贵金属催化剂活性组分分布对催化湿式氧化处理非达霉素提炼废水的影响

采用均匀型和蛋白型Ru/TiO₂催化剂为湿式氧化催化剂,应用于催化湿式氧化非达霉素提炼废水,以出水COD和TOC去除率作为指标来评价2种催化剂的催化活性差异;采用实验室连续评价装置对柱状颗粒催化剂在不同pH、不同废水流量和不同温度下处理非达霉素提炼废水进行了优化评价。结果表明：在265 ℃、pH=4.1、废水流量为10 mL·h⁻¹时,催化剂的催化活性最高,故确定此条件为该废水处理的最优条件;同时对比均匀型和蛋白型2种催化剂,蛋白型催化剂具有更高的催化效率;结合SEM及N₂-物理吸附结果,推断蛋白型催化剂活性组分集中分布在催化剂颗粒的较浅层,有利于降低反应过程中的扩散阻力,提高贵金属活性组分的利用率,进而提高催化剂的催化活性。以上结果对开发高效湿式氧化催化剂,充分利用贵金属活性组分降低催化剂成本具有十分重要的意义。     

成都平原核心区土壤砷空间变异特征及影响因素

掌握土壤污染物的空间变异特征及其影响因素是开展土壤污染防治的前提.基于189个表层(0～20 cm)土壤样品,运用经典统计学和地统计学方法分析了成都平原核心区土壤中w(As)的空间分布特征,并探讨了成土母质、水系和土地利用方式对土壤中w(As)的影响.结果表明:①研究区土壤中w(As)在3.74～35.32 mg/kg之间,平均值为14.64 mg/kg其中超过GB 15618—2018《土壤环境质量农用地土壤污染风险管控标准(试行)》风险筛查值的采样点仅占总采样点的7.53%.②地累积指数分析结果表明研究区土壤As处于无污染至轻度污染状态.③研究区土壤中w(As)总体呈西高东低的趋势,高值主要分布在都江堰市的南部、崇州市的东北部以及邛崃市与新津县接壤处.土壤As的块金系数为26.60%,属于中等程度变异,受结构性因素和随机性因素的共同影响.④由于人类活动的增强,成土母质对土壤中w(As)的影响已经不显著.距水系越近,土壤中w(As)越高.土地利用方式对土壤中w(As)空间变异的影响程度最大,不同土地利用方式下土壤中w(As)差异显著表现为园林地>农林地>水稻-小麦轮作&g...     

生态调控后贵州花溪水库浮游植物群落结构的变化特征及影响因素

为了解生态调控后花溪水库浮游植物功能群变化特征与环境因子的关系,基于浮游植物功能群、NMDS(非度量多维尺度分析)、RDA(冗余分析)、Pearson相关性分析方法,于2017年3月—2018年3月逐月对浮游植物群落结构与水环境指标进行采样分析.结果表明:①生态调控前,花溪水库共鉴定浮游植物4门18种,共归类出10个功能群,且功能群H1占绝对优势,其代表藻种为水华束丝藻(Aphanizomenon flosaquae);生态调控后,共鉴定浮游植物6门66种,共归类出20个功能群,主要优势功能群为B/Lo,其代表藻种为小环藻(Cyclotella sp.)和多甲藻(Peridinium sp.).②生态调控后,花溪水库优势功能群结构发生了变化,其变化特征为B/Lo(春季)→D/B/Lo/X2/N/P(夏季)→D/B/Lo/N(秋季)→D/MP/B/Lo/W1/W2(冬季).功能群B的生物量在春季达到峰值(3 056.3μg/L),与其对低营养环境有良好的耐受性有关;功能群Lo的生物量在秋季达到峰值(2 900.9μg/L),与组成功能群Lo的甲藻特性有关.③RDA结果表明,生态调控前影响...     

黑臭水体综合整治案例分析——以海口市美舍河为例

阐述了海口市的母亲河——美舍河黑臭的主要原因以及整治工程措施,总结了黑臭水体治理的成效。由于市政基础设施薄弱,美舍河沿线存在生活污水直排,雨污错接、混接,合流溢流污染等情况,导致水体常年黑臭。自2015年以来海口市以流域为单元,遵循海绵城市、生态河道的先进理念,按照控源截污、内源治理、生态修复三步走原则,对美舍河开展黑臭水体整治。在控源截污方面,新建合流制排放管、布设截污管道共7.2 km,一体化污水处理设施3个,增加污水处理量7 500 m³/d;内源治理方面,采用挖掘机和绞吸清淤船配合的清淤方式清除污染底泥;生态修复方面,采用环境修复剂对底质进行改良,种植沉水植被36万m²,建设1.0 m×22 m橡胶坝2座,全水域投放水生态修复剂等。此外,美舍河采用梯级潜流人工湿地技术,在增强处理效果的同时,营造出良好的景观。通过上述综合整治,美舍河于2017年消除黑臭。     

建筑小区的海绵化改造效益核算——以固原市玫瑰苑小区为例

以固原市玫瑰苑小区为例,根据小区可改造绿地空间充足、雨落管断接改造难度较小等特点,提出了海绵化改造思路及工程内容,并对海绵化改造后的经济效益和生态效益进行核算。结果表明:通过海绵化改造即改造排水系统,建设下沉式绿地、植草沟、雨水花园、雨水罐、蓄水池、透水铺装等措施,可使小区综合雨量径流系数降低0.21,小区雨水径流量减少5 137.85 m ³∕a,具有良好的雨水调蓄效益;海绵化改造后具有一定的经济效益,可节约城市排水设施费用411.03元∕a,节约自来水费用4 159.20元∕a,节水效益达28 155.42元∕a;海绵化改造后可吸碳8.18 t∕a,释放氧气6.31 t∕a,吸收二氧化硫50.73 kg∕a,生态环境效益显著。     

我国华北地区城市水生态环境现状分析及综合整治对策

从水环境、水资源和水生态3个方面解析了我国华北片区城市水生态环境问题的内在因素。结果表明,区域城市生活污水排放量大,污水收集与处理设施仍存在短板;钢铁、制药、石化行业污染问题突出,特别是山东省和京津冀城市群;季节性降雨引起的城市面源污染不容忽视;城市水生态系统受损严重,水域面积大幅萎缩,河湖岸带破坏严重,富营养化进程加剧,生物多样性下降;城市水资源极度匮乏,水资源开发利用强度大,用水浪费严重,河流干涸断流问题突出。针对上述问题,提出了区域城市近期 (2021—2025年) 、中期 (2026—2030年) 和远期 (2031—2035年) 分阶段的城市水生态环境质量提升目标和综合整治对策建议。本研究结果可为同类北方城市解决水生态环境问题提供参考。     

Parks versus PES: Evaluating direct and incentive-based land conservation in Mexico

Protected areas (PAs) and payments for ecosystem services (PES) are the top two mechanisms available for countries to achieve international REDD agreements, yet there are few empirical comparisons of their effects. We estimate the impacts of PAs and PES on forest conservation, poverty reduction, and population change at the locality level in Mexico in the 2000s. Both policies conserved forest, generating an approximately 20–25% reduction in expected forest cover loss. PES created statistically significant but small poverty alleviation while PAs had overall neutral impacts on livelihoods. Estimates by individual policy type for the same level of deforestation risk indicate that biosphere reserves and PES balanced conservation and livelihood goals better than strict protected areas or mixed-use areas. This suggests that both direct and incentive-based instruments can be effective, and that policies combining sustainable financing, flexible zoning, and recognition of local economic goals are more likely to achieve conservation without harming livelihoods.     

Sustainable supplier selection criteria classification for Indian iron and steel industry: a fuzzy modified Kano model approach

ABSTRACT

The aim of this work is to provide a systematic approach for sustainability criteria clustering into different useful categories. For this purpose, a methodology has been proposed with the following three steps. (i) A comprehensive set of the sustainability criteria in economic, environmental and social dimension has been extracted from the literature and have been customised for the iron and steel industry. (ii) A fuzzy Kano methodology has been used to classify these sustainability criteria into useful Kano cluster like must-be, one-dimensional, and attractive cluster (iii) further, must-be and attractive criteria derived from the second step were further sub-classified into three categories using Type IV Kano model. All steps have been examined in the iron and steel industry of India and findings indicate that quality and delivery criteria are classified as high must be criteria in the economic realm. Further, environmental and energy management system in the environmental dimension and social responsibility and right of stakeholders criteria in the social dimension are classified as high must be criteria. Prioritising must be and attractive criteria enable decision makers of other industries to select the appropriate criteria to adopt sustainability.     

分布式能量系统在我国未来20年能源发展战略中的地位

为了使分布式能量系统（Distributed Energy System,简称DES）在我国更好地发展，本文从我国未来20年的能源发展战略出发，介绍了我国能源发展中依然存在的矛盾和问题，并通过对分布式能量系统组成、特点的研究，认为目前正是分布式能量系统发展的良好机遇：通过对分布式能量系统利用方式的研究，指出了分布式能量系统将在我国未来20年能源发展战略中的地位以及需要解决的相关问题。     

TEACHING WATER RESOURCES POLICY TO UNWERSITY SCIENCE AND ENGINEERING STUDENTS: OPPORTUNITIES AND CHALLENGES1

ABSTRACT: Effectively teaching water resources policy to university science and engineering students is both important and difficult. Most careers in the water resources field require an understanding of the comprehensive governmental regulatory structure affecting water use. Also, few science and engineering curricula encourage their students to take policy courses. Successful approaches to teaching water resources policy might include epistemological comparisons, case studies, issue maps, and interactive simulations. Obstacles to the effective teaching of this subject include students' insufficient preparation and student disdain and cynicism. These obstacles may be mitigated by requiring a prerequisite, developing a glossary of policy-related terms, and introducing the course through lectures emphasizing realistic views of the water resources management field and the nature of the American political system.