基于力学分析的深井煤与瓦斯突出临界值研究

为研究应力对深井煤与瓦斯突出工作面的影响,采用力学模型分析了平行六面微元体各个面的受力情况,结合煤体强度理论和矿山压力理论,从煤体所受瓦斯压力、地应力和煤体破坏条件等方面入手,研究了三轴应力态下煤体力平衡问题.探讨了瓦斯压力、地应力、煤壁支撑力等参数和煤与瓦斯突出之间的关系.结果表明,煤与瓦斯突出的瓦斯压力临界值由采场内的应力、煤壁支撑力和煤的力学参数等确定,综合考虑上述因素后,对煤与瓦斯突出预测时瓦斯压力临界值进行了理论推导和关键参数修正,建立了包含应力、采场条件和煤的力学参数的推算瓦斯压力临界值的理论模型,并对理论模型的可靠性进行了分析.突出实例的反演表明在深部开采时,如果不考虑应力对煤与瓦斯突出的影响,会出现预测结果偏差而影响安全生产.建立的理论模型可对这种偏差进行分析和校正.     

基于正压密封方法的闭式采空区灭火技术

为提高闭式采空区密闭漏风控制效果,基于矿井空气流动基础理论,运用RFPA软件建立了注氮气室正压密封采空区数值模型,模拟分析了注氮气室正压作用对采空区密闭漏风行为的影响规律,提出了基于注氮气室正压密封方法的采空区灭火技术,并在恒大煤矿5333工作面采空区进行了应用.结果表明,在气室内氮气相对正压作用下,通风巷道向采空区漏风速度快速减小至0,并最终产生反向,形成由气室向外部微量漏氮气的状态,5333采空区采取正压密封方法后,内部CO、C2H4和温度快速消失和降低至安全范围值.     

中国省域环境压力综合评价

以中国30个省、自治区和直辖市为研究对象,以1997-2010年为研究区间,选取各省工业SO2排放量、烟尘排放量、粉尘排放量、废水排放量、固体废弃物产生量和碳排放量6类环境污染基础指标,运用“纵横向”拉开档次法构建环境压力综合指标,从环境压力平均水平、变化趋势和变动程度3个角度深入分析各省、自治区和直辖市在1997-2010年的环境压力.结果表明,根据环境压力平均水平,我国各省、自治区和直辖市可分别划入高、中、低3个环境压力区域,各省环境压力也分别呈现上升、下降、U型和倒U型4种变化趋势.此外,内蒙古环境压力不断上升,四川和辽宁环境压力不断下降,三者变动系数较大,分别达到0.08、0.06和0.05.研究表明,内蒙古的环境现状不乐观,亟须改善;而四川和辽宁二省环保工作实施效果较好,大幅度降低了环境压力,可作为其他省、自治区和直辖市降低环境压力的学习对象.     

某铅锌矿采空区处理与卸压开采方案研究

900m水平似上采空区回收矿柱及900 m水平以下的巷道掘进或矿房开采时经常发生岩爆.为了安全、经济地回收矿柱并实施深部开采,在数值分析的基础上,提出了一种急倾斜矿体的采空区处理与卸压开采方法,并用ANSYS数值模拟确定了采空区处理及卸压开采的施工参数.结果表明,在下盘脉外巷道离采空区边缘的水平距离为10 m时,上盘脉外巷道离采空区边缘的水平距离取20m;在巷道底板隔断开采的深度不超过20m;必须从上、下盘脉外巷道同时向采空区围岩实施V型松动爆破;可只在上盘巷道底板进行隔断开采.该采空区处理与卸压开采方法技术可行、经济合理、简便适用.当地表允许岩体移动时这种新方法适合急倾斜、厚度大矿体的采空区处理与卸压开采;如果地表不许可岩体移动,使用这种新方法是不合适的.该采空区处理与卸压开采方法是一种采空区处理的联合法.它能够用工程爆破这一种手段实现采空区处理、应力向有利于安全生产的方向转移等多种目的.     

Risk analysis of deepwater drilling operations using Bayesian network

Deepwater drilling is one of the high-risk operations in the oil and gas sector due to large uncertainties and extreme operating conditions. In the last few decades Managed Pressure Drilling Operations (MPD) and Underbalanced Drilling (UBD) have become increasingly used as alternatives to conventional drilling operations such as Overbalanced Drilling (OVD) technology. These newer techniques provide several advantages however the blowout risk during these operations is still not fully understood. Blowout is regarded as one of the most catastrophic events in offshore drilling operations; therefore implementation and maintenance of safety measures is essential to maintain risk below the acceptance criteria. This study is aimed at applying the Bayesian Network (BN) to conduct a dynamic safety analysis of deepwater MPD and UBD operations. It investigates different risk factors associated with MPD and UBD technologies, which could lead to a blowout accident. Blowout accident scenarios are investigated and the BNs are developed for MPD and UBD technologies in order to predict the probability of blowout occurrence. The main objective of this paper is to understand MPD and UBD technologies, to identify hazardous events during MPD and UBD operations, to perform failure analysis (modelling) of blowout events and to evaluate plus compare risk. Importance factor analysis in drilling operations is performed to assess contribution of each root cause to the potential accident; the results show that UBD has a higher occurrence probability of kick and blowout compared to MPD technology. The Rotating Control Devices (RCD) failure in MPD technology and increase in flow-through annulus in UBD technology are the most critical situations for kick and blowout.     

On the explosion and flammability behavior of mixtures of combustible dusts

In the work presented in this paper, the explosion and flammability behavior of combustible dust mixtures was studied. Lycopodium, Nicotinic acid and Ascorbic acid were used as sample dusts.In the case of mixtures of two dusts, the minimum explosive concentration is reproduced well by a Le Chatelier's rule-like formula, whereas the minimum ignition energy is a linear combination of the ignition energies of the pure dusts.An unexpected behavior has been found in relation to the explosion behavior and the reactivity. When mixing Lycopodium and Nicotinic acid or Ascorbic acid, the rate of pressure rise of the mixture is much higher than the rate of pressure rise obtained by linearly averaging the values of the pure dusts (according to their weight proportions), thus suggesting that strong synergistic effects arise; but it is comparable to that of the most reactive dust in the mixture.The observed behavior seems to be linked to the presence of minerals in the Lycopodium particles which catalyze oxidation reactions of Nicotinic acid and Ascorbic acid, as suggested by TG analysis.In the case of mixtures of three dusts, a similar behavior is observed when the concentration of Lycopodium is twice that of the other two dusts.     

采用膜污染指数评估天然有机物在低压超滤膜中的污染行为

针对超滤膜的过滤特性,采用膜污染指数（FI）来研究天然有机物（NOM）的膜污染行为.实验中,腐殖酸（HA）、牛血清蛋白（BSA）以及海藻酸钠（NaAlg）被用作模型有机物进行超滤膜污染研究.结果表明,NOM-膜滤先后经过快反应和慢反应污染阶段,其中快反应膜污染指数（TFIF）远大于慢反应膜污染指数（TFIS）.说明短时间内NOM容易在低压膜上积累,造成通量迅速下降,引起较为严重的污染.因此,反应最初阶段,低压膜与有机物的作用决定了整个膜污染的趋势.经过水力清洗,通量有一定恢复,膜阻力降低,能够去除部分污染物,但仍有少量有机物附着在膜丝,从而造成不可逆污染.3种有机物造成的不可逆污染比例依次为BSA〉HA〉NaAlg,而通过化学清洗后,其不可逆污染比例依次为：NaAlg〉BSA〉HA,腐殖酸和蛋白容易造成不可逆污染,但碱洗易于除去,多糖造成的不可逆污染相对较轻,但碱洗难以去除.污染物与膜之间的相互作用可能是造成污染的主要原因.总的说来,FI计算方法简单,能够综合描述膜污染情况,具有一定的应用价值.     

不同调理剂对厌氧石化污泥脱水性能的影响研究

以厌氧消化后的石化污泥为研究对象,研究聚合硫酸亚铁(PFS)、聚丙烯酰胺(PAM)、聚合氯化铝(PAC)、Fenton试剂对厌氧石化污泥脱水性能的影响,再对调理后的厌氧污泥通过板框压滤机压滤脱水,考察其脱水难易程度。研究结果表明:相比无机絮凝剂PFS、PAC和有机絮凝剂PAM,Fenton试剂(七水合硫酸亚铁加到15,20,25 g/L时,H_2O_2溶液投加量为5 m L/L)的调理效果较好,调理后污泥的毛细吸水时间分别降低至36.82,18.3,27.28 s,污泥比阻分别降低至4.22×1011,1.23×1011,2.45×1011cm/g;采用FPS、PAC、PAM、Fenton(H_2O_2溶液投加量为5 m L/L,Fe SO4·7H2O加到15,20,25 g/L时)调理后的污泥,经过板框脱水后的泥饼含水率分别为68.65%、64.19%、67.21%、57.46%、55.83%、59.36%。由此可见,最优的厌氧石化污泥脱水调理剂为Fenton试剂(Fe SO4·7H2O、H_2O_2投加量分别为20 g/L、5 m L/L),该研究对厌氧石化污泥的高干脱水和减量化具有参考价值。     

印染集控区内导热油炉中温中压蒸汽改造环境效益分析研究

"十二五"期间,石狮市实施了印染集控区内导热油炉的中温中压蒸汽改造工程,作为大气污染防治控制,保障城市空气质量的重点工作之一.以石狮市印染集控区内导热油炉中温中压蒸汽改造为研究对象,应用排放系数和物料守恒法对工程实施前后区域污染物削减情况进行测算分析.研究表明,实施工程后,石狮市印染集控区SO2、粉尘、NOx等污染物的排放量分别下降了82.1%、48.3%和62.8%,实现了大气环境质量的改善.     

枯季乌江河流“呼吸”作用及其性质探讨

发源于云贵高原上的乌江是长江流域的重要支流之一。乌江流域喀斯特地貌广泛发育，是中国南方典型的喀斯特河流。以枯水季节乌江流域水体中的实测温度、溶解氧、碱度和pH值等理化参数为依据，探讨了乌江流域河道水体的CO2分压(〖WTBX〗P〖WTBZ〗CO2)与河流“呼吸”通量的变化规律。乌江流域枯水季节河道水体〖WTBX〗P〖WTBZ〗CO2介于2913~1 530 μatm之间，平均值为9493 μatm，约为大气的3倍，各支流样点的平均值为9924 μatm，大于干流平均值9026 μatm，由此推断乌江流域干支流河道在枯季是大气CO2的“源”。受各游段流域特征以及人类活动的影响，干支流河道水体〖WTBX〗P〖WTBZ〗CO2表现出明显的空间差异。水体〖WTBX〗P〖WTBZ〗CO2与溶解氧的相关关系不显著，说明河道内有机质的异养呼吸不是喀斯特乌江流域枯季水体中溶解无机碳的主要来源，其河道水体中高〖WTBX〗P〖WTBZ〗CO2成因复杂。〖WTBX〗P〖WTBZ〗CO2的上述分布规律是流域支流汇入、地下水以及河道水体有机质氧化分解等共同作用的结果。