城市人为热排放分类研究及其对气温的影响

随着城市化进程日益加速,城市热岛现象愈发严重。利用上海市近50 a各区县月均温数据,统计分析了各区与崇明夏季每5 a均温差,发现热岛效应由市区中心向郊区延伸,范围越来越大,特别是20世纪80年代开始温差呈较大幅增加,城市热岛现象显著;在前人工作的基础上,分析热岛产生机制中的主要原因之一：城市中人为热排。绘制人为热排放流程图,并将城市人为热源进行分类,分析所有可能成为人为热排放源的设施以便定性及控制研究;对供给,消费和排出3种阶段的计算方法进行对比归纳,根据目的不同分别使用;分别计算燃油排热和燃煤排热以估算上海市人为热排放总量,统计上海市区和郊区的年均温及年均温差随时间变化及其与人为热排放之间的关系,发现两者之间有很好的相关性;最后就上海市夏季空调使用排热对上海市温度影响进行了定性研究,数字化上海市航片得到上海市建筑物分布图,假设楼层和空调密度之间存在相关性,发现空调排热与地面温度反演有着非常良好的一致性,同时也是造成上海城市高温的主要因素之一     

中国城镇化与土地集约利用关系的动态计量分析

在测度城镇化与土地集约利用的基础上,运用动态计量经济模型探讨城镇化与土地集约利用的相互作用。研究结果表明：（1）城镇化与土地集约利用均为一阶单整序列;（2）城镇化与土地集约利用之间存在长期均衡关系,但短期内却存在失衡,短期波动向长期均衡趋近的调整幅度达到18.98%;（3）城镇化是土地集约利用的Granger原因,而反向关系得不到实证支持;（4）土地集约利用对来自城镇化的冲击响应强烈,城镇化的冲击对土地集约利用的解释水平达到了90%,而城镇化对来自土地集约利用的冲击响应较弱,土地集约利用的冲击对城镇化的解释水平仅为3%。因此,应采取长期而非短期的策略,有序推进城镇化进程,加强土地利用监督管理,不断提高土地资源集约利用水平     

Deactivation and regeneration of ZSM-5 zeolite in catalytic pyrolysis of plastic wastes

In this work, a study of the regeneration and reuse of ZSM-5 zeolite in the pyrolysis of a plastic mixture has been carried out in a semi-batch reactor at 440 °C. The results have been compared with those obtained with fresh-catalyst and in non-catalytic experiments with the same conditions. The use of fresh catalyst produces a significant change in both the pyrolysis yields and the properties of the liquids and gases obtained. Gases more rich in C3-C4 and H₂ are produced, as well as lower quantities of aromatic liquids if compared with those obtained in thermal decomposition. The authors have proved that after one pyrolysis experiment the zeolite loses quite a lot of its activity, which is reflected in both the yields and the products quality; however, this deactivation was found to be reversible since after regeneration heating at 550 °C in oxygen atmosphere, this catalyst recovered its initial activity, generating similar products and in equivalent proportions as those obtained with fresh catalyst.     

Riparian Zone Influence on Stream Water Dissolved Organic Carbon Concentrations at the Swedish Integrated Monitoring Sites

Short-term variability in stream water dissolved organic carbon (DOC) concentrations is controlled by hydrology, climate and atmospheric deposition. Using the Riparian flow-concentration Integration Model (RIM), we evaluated factors controlling stream water DOC in the Swedish Integrated Monitoring (IM) catchments by separating out hydrological effects on stream DOC dynamics. Model residuals were correlated with climate and deposition-related drivers. DOC was most strongly correlated to water flow in the northern catchment (Gammtratten). The southern Aneboda and Kindla catchments had pronounced seasonal DOC signals, which correlated weakly to flow. DOC concentrations at Gårdsjön increased, potentially in response to declining acid deposition. Soil temperature correlated strongly with model residuals at all sites. Incorporating soil temperature in RIM improved model performance substantially (20–62% lower median absolute error). According to the simulations, the RIM conceptualization of riparian processes explains between 36% (Kindla) and 61% (Aneboda) of the DOC dynamics at the IM sites.     

Ozone-enhanced catalytic oxidation of monochlorobenzene over iron oxide catalysts

In this study, we examined the experimental catalytic oxidation of gaseous monochlorobenzene (MCBz) with O₃ over Fe₂O₃ in a packed bed reactor to investigate the feasibility of economical low temperature decomposition at a high space velocity (SV). We investigated the effects of several reaction parameters (temperature, O₃ concentration, and SV) on the MCBz oxidation. At 150 °C, the conversion of MCBz over Fe₂O₃ in the absence of O₃ was only 3%; it increased to 91% over Fe₂O₃ in the presence of 1200 ppm of O₃ at a high SV of 83 s⁻¹. A long-term operation study revealed that the conversion of MCBz was stable for more than 96 h. In the steady state, the carbon and chlorine balances were 88% and 86%, respectively. Applying a Langmuir-Hinshelwood kinetic model, we estimated an activation energy of 16.7 kJ mol⁻¹ for MCBz oxidation over Fe₂O₃ in the presence of O₃.     

Persistence of two neonicotinoid insecticides in wastewater, and in aqueous solutions of surfactants and dissolved organic matter

Wastewater treatment plants receive organic contaminants, such as pesticides, which reach the sewage system from domestic, industrial or agricultural activities. In wastewater, which is a complex mixture of organic and inorganic compounds, biotic or abiotic degradation of contaminants can be affected by the presence of co-solutes. The photodecomposition in natural sunlight of two neonicotinoid insecticides, thiamethoxam and thiacloprid, was investigated in wastewater, aqueous extracts of sewage sludge and in aqueous surfactant solutions, which are abundant in wastewater. Dissipation in the dark was also studied in wastewater, due to reduction of transmitted sunlight in wastewater ponds. With regard to photolysis, thiamethoxam degraded rapidly in all the aqueous solutions. Among them sewage sludge extracts slightly modified (average half-life 17.6 h), wastewater increased (13.7 h) and non-ionic surfactants led, as a family, to the highest dissipation rates (average 6.2 h), with respect to control water (18.7 h). Additionally this pesticide also underwent a slower biodegradation process in wastewater in the dark under anaerobic conditions (around 25 d). A metabolite of thiamethoxam from the biological decomposition in wastewater was identified by HPLC/MS. On the other hand thiacloprid was found to be resistant to photo- and biodecomposition and remained almost unchanged during the experimental periods in all the tested media.     

PTFE乳液涂层对针刺毡复合滤料过滤性能的改良

采用PTFE乳液对P84.PTFE混纺针刺毡复合滤料进行涂层整理,并将其与未经整理的试样进行VDI滤料过滤性能模拟测试,进而阐述PTFE乳液涂层对该复合滤料过滤性能的影响。     

采用浅水盘加湿方式实现低温高湿应力

目前运用最为广范的加湿方法是利用浅水盘加湿,根据其加湿原理分析,浅水盘加湿方法一般只能控制在常温以上的湿度。本文介绍一种方法,结合湿度原理在不对设备进行改造的情况下实现了低温高湿的试验应力。同时,反应出国外某些先进设备对试验风险的完善考虑。     

Constructing an Interdisciplinary Flow Regime Recommendation1

Bartholow, John M., 2010. Constructing an Interdisciplinary Flow Regime Recommendation. Journal of the American Water Resources Association (JAWRA) 1-15. DOI: 10.1111/j.1752-1688.2010.00461.x Abstract: It is generally agreed that river rehabilitation most often relies on restoring a more natural flow regime, but credibly defining the desired regime can be problematic. I combined four distinct methods to develop and refine month-by-month and event-based flow recommendations to protect and partially restore the ecological integrity of the Cache la Poudre River through Fort Collins, Colorado. A statistical hydrologic approach was used to summarize the river’s natural flow regime and set provisional monthly flow targets at levels that were historically exceeded 75% of the time. These preliminary monthly targets were supplemented using results from three Poudre-specific disciplinary studies. A substrate maintenance flow model was used to better define the high flows needed to flush accumulated sediment from the river’s channel and help sustain the riparian zone in this snowmelt-dominated river. A hydraulic/habitat model and a water temperature model were both used to better define the minimum flows necessary to maintain a thriving cool water fishery. The result is a range of recommended monthly flows and daily flow guidance illustrating the advantage of combining a wide range of available disciplinary information, supplemented by judgment based on ecological principles and a general understanding of river ecosystems, in a highly altered, working river.     

钢筋混凝土结构抗火研究进展与趋势

火灾高温对钢筋混凝土结构材性有显著影响,极易造成结构损伤、破坏甚至倒塌。在大量阅读国内外文献的基础上,从建筑火灾发展过程研究、钢筋混凝土结构在火灾中的行为研究、钢筋混凝土结构抗火设计方法的研究、火灾后钢筋混凝土结构的损伤评估和加固方法的研究等4个方面对钢筋混凝土结构抗火研究进行了论述;总结了目前国内外钢筋混凝土结构抗火研究的主要进展及成果;指出了结构抗火研究尚存在的一些问题;最后,对结构抗火研究趋势进行了展望。