化学发光流动注射法测定雨水中过氧化氢

用化学发光流动注射分析装置,将16孔阀连接成异步双流路,以过氧化氢-鲁米诺-钴(Ⅱ)为化学发光体系,建立了快速测定雨水中过氧化氢的方法,最低检测限为0.1ng/ml,在0.1—400ppb范围内有良好的线性关系,相对标准差为0.78—3.03％,每小时可分析480个以上的样品.     

企业推行HSSE管理体系问题探讨

分析了企业安全管理体系运行中存在的体系文件模板化、体系运行"两张皮"和持续改进低效化等突出问题,探讨了企业推行HSSE管理体系的对策:提升企业最高管理层的引领力、部门的协同力和基层的执行力,发挥安全文化的影响力、渗透力,同时,要进一步细化体系运行有效性评价指标,做实内部审核和管理评审。     

Comparison of UV-based advanced oxidation processes for the removal of different fractions of NOM from drinking water

This study examined the effectiveness for degradation of hydrophobic (HPO), transphilic (TPI) and hydrophilic (HPI) fractions of natural organic matter (NOM) during UV/H₂O₂, UV/TiO₂ and UV/K₂S₂O₈ (UV/PS) advanced oxidation processes (AOPs). The changing characteristics of NOM were evaluated by dissolved organic carbon (DOC), the specific UV absorbance (SUVA), trihalomethanes formation potential (THMFP), organic halogen adsorbable on activated carbon formation potential (AOXFP) and parallel factor analysis of excitation–emission matrices (PARAFAC-EEMs). In the three UV-based AOPs, HPI fraction with low molecular weight and aromaticity was more likely to degradate than HPO and TPI, and the removal efficiency of SUVA for HPO was much higher than TPI and HPI fraction. In terms of the specific THMFP of HPO, TPI and HPI, a reduction was achieved in the UV/H₂O₂ process, and the higest removal rate even reached to 83%. UV/TiO₂ and UV/PS processes can only decrease the specific THMFP of HPI. The specific AOXFP of HPO, TPI and HPI fractions were all able to be degraded by the three UV-based AOPs, and HPO content is more susceptible to decompose than TPI and HPI content. UV/H₂O₂ was found to be the most effective treatment for the removal of THMFP and AOXFP under given conditions. C1 (microbial or marine derived humic-like substances), C2 (terrestrially derived humic-like substances) and C3 (tryptophan-like proteins) fluorescent components of HPO fraction were fairly labile across the UV-based AOPs treatment. C3 of each fraction of NOM was the most resistant to degrade upon the UV-based AOPs. Results from this study may provide the prediction about the consequence of UV-based AOPs for the degradation of different fractions of NOM with varied characteristics.     

泡沫分离--臭氧消毒装置的水处理效果研究

对闭合循环水产养殖系统中泡沫分离—臭氧消毒装置及泡沫分离装置的水处理效果进行研究。结果表明,泡沫分离—臭氧消毒装置对养殖水体中异养细菌去除率为93.58％,NH_4~ -N、NO_2~--N去除率分别为39.00％、38.10％,能明显提高水体pH和DO,对COD的去除效果不明显;连续运行24h,能有效控制养殖水体中的NO_2~--N浓度和异养细菌数量。泡沫分离装置出水口比进水口的NH_4~ -N、NO_2~--N和COD分别降低42.45％、24.71％、11.00％,能明显提高出水pH和DO;连续运行24h,对养殖系统中的NH_4~ -N和NO_2~--N有一定的处理效果。     

洛阳石化环境质量管理系统的开发及应用

洛阳石化开发的环境质量管理系统，实现了对环保监测站化验分析数据的自动采集、污染源分析数据的汇总统计分析。统计报表的自动生成和打印。系统建立了以废水、废气重点污染源排放点的污染源自动监测系统，对污染源进行实时监控与分析；系统具备方便直观的数据发布功能和人员、设备、库房等事务管理功能。     

Long-term nitrogen and phosphorus removal,shifts of functional bacteria and fate of resistance genes in bioretention systems under sulfamethoxazole stress

To understand the long-term performance of bioretention systems under sulfamethoxazole (SMX) stress, an unplanted bioretention system (BRS) and two modified BRSs with coconut-shell activated carbon (CAC) and CAC/zero-valent-iron (Fe0) granules (CAC-BRS and Fe/CAC-BRS) were established. Both CAC-BRS and Fe/CAC-BRS significantly outperformed BRS in removing total nitrogen (TN)(CAC-BRS:82.48%; Fe/CAC-BRS:78.08%; BRS:47.51%), total phosphorous (TP)(CAC-BRS:79.36%; Fe/CAC-BRS:98.26%; BRS:41.99%),and...     

HAZOP方法在炼化企业供电系统评估中的应用

基于HAZOP的方法对炼化企业电力系统进行分析,可以有效提高炼化企业电气安全平稳运行水平,降低发生大面积停电事故的风险。该分析方法不同于化工企业的HAZOP分析方法,在分析流程细节中,结合电气专业化的特点,形成了一套具有炼化企业供电系统风险评估特色的评价方法,为炼化企业供电系统在规划、设计、运行等阶段提供依据。     

天然气压缩机站的安全生产管理

天然气压缩机组目前在油田的注气采油，增压外输等方面发挥着越来越重要的作用。在压缩机站的生产管理中，安全管理非常重要，建立健全安全规范将对压缩机站的安全运行提供保证。本文主要从油水管理，操作规程，容器管网，安全教育等方面进行阐述。     

湖泊水质参数空间分析中异常值的识别与处理

异常值的存在对湖泊水质参数局部估计精度产生重要影响 ,制约了地统计学在湖泊水质研究中的应用。文章以太湖为例 ,介绍了在湖泊水质参数研究中的三种异常值识别和处理的方法。应用这些方法可以有效地降低异常值的影响水平