Highly sensitive and selective determination of malathion in vegetable extracts by an electrochemical sensor based on Cu-metal organic framework

Abstract

This article demonstrates the first application of a copper-based porous coordination polymer (BTCA-P-Cu-CP) as a carbon paste electrode (CPE) modifier for the detection of malathion. The electrochemical behavior of BTCA-P-Cu-CP/CPE was explored using cyclic voltammetry (CV) while chrono-amperometry methods were applied for the analytical evaluation of the sensor performance. Under optimized conditions, the developed sensor exhibited high reproducibility, stability, and wide dynamic range (0.6–24?nM) with the limits of detection and sensitivity equal to 0.17?nM and 5.7 µAnMcm^?1, respectively, based on inhibition signal measurement. Furthermore, the presence of common coexisting interfering species showed a minor change in signals (<4.4%). The developed sensor has been applied in the determination of malathion in spiked vegetable extracts. It exhibited promising results in term of fast and sensitive determination of malathion in real samples at trace level with recoveries of 91.0 to 104.4%. (RSDs < 5%, n?=?3). A comparison of the two studied techniques showed that the HPLC technique is unable to detect malathion when the concentration is lower than 1.8?µM while 0.006 µM is detected with appropriate RSDs 0.2–5.2% (n?=?3) by amperometric method. Due to the high sensitivity and selectivity, this new electrochemical sensor will be useful for monitoring trace malathion in real samples.     

环境公平问题既有研究述评及研究框架思考

环境不公平问题,日益成为经济发展现实中的一个重要问题,也日益成为环境经济学的一个着重关注领域,但既有的研究尚缺乏系统性和理论基础。本文系统梳理了国内外关于环境公平定义的代表性观点,在此基础上提出了作者对环境公平的认识。然后笔者在各种形式的环境不公平研究(包括不同群体间的环境不公平问题的研究和不同区域间的环境不公平问题的研究)、环境公平问题的研究方法(主要指基于地理信息系统获取相应的变量数据进而用计量模型的方法和借鉴收入差距的分析方法)等既有研究进行梳理和简要评述的基础上,提出:环境不公平问题的实质是经济利益不公平问题的转化与延伸,应在这一认识前提下来探讨环境公平问题、来建立环境公平问题的研究框架。进而提出:以经济学方法讨论利益主体之间如何实现公平享有环境利益、公平分配使用环境容量、公平承受环境破坏后果、公平分担环境维护责任、公平分担环境治理成本,是环境公平问题研究的主要方向。     

中国环保行政体制结构初探

环保行政体制结构是环保行政组织系统的基本框架,是实现环保行政管理职能的组织方式。我国长期以来的环保行政体制改革较为关注机构地位提升与管理职能强化,环保行政体制的结构较少得到关注。对环保行政体制结构的分析揭示了在机构地位提升与管理职能得到强化的前提下我国环保行政管理依然面临执法监督难、部门协调难等问难题的深层体制原因。本文首先根据组织行为学的基本原理,提出我国环保行政体制的矩阵结构模式,这一矩阵结构在纵向上存在双权威系统,横向上协调关系较为薄弱,从而造成环保监管权威弱化。其次,基于对我国地方环保行政体制改革效果的调查,指出我国环保行政体制结构出的了若干变化。最后,结合我国"十二五"时期落实国家环保意志的基本要求,提出改善我国环保行政体制结构的若干政策建议,即在基层改善体制结构中的双权威系统,并以流域水环境管理体制创新为大部门体制改革突破点,探索环境管理职能组织方式的优化途径。     

中国能源安全的路径选择与战略框架

能源是国民经济可持续发展的基础,可持续能源战略对保障国家能源安全具有重要意义,能源安全与能源战略日益成为当前国际社会和国家安全战略中备受关注的重大问题.本文从中国的现实状况出发,阐述了制定国家能源安全战略的重要性,提出了能源安全的选择路径,构建了全面性能源安全战略框架,为制定我国长期能源安全战略提供参考.论文认为:国家能源安全战略是能源可持续供给、社会经济健康发展、突发事件合理应对、生态环境安全的重要保障;中国能源安全的路径应从能源供给安全、能源生产和使用安全、能源运输安全、能源环境安全及能源安全预警机制等方面进行选择;健全能源管理体制、能源政策、能源市场、能源技术、能源战略储备、提高输送能力、能源环境与节能是能源安全战略框架的重要内容.并提出以下建议:建立国家能源安全综合协调机构;运用市场机制提高能源效率,促进能源利用多元化;加快替代能源和新能源的技术研发;加强能源资源的战略储备.     

Benchmarking of power cycles with CO2 capture—The impact of the selected framework

The paper puts focus on the selection of an appropriate framework for benchmarking studies of power cycles with CO₂ capture. The need for a reference power plant without CO₂ capture in a benchmarking study is emphasized. The impact of the use of site-specific plant boundary conditions is discussed as well as the selection of computational assumptions to reflect future technology development. A significant part of the paper is dedicated to a study of how changes in the benchmarking framework to reflect technology development can give additional knowledge about the potential for different CO₂ capture technologies. A major conclusion, based on the findings, is that it should be highly relevant for technology providers to investigate the future development potential for a CO₂ capture technology before launching a product development program.     

2006年促进职业安全与健康框架公约和建议书介绍及相关问题探讨

《2006年促进职业安全与健康框架公约》(C187,2006)和《职业安全与健康框架建议书》(R197,2006)的公布是为了进一步减少全球发生的大量职业性伤病和死亡,保护工人免受因就业而引发的病患和伤害,降低职业性伤病和死亡对劳动生产率和经济与社会发展的负面影响。本文对《公约》及《建议书》的主要内容,包括《公约》中的定义、《公约》制定的目标、国家政策、国家制度、国家计划等进行了详细的介绍和分析,以期继续推广预防性安全健康文化建设。     

Erosion Control at Construction Sites: The Science–Policy Gap

/ To test the effectiveness of Michigan's soil erosion control law, 30 construction sites were evaluated in the east-central part of the state. The analytical framework lumped nine best management practices (BMPs) most closely related to the law into three categories: slope stabilization, soil stabilization, and water management. All sites were in the land clearing or foundation/framing stage of construction and were evaluated within 2 days after a rainfall event. Only four of the sites performed above the mean of the scoring scale, with the categorical scoring of BMPs indicating the worst performance for slope stabilization measures. The poor results suggest a failure to integrate scientific knowledge of erosion control with policy. A fundamental problem is the lack of basic site data on soil, topography, and hydrology, resulting in the incorrect application of BMPs, such as staging, filter fences, and berms. The current institutional framework for soil erosion control also provides disincentives to mitigate local erosion problems.     

城市公共危机管理框架及系统平台研究

在分析公共危机特点和危机管理的关键问题的基础上,归纳了城市公共危机管理的9个主题,从组织结构、信息系统、应急计划、社会应对能力4个层面提炼出较为完整的、针对城市的公共危机管理框架。基于该框架,按照日常管理与应急管理相结合的要求,设计了城市公共危机管理系统平台概念模型,详细分析了系统各个模块之间的关系;并从危机监测分析和危机应急指挥两个层面具体研究了系统平台技术体系和建设方法。最后,对公共危机管理系统建设现状和未来研究重点进行了讨论。     

对我院英语分级教学的进一步探索

我校从2005年开始在大一年级试实施分级教学，一个学期的教学实践证明我们的改革是可行的，我们的分级教学取得了初步的效果。     

QUANTIFYING URBAN INTENSITY IN DRAINAGE BASINS FOR ASSESSING STREAM ECOLOGICAL CONDITIONS1

ABSTRACT: Three investigations are underway, as part of the U.S. Geological Survey's National Water‐Quality Assessment (NAWQA) Program, to study the relation between varying levels of urban intensity in drainage basins and in‐stream water quality, measured by physical, chemical, and biological factors. These studies are being conducted in the vicinities of Boston (Massachusetts), Salt Lake City (Utah), and Birmingham (Alabama), areas where rapid urbanization is occurring. For each study, water quality will be sampled in approximately 30 drainage basins that represent a gradient of urban intensity. This paper focuses on the methods used to characterize and select the basins used in the studies. It presents a methodology for limiting the variability of natural landscape characteristics in the potential study drainage basins and for ranking the magnitude of human influence, or urbanization, based on land cover, infrastructure, and socioeconomic data in potential study basins. Basin characterization efforts associated with the Boston study are described for illustrative purposes.