选择性吸附法处理含表面活性剂和多环芳烃的土壤淋洗液研究

比较研究了H103树脂、活性炭、沸石、硅藻土和膨润土等5种吸附剂对土壤淋洗液中TX-100与PAHs的吸附性能.批实验结果表明,H103树脂、活性炭、沸石、硅藻土和膨润土吸附后,淋洗液中T-PAHs及TX-100浓度分别为0.03和0 mg·L~(-1)、0.16和3623 mg·L~(-1)、15.21和6175 mg·L~(-1)、15.98和6555 mg·L~(-1)、9.49和4332 mg·L~(-1),选择性吸附系数排序依次为活性炭膨润土沸石硅藻土H103树脂.其中,活性炭能够去除淋洗液中99%的PAHs,同时保留51.33%的TX-100回收再利用,选择吸附系数达到109.5.活性炭固定床实验中,由淋洗液溶质的穿透曲线计算出物质的吸附容量.当空隙体积为2.5-7PV时,活性炭能够去除淋洗液中72%的PAHs,同时保留81%的TX-100,平均选择吸附系数为10.08.由此可见,活性炭固定床可有效处理含表面活性剂土壤淋洗液中的多环芳烃,同时实现表面活性剂的回收再利用.     

Chemical fluxes in time through forest ecosystems in the UK - Soil response to pollution recovery

Long term trend analysis of bulk precipitation, throughfall and soil solution elemental fluxes from 12 years monitoring at 10 ICP Level II forest sites in the UK reveal coherent national chemical trends indicating recovery from sulphur deposition and acidification. Soil solution pH increased and sulphate and aluminium decreased at most sites. Trends in nitrogen were variable and dependant on its form. Dissolved organic nitrogen increased in bulk precipitation, throughfall and soil solution at most sites. Nitrate in soil solution declined at sites receiving high nitrogen deposition. Increase in soil dissolved organic carbon was detected - a response to pollution recovery, changes in soil temperature and/or increased microbial activity. An increase of sodium and chloride was evident - a possible result of more frequent storm events at exposed sites. The intensive and integrated nature of monitoring enables the relationships between climate/pollutant exposure and chemical/biological response in forestry to be explored.     

DSD酸氧化缩合废水浓缩液回用试验研究

研究了DSD酸氧化缩合废水浓缩液回用到原生产过程的可行性。对DSD酸氧化缩合废水可采用萃取技术分离出其中97％的有机物，反萃产生的4－8倍的浓缩液返回到DSD酸生产中的氧化缩合单元后，可提高DNS酸的收率约7．43％，且不会明显影响产品的纯度，浓缩液8次循环磁用试验的结果表明，虽然DSD酸氧化缩合废水的COD从15000－20000mg/L提高到20000－29000mg/L，但没有显著持续增长的趋势，表明反应液中副产物的浓度得到了有效的控制。     

锅炉运行中水击事故的原因及处理

通过对水击现象的剖析 ,详细分析了锅筒、给水管道、蒸汽管道、省煤器内的水击原因 ,并提出了水击事故的处理方法及预防措施。     

DISTRIBUTED DISCHARGE OF COOLING WATER ALONG DIRECTION OF STREAM FLOW1

ABSTRACT. A multiple-outfall system for cooling water disposal which is distributed along the direction of stream flow is analyzed. The results provide a simple method of preliminary design of a cooling water discharge outfall system and for a quick extimate of water quality of a polluted stream. It is shown that a properly designed distributed discharge system is capable of preventing serious pollution due to localized discharge of wastes and waste heat; however, the final design of the discharge system should take into account alternative schemes of waste heat disposal and their economic consequences.     

CRITICAL EVALUATION OF CERTAIN METHODS OF UNSTEADY GROUNDWATER HYDRAULICS1

The basic theories and fundamental assumptions usually employed in the solution of unsteady groundwater flow problems are reviewed critically. The best known method of analysis for such problems is based on the Dupuit-Forchheimer approximation and leads to a nonlinear parabolic differential equation which is generally solved by linearization or numerical methods. The accuracy of the solution to this equation can be improved by use of a different approach which does not employ the Dupuit Forchheimer assumption, but rather is based on a semi-numerical solution of the Laplace equation for quasi-steady conditions. The actual unsteady process is replaced by a sequence of steady-state conditions, and it is assumed that the actual unsteady flow characteristics during a short time interval can be approximated by those associated with “average” steady state flow. The Laplace equation is solved by a semi-discretization method according to which the horizontal coordinate is divided into subintervals, while the vertical coordinate is maintained continuous. The proposed method is applied to a typical tile drainage problem, and, based on a comparison of calculated results with experimental data, the method is evaluated and practical conclusions regarding its applicability are advanced.     

The Fernow Watershed Acidification Study: Ecosystem Acidification, Nitrogen Saturation and Base Cation Leaching

In 1989, a watershed acidification experiment was begun on the Fernow Experimental Forest in West Virginia, USA. Ammonium sulfate fertilizer (35.5 kg N ha⁻¹ yr⁻¹and 40.5 kg S ha⁻¹ yr⁻¹) was applied to a forested watershed (WS3) that supported a 20-year-old stand of eastern deciduous hardwoods. Additions of N and S are approximately twice the ambient deposition of nitrogen and sulfur in the adjacent mature forested watershed (WS4), that serves as the reference watershed for this study. Acidification of stream water and soil solution was documented, although the response was delayed, and acidification processes appeared to be driven by nitrate rather than sulfate. As a result of the acidification treatment, nitrate solution concentrations increased below all soil layers, whereas sulfate was retained by all soil layers after only a few years of the fertilization treatments, perhaps due to adsorption induced from decreasing sulfate deposition. Based on soil solution monitoring, depletion of calcium and magnesium was observed, first from the upper soil horizons and later from the lower soil horizons. Increased base cation concentrations in stream water also were documented and linked closely with high solution levels of nitrate. Significant changes in soil chemical properties were not detected after 12 years of treatment, however.     

矿井通风网络解算可视化软件研究

采用面向对象编程语言Visual Basic6.0为开发工具,以Access为后台数据库,开发了具有风机优选功能的矿井通风网络解算软件。该软件承袭了Windows系统应用程序界面直观、交互性好的特点,集矿井通风网络解算、自然风压计算、风机自动选型以及经济断面优化等功能于一体,并辅以强大的数据管理系统,为矿山通风设计和管理工作提供了便利工具。     

WATER RIGHTS,EMINENT DOMAIN,AND THE PUBLIC TRUST1

ABSTRACT: Faced with the necessity of meeting growing municipal water requirements in areas where available supplies are completely allocated, numerous cities throughout the West are turning to their eminent domain powers to affect a reallocation of water from less preferred uses to municipal uses, thus bringing about a sharp conflict with agricultural interests. As a basis for discussing these eminent domain powers, this paper begins with a brief review of the development of property rights. The existence of both private and public (social) rights in the “bundle of rights” is noted. In recent years the Public Trust Doctrine has been used to limit private rights in property, and to protect and strengthen social rights. A case study which focuses on a conflict between individual and social interests in water rights is discussed. This case involves the City of Thorton, Colorado which initiated municipal condemnation proceedings to acquire the water rights and structures of two nearby irrigation companies. The case represents an attempt to incorporate the spirit of the Public Trust Doctrine into legislation which sets forth procedures for resolution of similar water rights conflicts that will inevitably become more numerous throughout the West in the future.     

Semi-analytical solution of two-dimensional sharp interface LNAPL transport models

In this paper, we present semi-analytical solutions for two-dimensional equations governing transport of Light Non-Aqueous Phase Liquids (LNAPL) in unconfined aquifers. The proposed model is based on sharp interface displacement and steady groundwater flow assumptions, where both the water–LNAPL interface and the LNAPL–air interface are represented as sharp interfaces. In the case of steady groundwater flow, these equations can be reduced to a two-dimensional nonlinear solute transport equation, with the LNAPL thickness in the free product lens being the primary unknown variable. The linearized form of this solute transport equation falls into the category of two-dimensional transport equation with time-dependent dispersion coefficients. This equation can be solved analytically for an infinite domain region. In this paper, the general form of the analytical solution for the transport equation, as well as the solutions for some specific cases are presented. To demonstrate the utility of the proposed solution, numerical results obtained for two example problems are discussed and presented comparatively with a finite-element solution and other more restrictive solutions available in the literature. Although the solutions discussed in this paper have some simplifying assumptions, such as sharp-interfaces between fluid phases, steady groundwater flow and homogeneous aquifer properties, the semi-analytical solutions presented in this study may be used effectively as bench mark solutions in evaluating LNAPL migration in the subsurface. These solutions are simple and cost effective to implement and may be used in the calibration of other more complex numerical solutions that can be found in the literature.