行分析,明确该方法在节约安全投入方面具有非常明显的优势。抑氢本质化安全设计方法为控制铝合金湿式除尘系统氢气爆炸事故提供了1种新的思路,同时也可被控制核反应堆氢气爆炸事故所借鉴。     

基于量子化学分析表面活性剂对不同煤种润湿机理的影响*

为研究不同类型表面活性剂对煤润湿性的调控机理,首先将所选煤样的润湿性与煤样成分进行关联分析,然后采用透过高度法实验及量子化学计算相结合的方法研究表面活性剂对煤样润湿性的影响效果及机理。结果表明:煤的润湿性与煤中固有水分、灰分呈正相关关系,与煤中固定碳呈负相关关系;所选取的4种表面活性剂的加入会降低褐煤的亲水性,而对长焰煤、焦煤和无烟煤亲水性有提升作用,并且十二烷基硫酸钠对于这3种煤样亲水性的提升作用最为明显;表面活性剂分子、水分子及煤分子的表面静电势分布共同决定了表面活性剂对煤浸润性的影响。