C60丙二酸二(2,4,6-三硝基苯乙基)酯马来酸聚合物铅盐的合成

以TNT和甲醛为原料,首先得到2,4,6-三硝基苯乙醇(TNPE),TNPE和丙二酰氯经酯化反应合成得到丙二酸二(2,4,6-三硝基苯乙基)酯(TNPEM),TNPEM与C60通过Bingel反应制备了C60丙二酸二(2,4,6-三硝基苯乙基)酯(FTNPEM).FTNPEM再与马来酸和硝酸铅通过共聚合成盐反应得到含能的C60丙二酸二(2,4,6-三硝基苯乙基)酯马来酸聚合物铅盐5.采用FT-IR、UV-Vis、GPC、XPS、XRD等表征方法对聚合物及其铅盐的结构进行了分析.利用差热分析法(DTA)和热重分析法(TGA)对聚合物铅盐5的热稳定性及其对RDX的热分解催化作用进行了研究.结果表明,在空气气氛下,聚合物铅盐5初始分解峰值温度为239℃,表明产物热稳定性良好.对RDX热分解催化作用研究结果表明,聚合物铅盐5能加速RDX的分解,并使RDX分解峰温降低6℃.     

基于改进物元可拓模型的采空区稳定性评价

为实现对采空区稳定性的准确评价,选取岩石抗压强度、采场埋深、暴露时间等13项影响因子,建立采空区稳定性评价指标体系。应用物元分析理论,通过物元构造、关联函数求解等步骤建立采空区稳定性评价的物元可拓模型。通过隶属函数对模型的物元量值规格化处理,运用改进层次分析法确定评价指标权重,从而得到改进的物元可拓评价模型。以山东某金矿6个采空区为例,运用改进物元可拓模型对其稳定性进行评价,并与模糊评价结果比较。采用空区探测系统对两种模型下评价结果相异的空区进行现场实测,结合数值方法分析其力学响应特征。结果表明,改进物元可拓模型的评价结果较模糊模型与实际情况更为吻合,准确度更高,将其应用于采空区稳定性评价是合理可行的。     

三峡-丹江口及邻区区域地壳稳定性的模糊数学评价

三峡-丹江口及邻区是南水北调中线补水工程线路的所在区域。以构造稳定性评价为主,辅以地面稳定性评价,选择地质、地震、活动断裂、地壳形变、地质灾害等共16个指标因素,通过专家咨询、打分,并最终综合集成确定了各指标因素的权重大小,运用模糊数学方法对该研究区进行了区域地壳稳定性评价。评价结果表明,该研究区共划分出相对较不稳定区3个、相对较稳定区15个、相对稳定区8个,未出现不稳定区。并对模糊数学方法进行了有意义的探讨,指出因素及其权重的决定对整个评价结果的影响至关重要,同时数据的准备及数据的二次分析提高对整个评价结果的可信度提供了重要保证,对今后的中线补水工程线路的选择提供了一定的指导和进一步论证的基础。     

Stability of self-reported favourite places and place attachment over a 10-month period

We investigated the reliability and stability of favourite place selections and evaluations of place attachment over a 10-month period. A simple random sample of 1273 respondents representative of the population of the two largest cities in Finland completed a mailed questionnaire. Reliability data was obtained in a second questionnaire (N = 427). We obtained five main favourite place types which were extensively managed natural settings (mainly urban woodlands), urban green spaces (mostly parks), waterside environments, exercise and activity/hobby areas, and indoor and outdoor urban areas. Sixty-four percent of the respondents in the second survey selected the same main favourite place type as 10 months earlier, which is more than what might be expected by chance. Extensively managed natural settings (mainly urban woodlands) and waterside environments were reselected most often. Indoor and outdoor urban favourite places had the lowest stability. We found evidence of people being more consistent in their attachment to natural favourite places than to urban favourite places. The findings lend further credence and credibility to earlier results concerning self-regulation and restorative experiences in favourite places.     

北京山区生态系统稳定性评价模型初步研究

在建立北京山区生态评价体系的基础上,参考有关资料和北京的实际状况确定山区生态系统稳定性评价的标准和分级,选择适当的方法确定评价因子的层次关系和重要度,建立了综合评价模型。并以北京山区的一典型区为例对评价模型进行检验,结果与实际基本相符。     

不同变形失稳模式下隧道围岩稳定性判据研究的进展

计算机模拟隧道围岩失稳研究的困难在于失稳模型不清楚、失稳判据不明确。本文综合分析了目前国内外应用的隧道稳定性判别方法,总结了不同变形失稳机制下的计算模型及其量化的破坏判据,分析了各种方法的研究进展和存在局限,为围岩稳定性数值模拟提供快速、合理、可操作的判据。     

考虑刚度劣化的剪切带-围岩系统稳定性分析

峰后的刚度劣化现象(渐进损伤)在多种煤、岩石、混凝土、土和砂子的循环加载实验中已被观察到。本文考虑了剪切带及带外弹性体的不同的刚度劣化现象,推导了剪切带(断层)-弹性围岩系统在直剪条件下的应力—变形曲线。剪切带的刚度劣化不改变剪切带的总变形,但使剪切带的弹性变形增加、塑性变形降低。考虑弹性体的刚度劣化现象之后,系统的峰后应力—变形曲线呈现非线性特征,这不同于过去忽略刚度劣化现象的结果。在应变软化过程中,剪切带之外弹性体的刚度劣化,使系统的峰后响应由负斜率(Ⅰ类行为)变为正斜率(Ⅱ类变形行为)。较高的弹性体尺寸、较高的脆性、较小的内部长度、较低的围岩初始弹性模量、较高的抗剪强度、较低的残余剪切应力及较高的残余剪切弹性模量,使系统的峰后响应变得陡峭,甚至发生Ⅱ类行为,使系统的失稳(岩爆、冲击地压、采矿诱发地震或矿震)易于发生。     

Impact of varying soil structure on transport processes in different diagnostic horizons of three soil types

When soil structure varies in different soil types and the horizons of these soil types, it has a significant impact on water flow and contaminant transport in soils. This paper focuses on the effect of soil structure variations on the transport of pesticides in the soil above the water table. Transport of a pesticide (chlorotoluron) initially applied on soil columns taken from various horizons of three different soil types (Haplic Luvisol, Greyic Phaeozem and Haplic Cambisol) was studied using two scenarios of ponding infiltration. The highest infiltration rate and pesticide mobility were observed for the Bt₁ horizon of Haplic Luvisol that exhibited a well-developed prismatic structure. The lowest infiltration rate was measured for the Bw horizon of Haplic Cambisol, which had a poorly developed soil structure and a low fraction of large capillary pores and gravitational pores. Water infiltration rates were reduced during the experiments by a soil structure breakdown, swelling of clay and/or air entrapped in soil samples. The largest soil structure breakdown and infiltration decrease was observed for the Ap horizon of Haplic Luvisol due to the low aggregate stability of the initially well-aggregated soil. Single-porosity and dual-permeability (with matrix and macropore domains) flow models in HYDRUS-1D were used to estimate soil hydraulic parameters via numerical inversion using data from the first infiltration experiment. A fraction of the macropore domain in the dual-permeability model was estimated using the micro-morphological images. Final soil hydraulic parameters determined using the single-porosity and dual-permeability models were subsequently used to optimize solute transport parameters. To improve numerical inversion results, the two-site sorption model was also applied. Although structural changes observed during the experiment affected water flow and solute transport, the dual-permeability model together with the two-site sorption model proved to be able to approximate experimental data.     

降低负荷以提高反硝化颗粒污泥的稳定性

在上流式污泥床反应器（USB）内,接种好氧活性污泥,以甲醇为碳源,NO-3为电子受体,经过40多d培养,得到良好的反硝化颗粒污泥,粒径2～3 mm,MLSS为36 g/L,氮去除速率和COD去除速率分别在0.15 g NO₃-N/(g VSS·d)和0.8 g COD/(g VSS·d)。当负荷提高至6.44 g NO₃-N/(L·d)继续运行1周后,观察到反应器内颗粒污泥出现上浮,浓度降低,颗粒粒径多数在3～5 mm,外观呈乳白色。为恢复反应器稳定运行,当负荷降至3.86 g NO₃-N/(L·d)时,上浮现象减轻,当负荷降至2.57 g NO₃-N/(L·d)时,上浮现象消失,颗粒污泥密度由不稳定时的1.0018 g/cm³提高到1.0126 g/cm³,颗粒粘连现象基本消失,污泥氮去除速率在0.19 g NO₃-N/(g VSS·d),连续运行30 d,系统保持稳定。分析认为,颗粒污泥表面微生物生长速度过快是导致不稳定的主要因素,较长的泥龄有利于系统稳定。