Molecularly imprinted polymer for analysis of trace atrazine herbicide in water

A molecularly imprinted polymer (MIP) for atrazine was synthesized by non-covalent method. The binding capacity of MIP was 1.00 mg g^{? 1} polymer. The selectivity and recovery were investigated with various pesticides which are mostly, found in the environment, for both similar and different chemical structure of atrazine. The competitive recognition between atrazine and structurally similar compounds was evaluated and it was found that the system provided highest recovery and selectivity for atrazine while low recovery and selectivity were obtained for the other compounds. The highest recovery was obtained from MIP compared with non-imprinted polymer (NIP), a commercial C₁₈ and a granular activated carbon (GAC) sorbent. The method provided high recoveries ranged from 94 to 99% at two spiked levels with relative standard deviations less than 2%. The lower detection limit of the method was 80 ng L^{? 1}. This method was successfully applied for analysis of environmental water samples.     

Study on evaluation and optimization of ecological service efficiency of urban greenbelt system： A case study of Huai＇an ecological new town

通过运用生态服务效能指数的概念,选择5种指标因子（吸收二氧化硫量、吸收热量、蒸腾水量、涵养水源量、滞尘降尘量）构建了淮安生态新城绿地系统生态服务效能评估模型,并运用全排列多边形图示指标法,针对“现状条件”、“概念规划”、“控制性详细规划”、“理想状态”4种情景下的绿地系统进行了生态服务效能评价与预测．结果表明,4种不同的土地利用方式下,绿地系统生态服务效能综合指数分别为0．24、0．56、0．70和0．89,生态服务效能逐步改善．研究结果进一步表明,在“概念规划”和“控制性详细规划”两种情景下,应使城市绿地系统面积大于1200hm^2,采用复合式绿地结构并调整林地与草地面积的比例达到7：3,同时应保证本地植物指数大于70％,研究结果可为生态城市建设提供一定的参考．     

改进测定水中氨氮分子吸收光谱法的试验研究

水中氨氮含量是反应水质状况的重要指标。文章对测定水中氨氮气相分子吸收光谱法(标准号HJ/T195-2005)进行了改进试验研究。第一,对氧化剂的配比进行了改进,使氨氮的测定范围扩展至100μg。第二,对标准HJ/T195-2005中直接使用亚硝酸钠标准溶液做标准曲线的处理方式也做了探讨。通过一系列对比实验认为,应用硫酸铵标准溶液做工作曲线更加准确合理。最后应用改进后的气相分子吸收光谱法和纳氏比色法或滴定法对多种实际废水样品进行同时测定。结果表明,改进后的气相分子吸收光谱法测定氨氮的范围更宽,灵敏度更高和准确度更好。     

植物释放挥发性有机物(BVOC)向二次有机气溶胶(SOA)转化机制研究

利用自制玻璃生态罩,研究植物挥发性有机物（BVOC）的释放机制.在紫外光诱导条件下,BVOC经历一系列的光氧化反应,最终产生了二次有机气溶胶（SOA）.运用固相微萃取（SPME）和气相色谱-质谱联用（GC-MS）技术,对目标植物（驱蚊草）释放出的BVOC进行采样分析,共检测出7种主要化合物,其中主要为单萜类、倍半萜类、醇类和酮类物质.研究发现,在紫外光的照射下,这些BVOC可以发生光氧化反应转化为SOA.利用串联差分淌度分析仪（TDMA）测定SOA的粒径分布和SOA颗粒物的吸湿性.结果表明粒径范围大致是50～320 nm,吸湿性研究发现这些SOA具有吸湿性,生长因子可以从1.05增长到1.11.     

Study of metabolites from the degradation of polycyclic aromatic hydrocarbons (PAHs) by bacterial consortium enriched from mangrove sediments

The PAH metabolites produced during degradation of fluorene, phenanthrene and pyrene by a bacterial consortium enriched from mangrove sediments were analyzed using the on-fiber silylation solid-phase microextraction (SPME) combining with gas chromatography–mass spectrometry (GC–MS) method. Seventeen metabolites at trace levels were identified in different PAH degradation cultures based on the full scan mass spectra. In fluorene degradation cultures, 1-, 2-, 3- and 9-hydroxyfluorene, fluorenone, and phthalic acid were detected. In phenanthrene and pyrene degradation cultures, various common metabolites such as phenanthrene and pyrene dihydrodiols, mono-hydroxy phenanthrene, dihydroxy pyrene, lactone and 4-hydroxyphenanthrene, methyl ester, and phthalic acid were found. The detection of various common and novel metabolites demonstrates that SPME combining with GC–MS is a quick and convenient method for identification as well as monitoring the real time changes of metabolite concentrations throughout the degradation processes. The knowledge of PAH metabolic pathways and kinetics within indigenous bacterial consortium enriched from mangrove sediments contributes to enhance the bioremediation efficiency of PAH in real environment.     

Phytoremediation of Cadmium-Contaminated Soils by Rorippa globosa Using Two-Phase Planting (5 pp)

Background Phytoextraction of contaminated soils by heavy metals can provide a great promise of commercial development. Although there are more than 400 species of hyperaccumulators found in the world, phytoremediation technology is rarely applied in field practice for remedying contaminated soils, partially due to low biomass and long growth duration for most of discovered hyperaccumulating plants. In order to enhance the metal-removing efficiency in a year, the two-phase planting countermeasure of phytoextraction by harvesting anthesis biomass was investigated on the basis of the newly found Cd-hyperaccumulator Rorippa globosa (Turcz.) Thell. with 107.0 and 150.1 mg/kg of the Cd accumulation in stems and leaves, respectively, when soil Cd added was concentrated to 25.0 mg/kg. Methods The field pot-culture experiment was used to observe the distribution property of R. globosa aboveground biomass and to examine characteristics of accumulating Cd by the plant at different growth stages. The concentration of Cd in plants and soils was determined using atomic absorption spectrophotometry (AAS). Results and Discussion The results indicated that the total dry stem and leaf biomass of R. globosa harvested at the flowering phase was up to 92.3% of that at its full maturity and the concentration of Cd in stems and leaves harvested at the flowering phase was up to 73.8% and 87.7% of that at the mature phase, respectively. The Cd-removing ratio by shoots of R. globosa harvested at the flowering phase was up to 71.4% of that at the mature phase. It was also found, by observing the growth duration of R. globosa, that the frostless period at the experiment site was twice as long as the growth time from the seedling-transplanted phase to the flowering phase of the hyperaccumulator. Conclusion R. globosa could be transplanted into contaminated soils twice in one year by harvesting the hyperaccumulator at its flowering phase based on climatic conditions of the site and traits of the plant growth. In this sense, the extraction efficiency of Cd in shoots of R. globosa increased 42.8% compared to that of at its single maturity when the plant was transplanted into contaminated soils after it had been harvested at its flowering phase and the plant accumulated Cd from soil at the same extraction ratio at its second flowering phase. Thus, the method of anthesis biomass regulation by the two-phase planting is very significant to increase the Cd-removing efficiency by phytoremediation used in practice over the course of a year. Recommendation and Outlook As for some hyperaccumulators that the growth duration from the seedling-transplanted phase to the flowering phase are short and the concentrations of heavy metals accumulated in their shoots at the flowering phase are high, the efficiency of phytoremediation can greatly be improved using the method of the two-phase planting.     

连续起伏管道投产过程中的气相运移研究*

为应对山区液体管道在投产过程中可能出现的气阻、超压问题,从气相运移角度出发,建立液顶气模型,研究在1个U型单元内积气形成、压缩和破碎的全过程,在此基础上,提出连接各个U型单元的气相的传递函数,探讨背压累积因素下,连续起伏管道投产过程中各个U型管段的积气情况和压力的变化,进行动态的建模和计算。以国内某原油管道的现场投产数据与模型结果进行比对。结果表明:可以更加准确地预测山区液体管道投产过程中的气相传递和压力变化过程,能为未来连续起伏大落差液体管道投产的安全稳定运行提供理论指导和技术支持。     

基于偏序集的采空区塌陷危险性评价研究

针对采空区塌陷危险性评价方法中的赋权争议问题,基于偏序集理论提出偏序集评价模型。首先阐明评价指标并确定其分级标准;然后应用偏序集评价模型得到Hasse图,并通过图展现的层集信息判别采空区塌陷危险程度;最后应用该模型对大宝山矿11个采空区的塌陷程度进行判别,评价结果准确合理。研究结果表明:该模型避免了以往研究中的赋权争议问题,克服了样本量不足致使模型无法应用的问题,而且能够应用更多的赋权方法识别排序的稳定程度,体现出样本间的分层信息。     

基于重构相空间充填体变形规律的灰色预测研究

尾砂胶结充填体是非线性力学介质,其变形是能量耗散的复杂过程,必须研究其内在变形规律,才能正确预测采矿过程中充填体的稳定性.对不同配比的尾砂胶结充填体进行力学试验,得出了其应力-应变规律,对安庆铜矿高阶段充填体变形进行了监测.采用自适应滤波原理,研究基于重构相空间的测量数据去噪处理方法.用灰色理论研究充填体变形在相空间中相点距离的演变规律,建立了重构相空间的灰色预测模型.为减小预测误差,对预测结果采用残差模型修正.应用建立的模型,对安庆铜矿高阶段充填体变形进行分析,确定了采场合理回采周期.结果表明,充填体变形具有非线性混沌特性,不同配比的充填体表现出不同的非线性动力学行为,重构相空间能充分展示充填体变形的内在规律.     

基于CFD-DEM的旋风除尘器内气固流动特性研究

为了研究旋风除尘器内气固流动特性,采用CFD-DEM耦合算法研究不同入口气体速度下旋风除尘器内颗粒流态、静压、径向速度及轴向速度分布特征。结果表明:煤屑颗粒在离心力和径向曳力的作用下以螺旋颗粒条带靠近除尘器的壁面稳定向下移动,随着入口风速的增加煤屑颗粒条带变宽,条带与除尘器的第1次接触的拐点上移,螺距减小;除尘器内部压力轴向变化较小,径向变化较大,随着入口气体速度增加,除尘器壁面附近高压区范围和压力也随之增加,除尘器上方和下方的负压区变宽并朝轴向方向延伸;随入口气体速度增加,除尘器内径向速度和轴向速度逐渐增加,煤屑颗粒在除尘器中部聚集较多,煤屑停留时间变长,入口气体速度为15 m/s时,煤屑颗粒在除尘器内停留时间最长。