天然沸石中离子交换平衡的离子特异性研究

沸石在改良土壤和保护环境等方面有着广泛的应用,研究沸石离子交换中的特异性效应对更好地利用沸石有着重要意义.碱金属离子在天然斜发沸石中的交换平衡时的最大吸附量存在着明显的特异性效应;对于同价的碱金属离子,其交换吸附能力差异随着离子浓度的降低而增大.这种实验现象不能用库仑力、离子体积、水合作用、色散力、经典诱导力以及表面络合等相关理论进行完整解释.分析发现,根本原因来自离子因量子涨落而产生的极化与沸石颗粒表面电荷产生的强电场之间的相互作用,这种相互作用导致了离子间偶极矩差异随着表面电位的升高而增大,进而使离子-表面吸附能差异增大,并出现不同的交换吸附能力.由于沸石表面电荷密度较高,离子体积效应对其在双电层中的分布也起着比较重要的作用,导致碱金属离子在沸石表面的交换平衡结果在高表面电位(绝对值大于0.2 V)下才表现出较大选择性,与低电荷密度表面上的交换平衡结果存在一定差异.     

Economic analysis of atmospheric mercury emission control for coal-fired power plants in China

Coal combustion and mercury pollution are closely linked, and this relationship is particularly relevant in China, the world's largest coal consumer. This paper begins with a summary of recent China-specific studies on mercury removal by air pollution control technologies and then provides an economic analysis of mercury abatement from these emission control technologies at coal-fired power plants in China. This includes a cost-effectiveness analysis at the enterprise and sector level in China using 2010 as a baseline and projecting out to 2020 and 2030. Of the control technologies evaluated, the most cost-effective is a fabric filter installed upstream of the wet flue gas desulfurization system (FF + WFGD). Halogen injection (HI) is also a cost-effective mercury-specific control strategy, although it has not yet reached commercial maturity. The sector-level analysis shows that 193 tons of mercury was removed in 2010 in China's coal-fired power sector, with annualized mercury emission control costs of 2.7 billion Chinese Yuan. Under a projected 2030 Emission Control (EC) scenario with stringent mercury limits compared to Business As Usual (BAU) scenario, the increase of selective catalytic reduction systems (SCR) and the use of HI could contribute to 39 tons of mercury removal at a cost of 3.8 billion CNY. The economic analysis presented in this paper offers insights on air pollution control technologies and practices for enhancing atmospheric mercury control that can aid decision-making in policy design and private-sector investments.     

陆军基地化训练雷达干扰威胁环境构设方法研究

目的研究陆军基地化训练中雷达干扰威胁环境构设方法,重点研究对地面机动目标的威胁环境构设方法。方法从功率等效和空间等效两方面着手,运用干扰信号模拟器抵近目标目标构设雷达干扰环境。结果针对机动目标,给出了两种思路的构设方法,并对其优劣进行了比较。结论通过对构设方法及构设逼真度的研究,明确了实现构设方法的关键在于保证训练场上的装备数据采集和训练场电磁环境监测的实时性和准确性。     

铝在红沿河核电厂地区的初期大气腐蚀表征

目的研究铝在辽宁红沿河核电厂地区的初期大气腐蚀行为。方法按GB/T 6464—1997,将制备好的试样在红沿河核电厂进行大气暴露试验,利用XRD,FTIR,SEM分析技术,对试验6个月和10个月的试样进行腐蚀产物观察与分析。结果铝在红沿河大气暴露腐蚀6个月和10个月样品表面均布满了点蚀坑、腐蚀产物及沉积物,腐蚀产物主要为Al2O3,Al OOH以及一些含氯和含硫的铝盐。腐蚀产物都较疏松,上下表面均有龟裂纹,相邻较近的点蚀坑已相互连接。随腐蚀时间延长,点蚀坑变深变大,朝地面点蚀坑深度已达上百微米。结论铝在红沿河核电厂大气环境中腐蚀以点蚀为主要特征,其腐蚀比普通大气环境中的严重,朝地面的腐蚀比朝天面严重,大气中氯离子及SO2参与铝的腐蚀过程并起促进作用。     

2011—2013年广州市道路交通噪声监测与分析

在2013年10—12月期间,选取了广州市58条道路和20栋噪声敏感建筑物进行噪声监测,与2011—2012年监测数据相比较,综合分析了广州市道路交通噪声的现状和变化规律。分析表明:广州市昼夜道路交通噪声以71 d B和70 d B为中心上下波动。对于2013年监测数据,噪声敏感建筑物昼夜噪声均值为65.1 d B和64.6 d B,夜间最大突发噪声均值为80.7 d B。此外还计算了每条道路的昼夜噪声频率重心,结果显示,广州市道路昼夜交通噪声频率重心分布基本相同,以1 000~2 000 Hz最为集中。     

An executive review of sludge pretreatment by sonication

Ultrasonication (US), which creates hydro-mechanical shear forces in cavitation, is an advanced technology in sludge pretreatment. However, there are many factors affecting the efficacy of cavitation and ultrasonication disintegration of sludge as a consequence. The objective of this work is to present an extensive review of evaluation approaches of sludge US pretreatment efficiency. Besides, optimization methodologies of related parameters, the differences of optimum values and the similarities of affecting trends on cavitation and sludge pretreatment efficiency were specifically pointed out, including ambient conditions, ultrasonic properties, and sludge characteristics. The research is a prerequisite for optimization of sludge US pretreatment efficiency in lab-scale and practical application. There is not-yet a comprehensive method to evaluate the efficiency of sludge US pretreatment, but some main parameters commonly used for this purpose are degree of sludge disintegration, proteins, particle size reduction, etc. Regarding US parameters, power input P_US, intensity I_US, and frequency F_S seem to have significant effects. However, the magnitude of the effect of P_US and probe size in terms of I_US has not been clearly detailed. Investigating very low F_S seems interesting but has not yet been taken into consideration. In addition, static pressure effect has been marginally studied only and investigation on the effect of pH prior to US process has been restricted. Their effects therefore should be varied separately and simultaneously with other related parameters, i.e. process conditions, ultrasonic properties, and sludge characteristics, to optimize sludge US pretreatment process.     

含油污水海洋处置的混合区范围界定探讨

本文建立深度平均二维对流扩散模型进行含油污水排海的浓度场数值模拟,根据各时刻的最高瞬时浓度,得出了远区混合区的范围.利用验证良好的水动力模型的计算结果,Cormix模型选择最小的潮流流速,计算了近区混合区范围,并在计算机控制的潮汐流动水槽中进行了系统的排污试验,计算结果与试验值符合性良好.结合远区和近区模型的模拟结果,最终确定了混合区的位置、范围,为含油污水排海工程的混合区范围确定提供了一种较为高效、实用的解决途径.     

特高压输变电工程环境影响评价公众参与工作程序细化研究

公众参与工作程序的合法性和有效性,直接影响特高压输变电工程环境影响评价工作质量,不仅关系到公众对环境保护的参与权、知情权和监督权,还关系到项目能否顺利取得环境行政许可.结合特高压输变电工程环境影响评价公众参与工作实际,细化环境影响评价信息第一次公告、报告书简本公示、第二次公告、征求公众意见、报告书受理公示及审批公示完成时序,规范公众参与一般工作程序及变更工作程序.     

杭州市典型共站移动通信基站周围电磁环境影响调查与研究

在4G基站快速增加的背景下,基站共站已成为较为普遍的架设方式.根据移动通信基站的发展趋势和工作原理,选取典型共站的移动通信基站,按照测量规范进行布点,了解基站周围电场强度的大小、楼顶架设基站的建筑物内部电场强度,以及周围建筑物室内的电场强度垂直方向的变化规律.分析结果表明,只要基站选址合理,天线面板角度与高度能尽量避开周围环境保护目标的方向,共站的基站运营时周围环境的电磁辐射水平可以满足相应的评价标准,不会对周围的环境造成明显的影响.     

海上油田开发清洁生产定量评价与实例分析

本文以渤海湾某海上油田的实际值为例,采用层次分析法和模糊数学评价法,对海上油田开发过程中的清洁生产做了定量的评价,根据评价结果确定评价等级,本文可以为海上油田清洁生产评价体系的研究提供参考,同时可以为环境保护和可持续发展提供依据.