确定不同保证率下的中国酸沉降临界负荷

在进行中国酸沉降临界负荷区划时 ,通常以 1°× 1°(经纬度 )的网格为单位进行计算 ,难以反映网格内不同生态系统对酸沉降敏感性的差异 .为了便于决策者根据临界负荷确定酸沉降控制对策 ,也为了使 1°× 1°的结果更具代表性和实用性 ,本研究确定了 0 1°× 0 1°网格为单位计算的中国酸沉降临界负荷 ,并在此基础上通过引入保证率的概念 ,得到了一系列与一定的经济技术水平相适应的、允许有一定损失的 1°× 1°的中国酸沉降临界负荷图 .利用累积分布函数 ,本研究还确定了不同保证率下的中国酸沉降超临界负荷分布和各省、市、自治区的酸沉降临界负荷 .     

复合混凝剂处理印染废水

为了处理高浓度、高色度、高COD的印染废水，利用硫酸亚铁、工业废酸和金属下脚料自行配制了复合混凝剂，并将其与聚合双酸铝铁、聚合氯化铝铁、硫酸亚铁对印染废水的混凝效果进行对比。研究表明，复合混凝剂处理印染废水具有成本低、效果好的特点。当硫酸亚铁的投加量为200mg/L，复合混凝剂的投加量为1280mg／L，PAM的用量为2mg／L时，脱色率达94．9％，COD去除率达78．1％，悬浮固体（SS）去除率达90．9％。     

Insights into the mechanism of the deterioration of mainstream partial nitritation/anammox under low residual ammonium

Residual ammonium is a critical parameter affecting the stability of mainstream partial nitritation/anammox (PN/A), but the underlying mechanism remains unclear. In this study, mainstream PN/A was established and operated with progressively decreasing residual ammonium. PN/A deteriorated as the residual ammonium decreased to below 5 mg/L, and this was paralleled by a significant loss in anammox activity in situ and an increasing nitrite oxidation rate. Further analysis revealed that the low-ammonium condition directly decreased anammox activity in situ via two distinct mechanisms. First, anammox bacteria were located in the inner layer of the granular sludge, and thus were disadvantageous when competing for ammonium with ammonium-oxidizing bacteria (AOB) in the outer layer. Second, the complete ammonia oxidizer (comammox) was enriched at low residual ammonium concentrations because of its high ammonium affinity. Both AOB and comammox presented kinetic advantages over anammox bacteria. At high residual ammonium concentrations, nitrite-oxidizing bacteria (NOB) were effectively suppressed, even when their maximum activity was high due to competition for nitrite with anammox bacteria. At low residual ammonium concentrations, the decrease in anammox activity in situ led to an increase in nitrite availability for nitrite oxidation, facilitating the activation of NOB despite the dissolved oxygen limitation (0.15–0.35 mg/L) for NOB persisting throughout the operation. Therefore, the deterioration of mainstream PN/A at low residual ammonium was primarily triggered by a decline in anammox activity in situ. This study provides novel insights into the optimized design of mainstream PN/As in engineering applications.     

表面活性剂吸收法治理含苯废气的中试实验

采用添加表面活性剂的填料塔来吸收治理含苯废气，分析了水一吸收剂的吸收机理。考察了喷淋量、废气入口浓度和表面活性剂添加量这三个因素对苯去除率的影响。结果表明，对苯来说入口浓度对去除率的影响最大，喷淋液体流量次之，表面活性剂的影响最小。条件满足时，含苯废气可以达标排放。     

海绵铁预处理DSD酸废水的研究

用铁泥废渣制备水处理材料海绵铁,研究含碳球团直接还原的金属化率与还原时间,温度和铁泥粒度之间的关系,得到含碳球团制备海绵铁的反应参数。并对海绵铁预处理DSD酸废水的各种影响因素进行了试验研究,确定最佳试验条件;通过试验对海绵铁处理DSD酸废水的机理进行了探讨,确定它是电化学作用、电场作用、絮凝沉淀以及物理吸附等共同作用的结果。试验表明,海绵铁可作为高浓度DSD废水的预处理材料。     

层次分析法评价濠河水质研究

介绍了层次分析法的步骤 ,以濠河水质评价为例 ,建立了濠河断面 ,污染因子层次结构模型。运用层次模型计算各断面相对权重。将各断面的单因子指数进行排序。最终确定濠河水质从优—劣的总排序 :和平桥 >北濠桥 >跃南路 >三元桥 >长桥。为污染优先控制提供技术支持     

Petro-chemical wastewater treatment by biological process

Ｉｎｔｈｅｃｏｕｒｓｅｏｆｏｉｌｒｅｆｉｎｉｎｇ,ｏｒｇａｎｉｃｗａｓｔｅｗａｔｅｒｗｉｔｈｈｉｇｈｃｏｎｃｅｎｔｒａｔｉｏｎｏｆｅｍｕｌｓｉｆｉｅｄｏｉｌａｎｄｐｈｅｎｏｌｉｓｐｒｏｄｕｃｅｄ,ｓｏｆａｒ,ｔｈｅｍｅｔｈｏｄｓｏｆｐｈｙｓｉｃｏｃｈｅ?..     

改进密切值法在湖泊富营养化评价中的应用

密切值法(Osculating Method)作为一种多目标优选方法,在水环境质量评价中具有一定的应用.经过改进,将各级营养级别作为评价样本,参与到湖泊水环境样本的矩阵中,引入目标差值率对初始矩阵进行规范化处理,并应用层次分析法,对各评价指标的贡献程度加以确定.将改进后的密切值法应用于湖泊富营养化评价中.经实例分析表明,该方法概念清晰、计算简便实用,保证了湖泊水环境质量评价的科学性,能较好地反映湖泊水环境质量的优劣,并使其与各级营养级别的关系一目了然.     

Adsorption selectivity of salicylic acid and 5-sulfosalicylic acid onto hypercrosslinked polymeric adsorbents

Both bottle-point and column-feeding experiments involving different solutes and sorbents were carried out to investigate the adsorption selectivity and separation performance of salicylic acid and 5-sulfosalicylic acid. Their adsorption isotherms onto such hypercrosslinked polymeric adsorbents as NDA-100 and NDA-99 could be well described by the Freundlich equations whose characteristics describe extrathermic and favorable adsorption processes. The adsorption towards NDA-100 mainly depended on the π-π interaction, while that towards NDA-99 was extremely influenced by the static-electric interaction. Additionally, the adsorptive capacity of salicylic acid on NDA-99 decreased while it increased on NDA-100 with the presence of 5-sulfosalicylic acid in the adsorptive environment as the competitive component. Comparatively, the adsorption capacity of 5-sulfosalicylic acid decreased on both resins with salicylic acid as the competitive component. In fact, the difference in the interaction between adsorbent and adsorbate resulted in the straight antagonism on the effective adsorption sites on the adsorbent. In conclusion, the adsorption selectivity of salicylic acid onto NDA-100 was obviously larger than that onto NDA-99 with the existence of 5-sulfosalicylic acid in the adsorptive environment. A satisfactory separation and recovery of tested solutes in aqueous phase could be foreseeably achieved by the sequencing adsorption technique involving NDA-100 as well as NDA-99. Translated from Environmental Pollution & Control, 2005, 27(8): 570–574 [译自: 环境污染与防治]     

茂名石化炼油废水处理扩建一期工程A/O系统改O/O工艺运行探索

茂名石化炼油废水A/O系统改O/O工艺运行后,出水水质各项指标均达到国标和地标排放。为期两个月的工业试运行,为工艺操作与管理提供了经验和依据,同时也为二期工程的设计、施工和管理奠定了基础。