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Granular acid-activated neutralized red mud (AaN-RM) has been successfully prepared with good chemical stability and physical strength. However, its potential for industrial application remains unknown. Therefore, the performance of granular AaN-RM for phosphate recovery in a fixed-bed column was investigated. The results demonstrated that the phosphate adsorption performance of granular AaN-RM in a fixed-bed column was affected by various operational parameters, such as the bed depth, flow rate, initial solution pH and initial phosphate concentration. With the optimal empty-bed contact time (EBCT) of 24.27 min, the number of processed bed volumes and the phosphate adsorption capacity reached 496.95 and 84.80 mg/g, respectively. Then, the saturated fixed-bed column could be effectively regenerated with a 0.5 mol/L HCl solution. The desorption efficiency remained as high as 83.45% with a low weight loss of 3.57% in the fifth regeneration cycle. In addition, breakthrough curve modelling showed that a 5-9-1 feed-forward artificial neural network (ANN) could be effectively applied for the optimization of the fixed-bed adsorption system; the coefficient of determination (R2) and the root mean square error (RMSE) evaluated on the validation-testing data were 0.9987 and 0.0183, respectively. Therefore, granular AaN-RM fixed-bed adsorption exhibits promising potential for phosphate removal and recovery from polluted water. 相似文献
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The distribution and sources of organochlorine pesticides (OCPs) in air and surface waters were monitored in Nairobi City using triolein-filled semipermeable membrane devices (SPMDs). The SPMDs were extracted by dialysis using n-hexane, followed by cleanup by adsorption chromatography on silica gel cartridges. Sample analysis was done by GC-ECD and confirmed by GC–MS. Separation of means was achieved by analysis of variance, followed by pair-wise comparison using the t-test (p≤ 0.05). The total OCPs ranged between 0.018 – 1.277 ng/m3 in the air and <LOD – 1391.000 ng/m3 in surface waters. Based on the results, the means of Industrial Area, Dandora and Kibera were not significantly different (p≤ 0.05), but were higher (p≤ 0.05) than those of City square and Ngong’ Forest. The results revealed non-significant (p≤ 0.05) contribution of long-range transport to OCP pollution in Nairobi City. This indicated possible presence of point sources of environmental OCPs in the city. The water-air fugacity ratios indicated that volatilization and deposition played an important role in the spatial distribution of OCPs in Nairobi City. This indicated that contaminated surface waters could be major sources of human exposure to OCPs, through volatilization. The incremental lifetime cancer risks (ILCR) determined from inhalation of atmospheric OCPs were 2.3745 × 10?13 – 1.6845 × 10?11 (adult) and 5.5404 × 10?13 – 3.9306 × 10?11 (child) in the order: Dandora > Kibera > Industrial Area > City Square > Ngong’ Forest. However, these were lower than the USEPA acceptable risks, 10?6 – 10?4. This study concluded that atmospheric OCPs did not pose significant cancer risks to the residents. 相似文献
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以铁基质生物载体为核心,将物理、生物和化学方法结合,对化粪池进行功能强化,实现黑水的原位深度处理.探究了溶解氧(DO)和碳氮比(C/N)等因素对黑水中污染物降解的影响,并在最佳运行参数下考察了氮素在系统中的转化机制.结果表明,当C/N为7.3~8.4时,好氧生物铁基质载体池DO为2.3~2.7mg/L时,系统氨氮(NH4+-N)、总氮(TN) 、COD和总磷(TP)的平均去除率分别可达90.74%、85.81%、92.65%和95.78%;当进水C/N降至3.3~4.2时,系统NH4+-N、TN、COD和TP的平均去除率仍可维持在81.16%、76.62%、93.87%和94.75%.铁基质生物载体内电解作用显著强化了化粪池内TN的脱除、COD的氧化和TP的固定.氮素转化机制分析表明,内电解与反硝化菌的耦合强化了反硝化作用,降低了反硝化过程对有机碳源的需求,强化了低C/N条件下TN、TP的脱除. 相似文献
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介绍对氨基二甲基苯胺光度法测定硫化物方法中如何降低空白值,提高硫化钠溶液的稳定度以及提高酸化吹气回收率的原理和方法. 相似文献
6.
对原CODMn法测地表水二次取样体积进行了推导,建立了实际适用取样体积公式,具有一定的适用性。 相似文献
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进一步推导了曲面零件悬空区上的应力分布及临界失稳公式。然后通过计算机编程 ,求解了临界失稳方程 ,得到了拉深系数、相对锥顶半径、相对圆角半径、材料相对厚度与临界失稳时刻间的关系曲线 ,并对曲线变化的规律进行了分析。 相似文献
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The curve of ion exchange ratio(%)-pH of the interactionbetween suspended particles with Cd(II) in the Yellow River wasstudied. The effects of lysine on this curve have been alsoinvestigated. The results showed that (1) Cadmium in Cd(OH)+ formin the suspended particles exchanges with the cations.The exchangeratio of Cd2+ is nearly at its greatest value in the range of pH(8.0-8.5) in natural aquatic system; (2) Ion exchange ratiodecreases as the concentration of Cd2+ raises from 8.9×10-6 mol/L to 2x8.9 x 10-6mol/L; (3) At the lysine concentration of 6.8x10-6 mol/L, it can promote the ion exchange ratio; (4) Adsorption of thesuspended particles to cadmium is weaker in seawater and Jin ShaRiver than in the Yellow River. 相似文献