Evaluation of the spontaneous combustion characteristics of coal of different metamorphic degrees based on a temperature-programmed oil bath experimental system

Research on the micro- and macrocharacteristics of different metamorphic degrees of coal helps improve the control and protection techniques used during spontaneous combustion. Nine coals with different properties were thoroughly investigated in this study. Fourier transform infrared spectroscopy and a self-designed temperature-programmed oil bath experimental system were adopted to analyze the molecular structure and macrocharacteristic parameters of the spontaneous combustion of coal. Additionally, the influence of particle size on spontaneous combustion was considered. Various functional groups were employed as microcharacteristic parameters to capture the principal active groups in oxidation. The gas production rate, oxygen consumption rate, gas concentration, heat energy release rate, and characteristic temperatures were evaluated as macrocharacteristic parameters to investigate the changes in coal during oxidation. The results establish that the microcharacteristics of coal molecules determine the degree of spontaneous combustion based on intrinsic properties and that changes in the macrocharacteristics of the spontaneous combustion of coal reflect the microstructural changes. The contents of the hydroxyl groups, carbonyl groups, alkyl ether and aryl ether in the coal molecules gradually decrease with the metamorphic increase. Oxygen-containing functional groups have higher reactivities and easily react with oxygen, causing the macroparameters, such as the oxygen consumption rate, the gas generation rate and the heat energy release rate, to consistently decrease with the increase of the metamorphic degree. Small-particle-size coal molecules have more active aliphatic hydrocarbons, oxygen-containing functional groups and a larger specific surface area, increasing the chances of adsorbing the oxygen of active groups and promoting the reaction between coal and oxygen. The experimental results indicate that coal samples with higher metamorphic degrees or larger sizes exhibit lower tendencies toward spontaneous combustion. Evaluation of the spontaneous combustion of coal based on a temperature-programmed oil bath experimental system is of great practical importance for preventing the spontaneous combustion of coal during storage, processing and utilization and can serve as a convenient reference for production safety in mining applications.     

驾驶机舱LED灯光色温与人员警觉度关系仿真实验研究

为了探讨驾驶机舱内LED灯光色温与人员警觉度的联系,在A320模拟驾驶舱内设置2 500～2 700 K,3 000～3 200 K,6 000～6 500 K 3种不同色温的LED灯光环境,采用卡斯罗林嗜睡量表（KSS）、闪光融合临界频率仪（CFF）、视觉舒适度评分量表（VCS）,对5名被试人员在不同灯光环境的疲劳程度和视觉舒适度进行实时测量。针对测量结果,采用方差分析及描述性统计的数据分析方法,评价被试人员于不同灯光环境下的疲劳程度、视觉舒适度的差异性及变化情况。研究结果表明:高色温LED灯光环境下,人员的主观嗜睡感受及客观疲劳感受较低,且有着较低的疲劳感受增长率;高色温LED光源下人员的视觉舒适度也较高;增高LED灯光色温可一定程度上提升人员的警觉性。     

两性聚丙烯酰胺的制备研究

本文研究了丙烯酰胺（ＡＭ）－丙烯酸（ＡＡ）共聚物的水溶液，经Ｍａｎｎｉｃｈ反应制备两性聚丙烯酰胺的反应条件，讨论了影响胺化度的因素。实验结果表明：分子量为３００万、阴离子度为２０％、浓度为２．５％的共聚物，在原料配比为（ＡＭ－ＡＡ）：ＨＣＨＯ：ＮＨ（ＣＨ３）２＝１：１．１：１．５、反应温度为５０±１℃、反应２ｈ的条件下，制得的两性聚丙烯酰胺的胺化度为４２．５％，是最佳的合成条件。用氯化胺和盐酸季胺     

南京地区农业资源的综合评价研究

客观、准确地评价地区农业资源,对于农业资源的开发和利用具有重要意义。本文从系统论观点出发,将地区农业资源分成自然资源和社会资源,在能够较好地反映系统结构特征、不同样点差异及满足易于收集、便于数量表示和定量处理等基本要求的基础上,选择了若干评价指标。利用综合指数法、区位商法等评价方法,对南京地区的主要农业资源（土地资源、气候资源与社会资源）进行了定量分析,并在此基础上,利用资源优势度分析法进行了综合评价。结果表明,南部小区的农业资源具有整体优势,南部和中部的资源利用较为合理,北部小区则具有较为丰富的后备资源。最后,根据各地资源要素的不同组合,简要给出了较适宜的开发途径,为该地农业资源的进一步开发与利用提供了依据。     

河流水质的动态马尔柯夫评价

根据马尔柯夫过程的原理,在水质级别评价结果的基础之上,构造水质变化的概率转移矩阵,并对转移概率赋权计算绝对进步度,然后在此基础上引出相对进步度的概念,用相对进步度来评价河流水质在一段时期内的变化程度.运用该方法计算了中国四大河流2005年的水质相对进步度,并对计算结果进行了分析.     

污水在水体中的稀释扩散及稀释度的计算

结合长江白龙港水域水力模型试验对污水排海工程中污水稀释扩散的机理进行了描述，并对污水的两种稀释度（浓度释稀度和体积稀释度）进行了分析比较，得出了在污染物本底值存在时两种稀释度之间的关系。     

Transformational leadership and employee voice behavior: A Pygmalion mechanism

We theorized and examined a Pygmalion perspective beyond those proposed in past studies in the relationship between transformational leadership and employee voice behavior. Specifically, we proposed that transformational leadership influences employee voice through leaders' voice expectation and employees' voice role perception (i.e., Pygmalion mechanism). We also theorized that personal identification with transformational leaders influences the extent to which employees internalize leaders' external voice expectation as their own voice role perception. In a time‐lagged field study, we found that leaders' voice expectation and employees' voice role perception (i.e., the Pygmalion process) mediate the relationship between transformational leadership and voice behavior. In addition, we found transformational leadership strengthens employees' personal identification with the leader, which in turn, as a moderator, amplifies the proposed Pygmalion process. Theoretical and practical implications are discussed. Copyright © 2016 John Wiley & Sons, Ltd.     

基于AHP和比较可能度关系的列控车载系统安全可靠性分析

列控车载系统是保证行车安全的重要系统,其对安全可靠性的要求极高。从人、机和环境3个方面,针对列控车载系统的特点,在分析列控车载系统各安全影响因素的基础上,利用层次分析法建立各影响因素间的关联关系,并充分考虑指标环境的不确定性和决策者思维的模糊性,构建三角模糊数互补判断矩阵。其次,运用三角模糊数比较可能度关系理论,集结所有指标比较的可能度,构建可能度关系比较矩阵。利用三角模糊数矩阵转换关系将可能度关系比较矩阵转换为模糊一致性判断矩阵,在此基础上求解各指标的各层单排序及总排序向量。最后,结合具体算例指出列控车载系统安全可靠性的关键影响因素,以及实际运行当中可能存在的问题并提出决策优化建议。     

碳减排路径模式选择研究——基于私家车管控的个人碳交易和碳税比较

为了研究大城市私家车碳减排的有效路径,引入个人碳交易概念,提出管控大城市私家车碳排放的设想,制定了个人碳交易管理办法基本内容;运用Cobb-Douglas效用函数建立了管控大城市私家车个人碳交易和碳税的经济模型,依托调研数据定量化研究交通领域的个人碳交易机制,运用Matlab软件绘制了个人碳交易和碳税方案的适用范围图形,并对二者的减排效果进行比较。结果表明:个人碳交易与碳税都可以使消费者减少实际行车里程并保证总效用的增加,个人碳交易比碳税更容易为消费者接受,并能够达到碳减排的效果;在消费领域碳减排初期、社会减排任务量不大时,个人碳交易优于碳税,当减排任务很大时,碳税政策更为有效;碳减排量对消费者刚性需求的影响决定着个人碳交易制度的接受程度。应在北京、上海等大城市或其他城市的拥堵区域试行个人碳交易管控大城市私家车出行的制度,并开展实施细则的研究。