化固定化Methylibium petroleiphilum PM1细胞降解MTBE及动力学特性分析

采用海藻酸钙包埋固定化高效降解菌Methylobium petroleiphilum PM1降解水相中的甲基叔丁基醚(MTBE),考察了不同强化方法对凝胶颗粒机械强度和降解活性的影响.响应面结果表明,交联剂和培养基中Ca2+浓度分别为0.2 mol·L-1和1.38mmol·L-1,化学交联剂聚乙烯亚胺(PEI)浓度为...     

江苏沿海化工快速发展的空间格局、环境响应和战略管理对策

江苏省的化工产业污染正呈现向沿海地区快速转移的趋势.为此,本研究首先利用Landsat TM遥感数据快速识别江苏沿海化工园区,并与GIS结合分析其空间分布格局;接着分析各化工园区与饮用水源地、重要生态敏感区距离及所处区域人口密度,计算各化工园区对周边生态系统的污染胁迫度;然后根据空间分布格局及污染胁迫度计算结果确定8个...     

改善烟气脱硫装置浆液池响应特性方法研究

通过对现有的烟气脱硫系统吸收塔浆液池在运行过程中浆液pH值响应过程的分析,针对现有脱硫装置浆液池pH值响应滞后导致的一系列问题,提出了改善烟气脱硫装置浆液池响应特性的措施方案,结合工程实例说明了通过在浆液池内加装浆液气氛控制系统使得pH值响应更为及时,并使浆液池内pH值分布满足浆液池功能要求。保证脱硫装置的安全稳定高效运行,有效降低运行消耗。     

Development and application of a water pollution emergency response system for the Three Gorges Reservoir in the Yangtze River, China

There are many watercraft and production accidents in the Three Gorges Reservoir Area (TGRA) of the Yangtze River in China every year. Accidents threaten the water quality of the 1085 km2 surface area of the TGRA and millions of local people if oil and chemical leakage were to occur. A water pollution management system for emergency response (WPMS ER) was therefore designed for the management of pollution in this area. An integrated geographic information system (GIS)-based water pollution management information system for the TGRA, called WPMS ER TGRA, was developed in this study. ArcGIS engine was used as the system development platform, and Visual Basic as the programming language. The models for hydraulic and water quality simulation and the generation of body-fitted coordinates were developed and programmed as a dynamically linked library file using Visual Basic, and they can be launched by other computer programs. Subsequently, the GIS-based information system was applied to the emergency water pollution management of a shipwreck releasing 10 tons of phenol into the Yangtze River during two hours. The results showed that WPMS ER TGRA can assist with emergency water pollution management and simulate the transfer and di usion of accidental pollutants in the river. Furthermore, it can quickly identify the a ected area and how it will change over time within a few minutes of an accident occurring.     

Optimization of an in vitro method to measure the bioaccessibility of polybrominated diphenyl ethers in dust using response surface methodology

To more reasonably evaluate human intake of PBDEs via dust ingestion, bioaccessibility should be taken into account. Previously, we developed an in vitro method to determine the bioaccessibility of PBDEs in food. Here, this method was adapted to determine the bioaccessibility of PBDEs in dust and the digestion conditions that influenced the bioaccessibility of PBDEs were optimized. The digestion conditions included the incubation time of dust in the intestinal digestion solution (T), the bile concentration in the intestinal digestion solution (C_bile), and the ratio of the volume of the intestinal digestion solution to dust (R). The influence of the concentrations of individual PBDE congeners (C_PBDE) on the bioaccessibility of PBDEs was also investigated. Central composite design was used to build an experimental model and set experimental parameters, and response surface methodology was used to analyze the obtained data. The results showed that the bioaccessibility of PBDEs increased with the increases of C_bile and R, and was independent of T and C_PBDE. Under the digestion conditions with C_bile and R being at 4.0-7.0 g/L and 150-250, respectively, the bioaccessibility of PBDEs in the method-dust varied from 39.2% to 72.8%, which were comparable with the bioaccessibility or bioavailability of PBDEs in dust/soil in the literature. Thus, the in vitro method to measure the bioaccessibility of PBDEs in dust was established and validated. Finally, the bioaccessibility of PBDEs in four natural dust samples, which ranged from 36.1% to 43.3%, were determined using the adapted method.     

Optimization of process parameters using response surface methodology for bioconversion of activated sludge by Penicillium corylophilum

The optimization of process parameters for the bioconversion of activated sludge by Penicillium corylophilum was investigated using response surface methodology （RSM）. The three parameters namely temperature of 33℃, agitation of 150 r/min, and pH of 5 were chosen as center point from the previous study of fungal treatment. The experimental data on chemical oxygen demand （COD） removal （%） were fitted into a quadratic polynomial model using multiple regression analysis. The optimum process conditions were determined by analyzing response surface three-dimensional surface plot and contour plot and by solving the regression model equation with Design Expert software. Box-Behnken design technique under RSM was used to optimize their interactions, which showed that an incubation temperature of 32.5℃, agitation of 105 r/min, and pH of 5.5 were the best conditions. Under these conditions, the maximum predicted yield of COD removal was 98.43%. These optimum conditions were used to evaluate the trail experiment, and the maximum yield of COD removal was recorded as 98.5%.     

配电箱在火灾环境下的热响应特性研究

对建筑中广泛使用的低压配电箱在实际火灾条件下的导热过程进行了分析,借鉴现有规范中对排烟风机的耐温要求,估算了配电箱在280℃时需要的隔热板厚度。在一腔室内利用火源功率为700kW的油池火模拟实际火灾环境,对普通配电箱和加隔热板配电箱箱体温升特性进行了研究,分析了火灾环境温度变化对配电箱箱体、内部温度变化的影响规律,验证了配电箱保持连续工作30min的耐火设计要求。     

超声Fenton法处理毒死蜱中间体废水的工艺优化

针对毒死蜱中间体生产的化工废水有机物浓度高、生物抑制性强的特点,以实际生产废水为研究对象,基于响应曲面法,进行了超声/Fenton法降解有机物效能研究与运行参数的优化.结果表明:1通过单因素试验确定响应曲面设计的自变量中心点为H2O2投加量0.5 mol/L、Fe2+投加量0.93 g/L、反应时间90 min.2采用Box-Behnken试验设计,建立了以H2O2及Fe2+投加量、反应时间为自变量的回归模型,经方差分析,模型显著(P0.000 1);对有机物去除率影响最大的因素为Fe2+投加量,其与反应时间的交互作用显著.3最优工况为H2O2投加量0.7 mol/L、Fe2+投加量1.36 g/L、反应时间96 min,该条件下模型预测CODCr去除率为96.63%,试验值与模型预测值的相对误差为1.36%,出水水质指标远低于GB 8978—1996《污水综合排放标准》三级标准,ρ(BOD5)/ρ(CODCr)从0.09升至0.22,CODCr单位去除负荷的H2O2及Fe2+用量相对较低,分别为0.14 mmol/mg和0.28 mg/mg.研究显示,采用超声/Fenton法处理高浓度难降解有机废水可有效提高CODCr去除率及其可生化性.     

某机载雷达多自由度振动试验控制方法比较

根据机载雷达实测振动数据,在三轴振动台上,采用不同振动控制方法,对机载雷达单元进行了多自由度振动试验。比较了雷达单元在不同振动控制方法下的安装点响应与参考谱的偏差。试验结果表明:相比于方阵控制,长方阵控制中的坐标变换控制(Input/Output控制)方法在进行多自由度振动试验时,可实现真正意义上的平均控制,振动的传递更为均匀。     

场地地震反应分析研究现状及展望∗

场地条件对结构震害的影响已成公认的事实,如何定量的进行场地地震反应分析成为地震工程学中亟待解决的问题之一,而在场地地震反应分析中确定地震动输入至关重要。针对场地条件和地震动输入对场地地震反应的具体影响、场地地震反应分析方法等方面的研究现状进行了系统总结。已有研究表明,场地条件和地震动输入对场地地震反应分析结果有显著影响。但目前仍存在的问题有:在冻土区进行场地地震反应分析时未充分考虑冻土层的影响效应;缺乏合理的地震动模型来准确描述实际地震动;尚未明确地震波入射角度对场地地震反应的影响规律;目前广泛使用的等效线性化方法不能完全反应土体在地震动作用下的真实运动状态而使其计算结果不尽合理。结合以上问题对还需进一步研究的内容进行了展望,为场地地震反应分析未来的研究工作提供参考。