金属用水性隔热防腐涂料的研制

以水性丙烯酸树脂作为成膜物质,配合多种防锈颜填料,以空心玻璃微珠为隔热填料,制备出了集防腐隔热于一体的单组分水性防腐隔热涂料。采用常规性能测试、隔热能力测试、电化学测试技术、扫描电镜观察对涂层进行了性能测试及表征,确定涂料配方PVC值为30%,空心微珠的添加量为8%时,涂料综合性能最好。     

颜料,油墨废水物化,生化法综合治理技术

本文详细阐述了颜料油墨废水的物化,生化法综合治理技术在其在工程 的实际应用,针对该行业废水的特点,该技术可以有效去除水中的悬浮物,有机物,色度及有毒有害物质使出水达标排放。该工程于１９９８年正式投产运行,成为国内首例成功运转达标的颜料,油墨废水治理工程。     

Bioaccessibility of metals in soils and dusts contaminated by marine antifouling paint particles

Fragments of antifouling paint and environmental geosolids have been sampled from the island of Malta and analysed for total and bioaccessible metals. Total concentrations of Ba, Cd, Cu, Pb, Sn and Zn were two to three orders of magnitude higher in spent antifouling composites relative to respective values in background soils and road dusts. Paint fragments were visible in geosolids taken from the immediate vicinity of boat maintenance facilities and mass balance calculations, based on Ba as a paint tracer, suggested that the most contaminated soils, road dusts and boatyard dusts contained about 1%, 7% and 9%, respectively, of antifouling particles. Human bioaccessibilities of metals were evaluated in selected samples using a physiologically based extraction technique. Accessibilities of Cd, Cu, Pb and Zn in the most contaminated solids were sufficient to be cause for concern for individuals working in the boat repair industry and to the wider, local community.     

Analytical methods for the determination of 9 antifouling paint booster biocides in estuarine water samples

Analytical procedures for the determination of nine organic booster biocides which are currently licensed for use in marine antifouling paints, and are thought likely to occur at concentrations in the ng 1⁻¹ range in estuarine water samples, are reviewed. A robust multiresidue method for the determination of four compounds (chlorothalonil, dichlofluanid, diuron and Irgarol 1051) is suggested. A route for the development of a method for the analysis of zinc pyrithione is outlined, based on an extraction method and subsequent derivatisation prior to determination by HPLC with fluorescence detection. Methodology for Zineb, Kathon 5287, TCMS pyridine and TCMTB is less clearly defined.     

重庆地区酸沉降对建筑涂料的影响

本文研究了重庆地区酸性沉降物对建筑外墙涂料的涂膜附着强度、色差及外观的影响;探讨了涂膜附着强度下降率与酸雨雨量之间的相关性;优选出了适合于重庆地区的外墙涂料。     

TBT的污染及控制措施的分析

综合分析了含TBT船舶防污漆的防污机理及产生危害的原因，概括论述了国际社会对TBT的控制措施以及立法的趋势。     

凹凸棒石处理电泳漆废水研究

凹凸棒石及其活化产物对阳极电泳漆废水ＣＯＤ和色度有较好的吸附去除能力，对ＣＯＤ的吸附作用符合Ｆｒｅｕｎｄｌｉｃｈ吸附等温式并呈现一级反应动力学的特征。提高温度和在较高的酸度或碱度条件下均将有利于ＣＯＤ的去除。常温下与聚丙烯酰胺组合使用，可使ＣＯＤ值较高的废水达到或接近排放标准。凹凸棒石经过适当处理可重复使用，效果良好。     

醇酸调和漆中甲醛释放规律研究

以目前国内市场上广泛使用的醇酸调和漆为研究对象,利用按照ASTM E1333-1996标准自行设计的环境测试舱,采用酚试剂比色法,检测醇酸调和漆样品涂刷后空气中甲醛浓度值随时间的变化规律,计算出相应的甲醛释放率,分析甲醛释放特征,并考察环境温度、空气置换率、环境相对湿度等主要环境因子对其影响,同时,建立了甲醛释放率的实测曲线,为建立预测装饰装修材料对室内空气质量影响的评价体系提供可靠数据依据.     

高层建筑水箱浸出有机物的GC/MS分析

采用高分子大网状吸附树脂(XAD)富集技术和GC/MS方法,对国内七种材料的水箱浸出有机物进行了分析,共计检出有机物百余种.根据测定结果可以判定,作为水箱的材质和涂料,水泥、SHZ-90瓷釉和玻璃钢是比较好的,其次为环氧树脂;聚胺酯和“青凝”涂料配方中都存在较大问题,应进一步改进;防锈漆问题最多,效果最差,应逐步淘汰.这一工作为合理地选择水箱材料和二次加压高层建筑供水设施的卫生学评价提供了科学依据.     

超滤膜材质对处理电泳漆液的影响

本文研究了聚砜，酞侧基聚砜，磺化聚砜，聚丙烯腈，醋酸纤维素，氰乙基醋酸纤维素，氯甲基化聚砜和季胺化聚砜等材质超滤膜的亲水性能，荷电性能以及它们对超滤阳极和阴极电泳漆液的影响，实验结果表明：亲水性较强，电负性较强的氰乙基醋酸纤维素和醋酸纤维素膜，适合用于处理阳极电泳漆液；而亲水性较强，电中性和电正性较强的氯甲基化聚砜和季胺化聚砜膜，则适合用于处理阴极电泳漆液。