Evaluation of activated sludge properties’ changes in industrial-wastewater pre-treatment: role of residual aluminum hydrolyzed species with different polymerization degree

● Medium poly Al salts dominated the PAC residual salts with a rational dosage. ● Settlement flocculation effect under medium poly Al salts showed a better trend. ● Complex of medium poly Al salts and enzymes promoted cell activity. ● Medium poly Al salts were beneficial to the effluent indexes. With the widespread introduction of pre-coagulation prior to the biological unit in various industrial wastewater treatments, it is noteworthy that long-term accumulation of residual coagulants has certains effect on both micro and macro characteristics of activated sludge (AS). In this study, the morphology distributions of residual aluminum salts (RAS) and their effects on the removal efficiency of AS were investigated under different PAC concentrations. The results showed that the dominance of medium polymeric RAS, formed under an appropriate PAC dose of 20 mg/L enhanced the hydrophobicity, flocculation, and sedimentation performances of AS, as well as the enzymatic activity in cells in the sludge system, improving the main pollutants removal efficiency of the treatment system. Comparatively the species composition with monomer and dimer / high polymer RAS as the overwhelming parts under an over-dosed PAC concentration of 55 mg/L resulted in excessive secretion of EPS with loose flocs structure and conspicuous inhibition of cellular activity, leading to the deterioration of physico-chemical and biological properties of AS. Based on these findings, this study can shed light on the role of the RAS hydrolyzed species distributions, closely relevant to Al dosage, in affecting the comprehensive properties of AS and provide a theoretical reference for coagulants dosage precise control in the pretreatment of industrial wastewater.     

高效液相色谱-串联质谱法同时测定地表水中33种药物

采用固相萃取-高效液相色谱-串联质谱法(SPE-HPLC-MS/MS)建立了地表水中25种抗生素类药物和8种非抗生素类药物的分析方法。通过重点优化质谱参数、色谱条件、样品pH、洗脱溶剂组成及用量等确定了最佳分析条件。水样经过滤、固相萃取柱富集净化后,选择Shim-pack XR-ODS为色谱柱,以乙腈和0.2%甲酸-2 mmol/L乙酸铵-水溶液为流动相进行梯度洗脱,采用电喷雾电离源,在多反应监测模式下(MRM)分析测定,内标法定量。33种药物的仪器定量限为0.012～4.68 ng/L,方法检出限为0.011～7.60 ng/L,地表水加标回收率为53.7%～122%,相对标准偏差为1.22%～32.1%(n=6)。方法成功应用于北京市凉水河12个地表水样分析,共检出32种药物,检出质量浓度为未检出～239 ng/L。利托那韦(RTV)作为新型冠状病毒诊疗方案中推荐的药物在凉水河检出率为100%。     

浙江省沿海地区农村房屋抗风情况调研

对浙江省沿海地区的农村房屋抗风情况进行了调研,总结了被破坏房屋的主要结构特点。在对现有房屋的统计中发现相对不富裕地区高达60%以上的房屋属于抗风能力差和较差的,而一些比较富裕且受过台风袭击有过惨痛教训地区的房屋抗风能力差和较差的仅在20%以下。进一步研究发现抗风能力较好的房屋大都是建造年代不久,多为混凝土现浇板屋盖,上部多为框架或砖混结构,而抗风能力较差和差的大都为建造年代已久,多为小青瓦屋面,上部结构多为砖木结构或构造措施较差的砖混结构。同时对当地村民传统的"砖头压瓦"防护措施进行理论验算,得出当风速超过台风界限风速时,屋面上的砖头将会飞起,该措施应该避免。     

When leaders are forced to stay: The indirect effects of leaders' reluctant staying on subordinates' performance

Leaders who desire to leave the current organization are sometimes forced to stay. The leadership behaviors of these leaders are underexplored in the current literature. Building on proximal withdrawal states theory, this study examines two pathways through which leaders' reluctant staying mindset (i.e., desire but are unable to quit) relates to their subordinates' task performance and organizational citizenship behaviors (OCB). One pathway proposes increased laissez-faire leadership behaviors due to leaders' lower intrinsic motivation; the second pathway proposes increased delegation behaviors due to leaders' higher extrinsic motivation. Using three-wave data collected from 100 leaders and 313 subordinates, we found that leaders' reluctant staying was indirectly and negatively associated with subordinates' task performance and OCB through leaders' lower perceptions of task significance and higher laissez-faire leadership behaviors. At the same time, leaders' reluctant staying increased their bottom-line mentality and delegation behaviors, but the indirect effects on subordinates' performance outcomes were not significant. We discuss the implications of our findings for theory, practices, and future research regarding how to manage leaders who stay reluctantly in the organization.     

袋式除尘器和静电除尘器在电厂除尘系统中运用的性能对比分析

针对目前火电厂除尘系统应用现状和当前环保要求,通过对袋式除尘器和静电除尘器在火电厂燃煤锅炉除尘系统中的应用,对袋式除尘器和静电除尘器在技术性能上的差异作了简单的对比分析,以指导除尘器在目前火电厂燃煤锅炉除尘系统中的具体应用。     

安全绩效研究综述

为探明安全绩效的研究方向,加强对安全绩效基础研究,从而为加强企业安全管理工作提供理论保障。从安全绩效的定义和范畴、安全绩效的评估、安全绩效影响因素的实证研究、安全绩效的提升等方面对国内外安全绩效相关研究进行论述和分析。提出以企业组织安全行为与员工安全行为作为研究的切入点;采用定性与定量相结合的方法;研究的重点应为更加注重过程的控制,注重安全行为的引导和安全文化的建设。     

地铁项目安全绩效关键影响因素分析研究

在分析研究地铁安全事故案例的基础上,识别出对地铁项目安全绩效的48个关键影响因素,将这些影响因素归为五大类,即项目参与各方对安全的影响程度、人员的不安全行为及不安全状态、材料的不安全状态、机械/设备的不安全状态和现场环境的不安全状态;采取调查问卷的方式,运用结构方程建模得出各个指标的重要度及各指标之间的相互影响。研究结果表明:"项目参与各方对安全的影响程度"和"现场环境的状态"对地铁安全绩效的贡献最大,同时,其他因素也有较强的影响,在地铁施工中应以此为重点,加强安全防范。     

消防服用织物热防护性能测试分析与研究

热防护性能(Thermal protective performance—TPP)是阻燃型服装或织物隔热防护性能重要指标。本文在已研制的一种模拟人体皮肤及体形的高温"圆筒仪"上进行了改进,并用其测试阻燃服装织物的热防护性能。用膜电偶测量模拟皮肤器表面温升率,并结合烧伤积分模型的评价方法来计算达到二级烧伤的防热时间。与其它一维平面测试装置相比,本装置可较为准确评估实际服装热收缩特征对服装热防护性能的影响。     

碳钠米管纤维在新型防弹衣中的性能优势

现代高科技武器的发展以及日益复杂的作战环境对防弹衣的防弹性能和穿着舒适性提出了更高要求。新材料仍将成为下一代新型防弹衣的开发方向。本文介绍的碳钠米管纤维早在20世纪90年代就已经被发现。由于其制造成本贵比黄金而一直未被广泛使用。近年来随着工艺技术的改进及生产规模的扩大,碳纳米管的生产成本大幅降低,其开发潜能和应用前景逐渐受到材料科学界和高新技术产业部门的关注。本文在分析现代常用防弹衣防弹机理的基础上着重论述碳钠米管作为超级纤维的独特性能在防弹领域中的应用优势。     

泄漏事故应急带压密封处置方法及术语译法研究

给出了泄漏的准确定义,指出了泄漏可能引发的火灾、爆炸、中毒、人身伤亡、环境污染噪音及腐蚀方面的危害。介绍了目前最有效的泄漏事故应急处置方法——带压密封技术的基本原理、特点、应用范围及现场操作步骤;研究了泄漏事故应急处置方法的汉英定名问题,简介了国际上流行的“30”式应急技术服务方式,辨析了“带压密封”汉译英巾“Stoppage under Pressure”等中式英文欠缺。同时举例论述了“带压密封”一词的规范用法和译法。