钴磷合金催化剂的制备及其催化分解磷化氢的研究

采用诱导化学沉积法制备系列Co-P合金,并将其引入PH3的分解试验.结果表明,所有样品均具有在较低温度下催化分解PH3的性能,且测定的表观催化反应温度随合金中磷质量分数的升高而降低,当磷的质量分数≥7.7%时,表观催化反应温度＜450 ℃.选取Co86.3P13.7样品进行催化分解PH3气体的研究表明,实验条件下,PH3分解率随催化反应温度的升高呈现先增后减的趋势,但随总通气流量QPH3 QN2或通气量比QN2∶QPH3的增大而降低.控制催化反应温度为470 ℃、PH3进气流量QPH3=4～6 mL/min、通气比QN2∶QPH3=33～35时,催化剂可发挥最佳的催化性能,此时PH3的分解率达95%以上.对Co86.3P13.7不同处理温度下的X射线衍射(XRD)表征分析表明,样品在催化反应温度下发生晶化,有磷化物Co2P析出,但催化反应测试温度范围内晶化后的催化剂基本保持稳定.     

On Characteristics of Production and Destruction Processes in Lowland and Mountain Tundras of the Extreme North

Parameters of the production and destruction processes in different types of tundras are compared. It is shown that there is a fairly high degree of correspondence between the structure of tundra communities and the ecotopes occupied by them. On the other hand, typologically similar lowland and mountain tundras markedly differ in the functional respect. The rate of decomposition processes is higher under environmental conditions of the mountain tundra belt.     

建设火电厂生态工业园的研究

通过建设以火电厂为中心的生态工业园的初步研究,阐述了建设生态工业园的重要意义,详细探讨了不同产业间的资源相互最大利用的循环经济发展模式,并总结了建设生态工业园经济发展模式的经验以及可能存在的问题,为各地建设类似生态工业园提供参考.     

便携式空调系统研究

在炎热环境中,便携式空调系统可以对人的身体进行冷热调节,创造一种微气候环境。根据Natick士兵中心研究结果:只要提供300 W制冷量就能满足一个人的热负荷需求。北京工业大学研制了微型蒸汽压缩制冷系统作为便携式空调的冷源,微型制冷系统的制冷量为300 W,重量为2．85 kg,几何尺寸为270 mm×260 mm×120 mm。采用强化传热措施及轻质材料来减小微型制冷系统的重量及体积。     

城市污水处理厂污泥稳定性与污水处理工艺关系研究

选取SCOD／TCOD作为评价稳定程度的标准，通过碱解液化的实验方法，对徐州市7个不同工艺的污水处理厂污泥稳定性进行了测试，以求污泥稳定性与污水处理工艺的关系，从而为污水处理工艺是否需要建设污泥消化池以及如何优化污水与污泥处理工艺系统提供参考性建议。     

小波分解在空气污染指数分析中的应用

本文利用Mallat分解在不同时频域的多分辩分析能力，以可吸入颗粒物污染指数为例，将其分解到不同的频域中进行分析，通过实际应用证明其效果良好。将Mallat法应用于上海市城区全年可吸入颗粒物、SO2、NO2等污染物的分析研究当中，发现秋冬两季煤、油等燃料的不完全燃烧对颗粒物浓度的增加影响最大，而汽车尾气对后两者浓度增加的影响也较大。     

重庆市基于排放绩效的火电行业二氧化硫总量控制研究

本文介绍了排放绩效及排放绩效方法在火电行业二氧化硫总量控制方面的应用，并对重庆市火电机组及其二氧化硫排放状况进行了全面调查，根据重庆市二氧化硫污染防治的需要制定了各时段机组“十一五”期间的排放绩效控制标准，利用排放绩效方法测算了重庆市火电行业二氧化硫总量控制目标，提出了总量配额分配方法。     

Micro calorimeter study on the thermal stability of lithium-ion battery electrolytes

With the extensive applications of lithium-ion batteries, many batteries explosion accidents were reported. The thermal stability of lithium-ion battery electrolyte could substantially affect the safety of lithium-ion battery. The C80 micro calorimeter was used to study the thermal stability of several commonly used organic solvents and electrolytes. The samples were heated in argon atmosphere and air atmosphere, respectively. The chemical reaction kinetics was supposed to fit by an Arrhenius law, then the self-accelerating decomposition temperature was calculated. It is found that most of the samples are stable in argon atmosphere while decomposing in air atmosphere, and the single organic solvent is more stable than the electrolyte generally.     

SIMULATED EFFECTS OF ALTERED SPILLWAY RELEASES ON THERMAL STRUCTURE AND KOKANEE GROWTH IN A COLORADO RESERVOIR1

ABSTRACT: In‐reservoir thermal and ecological effects of releasing some flows over the surface spillway at Blue Mesa Reservoir, Colorado, rather than routing all releases through the hypolimnetic outlet were evaluated using a calibrated and validated one‐dimensional thermal model (CE‐THERM) with a set of ecological models. Thermal model output indicated that surface water temperatures were influenced primarily by atmospheric conditions, but the release of warmer water over the spillway resulted in a thinner epilimnion and cooler metalimnetic water temperatures. Ecological model predictions indicated that spillway releases and associated temperatures resulted in lower growth rates for young‐of‐year (YOY) kokanee salmon (Oncorhynchus nerka) in the reservoir by up to 9 percent when compared with growth rates under baseline operations with no releases over the spillway. Kokanee growth rates were reduced under spillway release scenarios because lower temperatures not only affected metabolic rates, but limited the productivity of the zooplankton as well. Thus, altering the release regime with spillway discharges could have deleterious effects on Blue Mesa's YOY kokanee. However, in other reservoirs, distributing discharges among different elevations may provide managers with a mechanism to regulate temperatures to benefit species of concern that are facing challenges imposed by environmental conditions such as global warming.     

Soybean-Oil-Based Polyisocyanurate Rigid Foams

Polyisocyanurate foams were prepared from polymeric 4,4-diphenylmethane diisocyanate (MDI), soy polyol and polypropylene oxide polyol by varying isocyanate index from 110 to 350. The higher isocyanate index produced polyisocyanurate foams with higher thermal stability, improved flame resistance, tensile strength, higher modulus, and higher glass transition. Soy-based foams displayed better thermal stability, lower flammability, higher rigidity (modulus) and higher compression strength than those based on the propylene oxide polyols of the same molecular weight and functionality.