Thiolsulfonate functionalized polystyrene resin： Preparation and application in the isolation and identification of electrophilic mutagens

A new approach for isolation and identification of elecrtophilic mutagens from complex matrix was developed.Thiosulfonic anion was immobilized onto polystyrene beads and used as separation media.Potassium polystyryl-thiosulfonate,prepared from polystyryl- sulfonyl chloride and KHS,was observed to selectively react with model electrophilic mutagens such as alkyl halides,α-chloroketones andα-chloroesters to produce polystyryl-thiosulfonic esters.After separation from other nonreactive organic compounds,the beads then reacted with ethanethiol to produce unsymmetrical ethyl disulfides which are easily detected by GC/MS.For one mutagenic compound,only one unsymmetrical disulfide was found to contain its structure part.Thus,the structure of the parent mutagens could be deduced from that of the unsymmetrical disulfides.The degree of functionaiization of the potassium polystyryl-thiosulfonate resin was 1.11 mmol/g.Its reactivity was discussed and its recycling method was reported here.     

中国土地退化的分类与分级

在参照国际上土地退化评价指标体系的基础上,结合中国实际,从代表性、普遍性和可操作性原则出发,提出了中国土地退化的初步分类与分级标准。中国土地退化可划分为风蚀作用下的土地退化、水蚀作用下的土地退化、物理退化和化学退化4类,土地退化程度分为轻度、中度、强度和极强度退化4级,并拟定4类土地退化的评价标准。     

A review on analytical methods for pharmaceutical and personal care products and their transformation products

Pharmaceutical and personal care products (PPCPs) and corresponding transformation products have caused widespread concern due to their persistent emissions and potential toxicity. They have wide octanol-water partition coefficients (K_ow) and different ionization constants (pK_a) resulting in a poor analysis accuracy and efficiency. A suitable analytical method is the first prerequisite for further research on their environmental behavior to prioritize the substances. This study reviewed a full-scale analytical protocol for environmental samples in the recent ten years: from sampling to instrumental methods. Passive sampling techniques were compared and recommended for long-term continuous and scientific observation. A quick and effective sample extraction and clean-up method are highly required. Chromatographic methods coupled to mass spectrometry for determining PPCPs with a wide range of logK_ow (?7.53 to 10.80) were summed up. High-resolution mass spectrometry was confirmed to be a promising strategy for screening unknown transformation products, which would provide a nanogram level of detection limits and more accurate mass resolution. Screening strategies and mass change principles were summarized in detail. The recovery rate was important in multiple contaminants analysis identification and factors affecting the recovery rate of PPCPs were also discussed in this review, including sample matrix, target compounds characteristics, extraction method and solid-phase adsorbent. This review provides useful information for the selection of appropriate analytical methods and future development directions.     

船舶溢油事故等级评估方法比较

船舶溢油事故等级评估是船舶溢油应急计划研究的重要内容,它受到溢油量、事故发生位置等多种因素的影响,是复杂的多属性分类问题.利用熵值法、关联度法和BP神经网络法3种目前常用的事故等级评估方法,对上海港1984─2003年发生的12起船舶溢油事故进行了危害等级判定,以期探索溢油事故等级合理量化评估技术方法.对比了3种方法在结果一致性、误差精度上的优劣性及实际适用性.结果表明:BP神经网络和关联度法适用性较好,熵值法必须结合专家打分才能得到较好的判定结果;同时BP神经网络法的评估结果一致性比率较高,误差率较低,但存在建模成本高和对噪声较敏感的缺点.      

石首天鹅洲六合垸扩大麋鹿栖息地初析

自石首麋鹿国家级自然保护区设立以来,麋鹿种群得到了有效发展。因各种因素综合作用,现有保护区已呈现容纳量不足的趋势。相较其它湿地,依据岛屿生物地理学“平衡理论,”与麋鹿保护区相连通的六合垸似乎在扩大麋鹿栖息地方面具有地理优势。文章侧重从景观学(形状、连接度、廊道构建)及社会(移民)两个角度对其优势度状况作尝试性分析,进而得出六合垸并不具有明显优势的初步结论。     

冷冻取芯过程煤芯瓦斯解吸特性试验研究

为探究冷冻取芯过程煤芯瓦斯解吸特性,基于模拟试验的相似性,依托自主研发的含瓦斯煤冷冻取芯响应特性测试平台,开展不同变质程度煤样(长焰煤、贫瘦煤、无烟煤)及不同吸附平衡压力(1.0,2.0,3.0,4.0 MPa)下冷冻取芯过程煤芯瓦斯解吸特性试验研究。研究结果表明：冷冻取芯过程中,煤芯瓦斯解吸量与吸附平衡压力及煤变质程度呈正相关关系;在煤芯瓦斯解吸过程中存在倒吸现象,煤与瓦斯初始吸附平衡压力越大,煤的变质程度越高,倒吸开始时间越迟;冷冻取芯过程中,瓦斯解吸速度与吸附平衡压力及煤变质程度呈正相关关系,且瓦斯解吸速度随吸附平衡压力及煤变质程度变化曲线符合幂函数关系。     

智慧工地本质安全度评价方法研究

为对智慧工地全生命周期的本质安全度进行分析与评价,综合运用本质安全理论,构建智慧工地本质安全度评价模型。首先,根据智慧工地本质安全定义,将智慧工地本质安全度划分为初始级、简单级、标准级、成熟级和卓越级5个等级;其次,基于智慧工地的生产现状,构建包括人员管理系统、机械设备管理系统、现场监测预警系统、过程控制管理系统等4个一级指标和16个二级指标的本质安全度评价指标体系;最后,利用C-OWA算子对指标的权重进行计算,采用未确知测度评价法对系统进行综合评价。结果表明:将模型应用到西安地铁某在建项目中,得到该智慧工地项目现阶段推进状态本质安全度等级为标准级,明确该项目下一阶段提升改进的方向,为智慧工地本质安全管理的持续改进提供理论支持。     

海上溢油事故等级的综合评定

在综合分析影响溢油事故威胁程度有关的诸多因素的基础上，提出使用模糊神经网络技术来确定各影响因素的权重，进而使用模糊综合评价的方法来评定溢油事故的威胁程度及等级，为进一步的溢油事故应急决策奠定基础。     

装甲车辆舱室湿度调节系统设计与研制

目的设计研制舱室湿度调节系统,用于开展装甲车辆舱室热舒适性测试与评价技术研究。方法通过任务计算机设定实验任务,并将湿度目标值通过RS485总线传输给PLC控制器,由PLC控制器控制加湿机和除湿机工作,同时由湿度传感器对舱室内的湿度进行实施监控,达到目标值后,进行加湿和除湿的动态控制。结果该系统可实现20%～95%舱内湿度调节。结论为开展装甲车辆舱室湿热环境研究奠定实验基础。     

基于逻辑框架法和成功度评价的生态补偿政策评估与动态调整研究

生态补偿政策效果的发挥有赖于科学、合理的制度设计,制度设计不仅仅指制度建立之初的设计,还包括制度实施过程中的实施评估及其优化调整,本文选择在生态补偿政策实施一个阶段后,利用逻辑框架法从宏观目标、直接目的、政策产出和政策投入四个层次分析生态补偿政策的实施过程及其效果,进而利用成功度评价法,设计生态补偿成功度评价指标体系,并利用该指标体系评估出中山市生态补偿政策实施的成功度综合等级为0.866,属完全成功。基于前述研究,提出下一阶段中山市生态补偿政策调整的重点。