哈尔滨冬季大气污染及逆温对污染物扩散影响

利用实际监测资料研究分析了哈尔滨市2000-2003年大气污染物的变化状况,和冬季重度污染发生的气候条件,特别指出了逆温持续性、强度、和层厚对大气污染扩散影响的正比关系,即逆温日数越多,超标污染日越多,逆温强度越大,污染越重的规律.     

对西北地区冰雹影响因子的探讨

利用1971～2000年西北185站3～9月逐月和年冰雹次数,分析了其空间分布特征和时间演变规律.西北年冰雹次数有三个中心,一个在青海的曲麻莱为19.6次,另一个在新疆西部的昭苏为17.6次,第三个在青海的刚察为12.7次.冰雹主要出现在6～8月,总站次的月变化呈单峰型,最大值出现在6月为20.5次,其次是7月为17.8次,再是8月为14.4次.总站次的历年变化呈现下降趋势,这与该地区平均气温的历年变化呈现出相反的趋势.冰雹次数与拔海高度呈显著的正相关,相关系数高达0.783 9;年冰雹次数与年平均气温呈显著的负相关,相关系数高达-0.701 6;年降水量与年冰雹次数呈正相关,降水量大,年冰雹次数也多.     

矿渣与工业废渣改良黄土的性能与机理研究进展

黄土在世界上分布面积较广,在我国也有约60×104 km2的分布,具有湿陷性是其区别于其它区域性土的最显著特点,并由此引发造成各种地质灾害和工程问题.采用石灰、水泥或高分子材料等对其进行改性以达到消除湿陷性或提高黄土强度的目的,是岩土工程领域的重要课题.选用矿渣和工业废渣作为改性参料,用以研究改性黄土的力学特性变化和改...     

Transfer assessment of carbendazim residues from rapeseed to oil production determined by HPLC–MS/MS

Abstract

It is crucial to develop practical procedures for the control and reduction of pesticide residues in oil productions from farm to dining table. In this study, the dissipation behaviors of typical fungicide from rapeseed to oil production were studied to reveal relationship among spraying stage, application dosage, household oil processing stage, and pesticide residues. In the field trials, rape plants were sprayed with carbendazim at three different dosages during flowering period. Transfer assessment of carbendazim residues from rapeseed to oil production during household oil processing via different press techniques was determined using high-performance liquid chromatography coupled with tandem mass spectrometry (HPLC–MS/MS). The recoveries of carbendazim in rapeseed samples, meals after squeezing samples, and rapeseed oil samples ranged from 82.5% to 93.6% with relative standard deviations (RSDs) ＜5.2%. The validation results illustrated that the methods were reliable and sensitive. The average processing factor (PF) during household oil processing via hot press technique and cold press technique was 0.15 and 0.51, respectively. This study demonstrated that household oil processing could significantly reduce the pesticide residues, especially by hot press technique.     

2,4-dichlorophenoxyacetic acid (2,4-D) micropollutant herbicide removing from water using granular and powdered activated carbons: a comparison applied for water treatment and health safety

Abstract

Activated carbons are well-known porous materials as an effective adsorbent used for the removal of emerging contaminants, such as herbicides, which are increasingly present in water bodies. Most water treatment plants, specially in Brazil, are unable to completely remove such contaminants by the conventional process and advanced treatment using activated carbons is required. The aim of this paper was to verify the influence of the activated carbons granulometry and specific surface area on the 2,4-dichlorophenoxyacetic acid (2,4-D) herbicide removal efficiency using distilled-deionized water and filtered water collected from a conventional Water Treatment Plant. Commercial activated carbons samples used in this work were obtained from two different manufacturers. Activated carbons were analyzed by the specific surface area, pore size and volume distribution, nuclear magnetic resonance, infrared and x-ray spectroscopy, moisture, volatile matter and ash contents. Batch adsorption isotherms experiments were used and performed by Langmuir and Freundlich models. Granular and powdered activated carbons removed over 99% of 2,4-D in distilled water and near to 99% using filtered water. The activated carbons evaluated in this work presented high performance and played a key role in water treatment by removing 2,4-D herbicide, ensuring the protection of human health and the ecosystem.     

Integration & assessment of recycling into c-Si photovoltaic module’s life cycle

Photovoltaic (PV) energy generation devices have experienced a vigorous growth in production over the last decade in all major industrialised countries. In this research paper, the assessment of recycling and subsequent production of new crystalline silicon (c-Si) PV modules taking advantage of the recovered Si in terms of industrial symbiosis is being examined. With the aid of life cycle analysis method, the potential payback is thoroughly examined through a scenario application in the second useful phase of the PV module. Furthermore, key environmental performance indicators have been implemented in order to evaluate power and resource demands.     

凹型建筑外立面火灾烟气蔓延特性研究

为了研究凹型建筑外立面火灾烟气蔓延特性，对高层建筑凹槽内火灾烟气“三场”数值模拟。研究表明:结构因子α（进深与槽宽之比）的变化导致凹型建筑结构内呈现不同的火灾烟气蔓延规律；当α为0~0.4时，建筑凹槽内的火灾烟气无烟囱效应；当α为0.6~1.2时，建筑凹槽内的火灾烟气呈现一定的烟囱效应，其火灾烟气温度场、CO浓度场、扩散速度场变化显著；当α>1.2的，建筑凹槽内的火灾烟气烟囱效应显著。     

东湖磷酸酶活力及其生态学意义研究

本文对东湖磷酸酶活力(PA)的来源,不同湖区活力水平的比较,及其与主要环境因子的关系作了初步研究。结果表明,东湖水柱中磷酸酶活力主要来自藻类,底泥中则主要来自细菌;在东湖磷浓度波动范围内,磷对碱性磷酸酶活力(ALPA)无明显抑制,实验室条件下相当于环境水平的磷浓度不能抑制PA;光照促进藻类PA的增加;溶解氧有利于藻类PA提高,对细菌PA则相反。     

中国区域能源效率对霾污染的空间效应——基于空间杜宾模型的实证分析

以中国29个省市自治区为研究对象，并以2001~2015年PM_2.5年度均值作为衡量霾污染的指标，构建了全要素能源效率对中国霾污染影响的空间杜宾模型.研究表明：中国绝大部分省市的霾污染演变趋势具有倒"U"的特点，这说明中国的霾污染在2001~2015年间经历了先上升后下降的总体变化趋势；无论是采用地理相邻权重还是经济权重，中国省际间的霾污染均存在显著空间集聚效应，这揭示霾污染的治理与控制需要地区间建立恰当的合作机制，避免出现"损人利己"现象；在对一系列经济社会因素控制的基础上，全要素能源效率对霾污染存在显著的负向影响并且具有显著的空间溢出效应，这表明全要素能源效率的提高不仅会显著降低本地区的霾污染水平，还将对周边地区的霾污染产生显著的负向影响；分解方程结果显示，技术进步和技术效率对霾污染的负向效应显著，并且技术进步的直接效应大于技术效率，但两者的间接效应均显著大于直接效应，这揭示了技术扩散对霾污染具有重要的潜在促降效应.因此，在治理霾污染的过程中，要通过不断优化能源结构和开发新能源技术以发挥全要素能源效率的减霾效果，以及通过地区间的交流与合作发挥技术扩散效应在霾污染治理中的作用.     

洱海沉积物重金属地球化学相及其污染历史研究

高原封闭、半封闭型湖泊是气候和环境演化的敏感指示器，其沉积物记录具有连续性、敏感性和高分辨率的特点。高原湖泊沉积记录在恢复和重塑各种短时间尺度（千年、百年、十年）的气候和环境演化序列上，具有其它自然历史记录无法替代的优势，尤其在揭示近代环境污染历史方面更有其独到之处。本文通过对洱海沉积物重金属地球化学相的研究，利用因子分析方法，识别了沉积物重金属的主要来源和影响其分布的主要因素，即：流域侵蚀作用、大气沉降作用、工业废水与生活污水的排放，以及早期成岩作用。同时，结合沉积物柱芯210PBex计年结果，本文初步评价了洱海150多年来的重金属污染历史：1958年以来．因为化石燃料使用量的增加．洱海湖区大气污染日趋严重；1982年后，由于西洱河水电站的建成运行和湖区植被的破坏，流域侵蚀作用显著加强，应当引起重视。