全文获取类型
收费全文 | 4990篇 |
免费 | 620篇 |
国内免费 | 2702篇 |
专业分类
安全科学 | 296篇 |
废物处理 | 238篇 |
环保管理 | 573篇 |
综合类 | 4564篇 |
基础理论 | 998篇 |
环境理论 | 1篇 |
污染及防治 | 837篇 |
评价与监测 | 319篇 |
社会与环境 | 261篇 |
灾害及防治 | 225篇 |
出版年
2024年 | 30篇 |
2023年 | 155篇 |
2022年 | 281篇 |
2021年 | 292篇 |
2020年 | 306篇 |
2019年 | 287篇 |
2018年 | 293篇 |
2017年 | 262篇 |
2016年 | 357篇 |
2015年 | 302篇 |
2014年 | 336篇 |
2013年 | 577篇 |
2012年 | 481篇 |
2011年 | 531篇 |
2010年 | 376篇 |
2009年 | 338篇 |
2008年 | 293篇 |
2007年 | 395篇 |
2006年 | 362篇 |
2005年 | 298篇 |
2004年 | 251篇 |
2003年 | 272篇 |
2002年 | 212篇 |
2001年 | 181篇 |
2000年 | 149篇 |
1999年 | 157篇 |
1998年 | 78篇 |
1997年 | 87篇 |
1996年 | 78篇 |
1995年 | 61篇 |
1994年 | 56篇 |
1993年 | 58篇 |
1992年 | 38篇 |
1991年 | 27篇 |
1990年 | 16篇 |
1989年 | 11篇 |
1988年 | 7篇 |
1987年 | 6篇 |
1986年 | 3篇 |
1985年 | 2篇 |
1984年 | 2篇 |
1981年 | 1篇 |
1979年 | 1篇 |
1978年 | 2篇 |
1977年 | 3篇 |
1972年 | 1篇 |
排序方式: 共有8312条查询结果,搜索用时 46 毫秒
151.
《环境科学学报(英文版)》2023,35(4):263-274
The cryptomelane-type manganese oxide (OMS-2)-supported Co (xCo/OMS-2; x = 5, 10, and 15 wt.%) catalysts were prepared via a pre-incorporation route. The as-prepared materials were used as catalysts for catalytic oxidation of toluene (2000 ppmV). Physical and chemical properties of the catalysts were measured using the X-ray diffraction (XRD), Fourier transform infrared spectroscopic (FT-IR), scanning electron microscopic (SEM), X-ray photoelectron spectroscopy (XPS), and hydrogen temperature-programmed reduction (H2-TPR) techniques. Among all of the catalysts, 10Co/OMS-2 performed the best, with the T90%, specific reaction rate at 245°C, and turnover frequency at 245°C (TOFCo) being 245°C, 1.23 × 10−3 moltoluene/(gcat·sec), and 11.58 × 10−3 sec−1 for toluene oxidation at a space velocity of 60,000 mL/(g·hr), respectively. The excellent catalytic performance of 10Co/OMS-2 were due to more oxygen vacancies, enhanced redox ability and oxygen mobility, and strong synergistic effect between Co species and OMS-2 support. Moreover, in the presence of poisoning gases CO2, SO2 or NH3, the activity of 10Co/OMS-2 decreased for the carbonate, sulfate and ammonia species covered the active sites and oxygen vacancies, respectively. After the activation treatment, the catalytic activity was partly recovered. The good low-temperature reducibility of 10Co/OMS-2 could also facilitate the redox process accompanied by the consecutive electron transfer between the adsorbed O2 and the cobalt or manganese ions. In the oxidation process of toluene, the benzoic and aldehydic intermediates were first generated, which were further oxidized to the benzoate intermediate that were eventually converted into H2O and CO2. 相似文献
152.
天然气压缩机站的安全生产管理 总被引:1,自引:0,他引:1
天然气压缩机组目前在油田的注气采油,增压外输等方面发挥着越来越重要的作用。在压缩机站的生产管理中,安全管理非常重要,建立健全安全规范将对压缩机站的安全运行提供保证。本文主要从油水管理,操作规程,容器管网,安全教育等方面进行阐述。 相似文献
153.
大孔强碱阴树脂去除饮用水中微量有机物 总被引:2,自引:0,他引:2
比较了大孔强碱阴树脂和颗粒活性炭在饮用水的深度处理中对有机物的去除效果。结果表明:(1)大孔强碱阴树脂的吸附容量比颗粒活性炭的大。在pH为8时,大孔强碱阴树脂对TOC的去除率最高。pH6~8时,对TOC的去除率没有明显的区别,而颗粒活性炭在pH为2时。对TOC的去除率最高;水温低能提高2种吸附材料的吸附容量。(2)在动态实验条件下。当流速相同,大孔强碱阴树脂的穿透时间明显比颗粒活性炭的长,大孔强碱阴树脂的制水量约是吸附床的10000倍。而颗粒活性炭却只有吸附床的4000倍。在饮用水的深度处理中,大孔强碱阴树脂可作为活性炭的最佳替代品。 相似文献
154.
沼泽湿地孔隙水中溶解有机碳、氮浓度季节动态及与甲烷排放的关系 总被引:5,自引:1,他引:5
选择三江平原典型的毛果苔草沼泽湿地为研究对象,测定了沼泽湿地孔隙水中水溶性碳、氮浓度、CH4浓度和CH4排放通量,以及相关环境因子;研究了沼泽水中水溶性有机碳、氮浓度变化特征,探讨了沼泽湿地孔隙水中CH4浓度和排放通量季节性变化及发生原因.结果表明,三江平原沼泽湿地土壤孔隙水中DOC浓度有明显的季节变化(p<0.01).最高值(剖面平均值为95.1 mg·L-1)出现在6月份,9和10月份出现最低值(剖面平均值均为79.3 mg·L-1),剖面上浓集中心位于15~30 cm.孔隙水中NH4 -N和NO-3-N浓度也有明显的季节变化,而DON变化不明显.孔隙水中CH4浓度在剖面上的分布特征与DOC一致,高浓度中心位于20~30 cm.除6月份外,孔隙水甲烷浓度与土壤温度和DOC浓度有显著的正相关关系,与NH4 -N和NO3-N均没有显著相关性.土壤温度和孔隙水中DOC浓度是影响沼泽湿地产CH4能力的重要因素.CH4排放通量与土壤温度和积水深度呈很好的指数关系,与剖面CH4浓度和孔隙水NH4 -N浓度有显著的正相关关系.CH4排放通量与孔隙水DOC浓度相关性不显著. 相似文献
155.
广州大田山垃圾填埋场空气中微量挥发有机污染物组成 总被引:9,自引:1,他引:9
以广州大田山垃圾填埋场为例,研究了在不同季节填埋场空气中微量挥发性有机污染物的种类和含量变化情况。结果表明,在春、夏季样品中可分别检测出47和64种化合物,其中有些化合物为USEPA优先控制毒害有机污染物;夏季样品中微量挥发性有机污染物的浓度大多比春季样品高,有的甚至高1个数量级以上。因此加强对垃圾的卫生填埋,尤其是加强对夏季的垃圾卫生填埋的科学管理,减少挥发性有机污染物向大气中的扩散,应给予充分的关注。 相似文献
156.
157.
CLIMATE CHANGE AND NATURAL HAZARDS IN NORTHERN CANADA: INTEGRATING INDIGENOUS PERSPECTIVES WITH GOVERNMENT POLICY 总被引:1,自引:0,他引:1
John?NewtonEmail author C.?D.?James?Paci Aynslie?Ogden 《Mitigation and Adaptation Strategies for Global Change》2005,10(3):541-571
A study of the relationship between natural hazards and climate change in the international context provides the background
for a discussion of the expected changes. In the context of this global discussion, this paper reviews the current perspectives
of those natural hazards that are likely to be influenced by climate change, using northern Canada as a regional case study.
The northern implications of the United Nations Framework Convention on Climate Change are examined, including the status
of climate change action by the northern territorial governments, the evolving role of indigenous people, and the responsibility
for climate change impacts. The difficulties surrounding natural hazards research in remote locations, and the approaches
of indigenous people to natural hazards are then presented. The paper concludes with a suggested policy approach for climate
change and natural hazards in northern Canada, underscoring the need for more comprehensive adaptive strategies to complement
the current tendency to focus on the mitigation of greenhouse gases produced in this region. 相似文献
158.
Atsuyoshi Nakayama Norioki Kawasaki Ioannis Arvanitoyannis Seiichi Aiba Noboru Yamamoto 《Journal of Polymers and the Environment》1996,4(3):205-211
Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.1H and13C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×104. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT
m andT
g values of the copolymers showed a gradual depression with an increase in BL content. NoT
m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers. 相似文献
159.
自然降尘与常规气象因子的相关分析 总被引:1,自引:0,他引:1
笔者整理统计了1992年至1994年逐月自然降水和与之相应的常规气象因子监测数据,找到了自然降尘的季节性分布规律。在此基础上,求得了自然降尘分别与月平均气温、月平均气压、月平均风速、月平均温度、月降水量、月蒸发量的相关系数,并进行了检验,为污染预报工作提供了科学依据。 相似文献
160.