顶空气相色谱法测定食品中甜蜜素含量

采用顶空气相色谱法测定食品中甜蜜素含量,探讨了气液相平衡条件及色谱条件的选择,实验结果表明甜蜜素的标准溶液在0.1-0.4μg/l范围内具有良好的线性关系,回收率为87.5%-101.8%,相对标准偏差为2.6%.     

室内有毒易爆气体的检测

随着城市生活水平的提高,室内装修装饰日益普及.各种新材料的引入,使得室内的各种有害气体总量日益增加.长期生活在这样的环境下,会对人体健康产生极为不利的影响.居民生活用煤气,在给人们生活带来便利的同时,作为一种可燃性、有毒气体,也具有极强的危害性.因此,研制一种能检测多种有害气体的实用仪器,具有很大的应用价值.本仪器为便携式多功能仪器,采用可充电电池供电,可以检测ppb的挥发性气体,显示气体浓度值,也可检测煤气,并具有声光报警功能.     

Systems thinking in a gas explosion accident – lessons learned from Taiwan

On July 31, 2014, at around 23:57, several huge explosions occurred that lasted for 2 h in Kaohsiung City, Taiwan. As a result of a gas leak from a ruptured underground pipeline, the catastrophic incident destroyed more than 6 km of roads, killed 32 people, injured 321 people, and damaged 3259 buildings. Pipeline explosions have been reported as a repeatedly occurring problem, indicating that (1) complex systems are difficult to manage and control, and (2) humans are unable to effectively learn from experiences of accidents. Initial analyses results reveal that root causes of this incident were a combination of a series of complex chain reactions, which eventually led to propylene leakage and explosion. This is a systematic problem, which can hardly be investigated or analyzed by traditional research approaches. Based on the investigation reports and “systems thinking” method, this study develops causal loop diagrams for the Kaohsiung gas explosion to explore the root causes of the disaster. The research results indicate that (1) this pipeline explosion incident was the result of the chain reactions and was the output of a complex system; (2) the mental model of “production first” and “experience gap” were the root causes of the disaster; and (3) to achieve a higher safety standard, continuous education to improve the mental model of “safety first and safety over production” are essential. The findings of this study may contribute toward the improvement of the standard operating procedure for disaster management and preventing similar incidents in the future.     

毛细管柱气相色谱法测定工作场所空气中的丙烯腈

为了建立采用毛细管柱测定工作场所空气中丙烯腈浓度的方法,使用活性炭管采集工作场所空气中的丙烯腈,二硫化碳溶液解吸,毛细管柱分离后,用氢火焰离子化检测器检测。结果显示:丙烯腈的检出限为0.73μg/ml,相关系数为0.9998,解吸效率94.3%～104.7%,相对标准偏差为0.41%～1.0%。因此,该方法灵敏度高、检测准确、操作性强,可提高丙烯腈的检测效率,适用于工作场所空气中丙烯腈的分析。     

Experimental study on explosion inhibition by heptafluoropropane and its synergy with inert gas

The inhibition effect of heptafluoropropane (CF₃CHFCF₃) on methane explosions under different inhibitor concentrations in a closed vessel was studied. A high-speed camera and a pressure sensor were adopted respectively to record flame propagation characteristics and pressure data. Results indicate that the relationship between flame propagation and pressure rising was correlated. As the equivalent ratio (ϕ)≤1, the pressure presented a trend of rising firstly and then decreasing with increasing CF₃CHFCF₃ concentration, and it was found that there existed a critical concentration for pressure decrease. As ϕ > 1, the pressure exhibited a decreasing trend. Although the pressure appeared to seemingly increase, the moment that the pressure began to rise (t_rise) and the moment that the maximum explosion overpressure appeared (t_Pmax) were obviously delayed. The average rate of pressure rise ((dP/dt)_ave) was decreased as the concentration of CF3CHFCF3 increased. It indicates that CF₃CHFCF₃ can effectively reduce the explosion reaction rate. The critical concentration of CF₃CHFCF₃ for complete inhibition was determined. Meanwhile, the synergy of CF₃CHFCF₃-inert gas can improve the inhibition effect. Compared with CF₃CHFCF₃–N₂, the synergy of CF₃CHFCF₃–CO₂ presented a better inhibition effect, and the inhibition effect was increased with increasing inert gas concentration. And the mechanisms of physical and chemical effects on explosion inhibition were analyzed.     

考虑松动圈影响的钻孔瓦斯抽放合理封孔长度确定研究

以王行庄矿11071工作面为工程试验地点,通过超声波和钻孔窥视现场测试,结合理论计算,开展了瓦斯抽采煤巷松动圈范围和瓦斯抽放钻孔合理封孔长度确定的研究。确定了王行庄11071工作面二1煤层围岩卸压区宽度为8.87 m,极限平衡区宽度为9.87 m,合理封孔深度为10 m;通过极限平衡法理论计算得到的结果与超声波法、钻孔窥视法的测试结果基本相符。     

煤矿火灾烟气流动传播过程仿真研究

煤矿发生火灾后会生成大量有毒气体并产生火风压,烟气在火灾动力的影响下出现状态紊乱,研究煤矿火灾烟气流动传播过程对控制火情有着重要意义。基于国内外研究现状,对燃烧及风流特点进行分析,建立了煤矿火灾烟气流动数学模型,并利用CFD软件进行仿真。研究表明:无通风工况下的烟气为对称流动;随着风速增加,出口处温度降低,烟气向风流入口处的流速减小。     

Effects of particle thermal characteristics on flame microstructures during dust explosions of three long-chain monobasic alcohols in a half-closed chamber

To reveal clearly the effects of particle thermal characteristics on flame microstructures during organic dust explosions, three long-chain monobasic alcohols, solid at room temperature and similar in physical-chemical properties, were chosen to conduct experiments in a half-closed chamber. In the experiments, the dust materials were dispersed into the chamber by air to form dust clouds and the hybrids were ignited by an electrical spark. A high-speed optical schlieren system was used to record the flame propagation behaviors. A fine thermocouple and an ion current probe were respectively used to measure the flame temperature profile and the reaction behaviors of the combustion zone. Based on the experimental results, combustion behaviors and flame microstructures in dust clouds with different thermal characteristics were analyzed in detail. As a result, it was found that the dust flame surfaces were completely covered by cellular structures that significantly increased the flame frontal areas. Flame propagated more quickly and the number of the cellular cells increased as increasing the volatility of the particles. On the contrary, maximum temperature and the thickness of the preheated zone decreased as increasing the volatility of the particles. According to the ion current profile, the particles in the preheat zone were pyrolyzed to intermediate radicals and the radicals' fraction in the higher volatile dust flame was higher than that in the lower volatile dust flame.     

Application of the QuEChERS method for the determination of organochlorine pesticide residues in Brazilian fruit pulps by GC-ECD

The Quick, Easy, Cheap, Effective, Rugged, and Safe (QuEChERS) method was applied to the extraction of 14 organochlorine pesticides (OCPs) residues from commercial fruit pulps available in supermarkets in Fortaleza, Northeastern Brazil. The analyses were carried out by gas chromatography (GC), coupled to an electron-capture detector (ECD), and were confirmed by GC-tandem mass spectrometry (MS). The parameters of the analytical method, such as accuracy, precision, linear range, limits of detection and quantification, were determined for each pesticide. The results showed good linearity (R² ≥ 0.9916) and the overall average recoveries were considered satisfactory obtaining values between 69 and 110%, RSD of 2–15 %, except for hexachlorobenzene (HCB) in açai, acerola and guava pulp samples. The OCPs were detected in guava (α–HCH; lindane) and soursop (α, β–HCH isomers) samples. The QuEChERS method and GC–ECD were successfully used to analyze OCPs in commercially available Brazilian fruit pulps and can be applied in routine analytical laboratories.     

云技术在石油行业应急管理中的思考

面对石油行业突发事件全过程,利用大数据云处理技术,以应急管理4阶段为划分标准,将云技术运用到应急管理四大阶段当中,为解决缺乏合理的信息技术手段、应急信息搜集不全面、数据挖掘分析技术落后、决策支持模型构建不完善等落后的临时性应急管理模式,找寻到一种高效应急管理模式的新方向。