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11.
《环境科学学报(英文版)》2023,35(4):517-530
Graphite carbon nitride has many excellent properties as a two-dimensional semiconductor material so that it has a wide application prospect in the field of photocatalysis. However, the traditional problems such as high recombination rate of photogenerated carriers limit its application. In this work, we introduce nitrogen deficiency into g-C3N4 to solve this problem a simple and safe in-situ reduction method. g-C3N4/CaCO3 was obtained by a simple and safe one-step calcination method with industrial-grade micron particles CaCO3. Cyano group modification was in-situ reduced during the thermal polymerization process, which would change the internal electronic structure of g-C3N4. The successful combination of g-C3N4 and CaCO3 and the introduction of cyanide have been proved by Fourier transform infrared spectroscopy and X-ray photoelectron spectrometer. The formation of the cyano group, an electron-absorbing group, promotes the effective separation of photogenic electron hole pairs and inhibits the recombination of photogenic carriers. These advantages result in the generation of more •O2− and 1O2 in the catalytic system, which increases the photocatalytic efficiency of nicotine degradation by ten times. Furthermore, the degradation process of nicotine has been studied in this work to provide a basis for the degradation of nicotine organic pollutants in the air. 相似文献
12.
通过批次实验探究了不同有机物对铁盐化学除磷的影响.结果显示,有机物对铁盐化学除磷的不利影响由强到弱依次为柠檬酸、黄腐酸、聚山梨酯-80、牛血清蛋白、葡萄糖、淀粉,柠檬酸的影响程度为其他五种有机物的5~20倍.较之含羟基有机物,含羧基有机物对铁盐除磷的不利影响更大.研究表明:铁盐化学除磷的实质是通过形成铁羟基氧化物(HFO)来除磷.含羧基有机物,如柠檬酸,可与磷酸根竞争HFO,有机物"抢占"HFO表面结合位点导致磷酸盐与HFO结合减少,从而使铁盐除磷效果下降.在所试柠檬酸浓度范围内,铁盐除磷率最高下降了90.70%. 相似文献
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14.
Zhang Qide Wang Yuxi Yu Shuqing Song Liming Liu Xianwan Li Changzhi Lin Hejie 《环境科学学报(英文版)》1989,1(1):73-84
The authors seek, through tests on simulated sand samples in a wind tunnel and analysis of minerals combination and trace elements, to discover the environmental implications of flying-up, falling-down and concentration variation as a function of natural wind speed and direction, distance of movement, range and extent of influence on the atmospheric environment, of micro-granular components on the ground surface in the Keerqin desert area in northwest Liaoning Province of China. 相似文献
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Georgios E. Pavlikakis Vassilios A. Tsihrintzis 《Journal of the American Water Resources Association》2003,39(2):277-288
ABSTRACT: The Ecosystem Management (EM) process belongs to the category of Multi‐Criteria Decision Making (MCDM) problems. It requires appropriate decision support systems (DSS) where “all interested people” would be involved in the decision making process. Environmental values critical to EM, such as the biological diversity, health, productivity and sustainability, have to be studied, and play an important role in modeling the ecosystem functions; human values and preferences also influence decision making. Public participation in decision and policy making is one of the elements that differentiate EM from the traditional methods of management. Here, a methodology is presented on how to quantify human preferences in EM decision making. The case study of the National Park of River Nestos Delta and Lakes Vistonida and Ismarida in Greece, presented as an application of this methodology, shows that the direct involvement of the public, the quantification of its preferences and the decision maker's attitude provide a strong tool to the EM decision making process. Public preferences have been given certain weights and three MCDM methods, namely, the Expected Utility Method, Compromise Programming and the Analytic Hierarchy Process, have been used to select alternative management solutions that lead to the best configuration of the ecosystem and are also socially acceptable. 相似文献
17.
分析了膨胀岩的胀缩机理及影响因素,总结了近几年的理论研究成果。着重论述了巷道和边坡工程中的膨胀 岩所造成的灾害形式,通过分析诱发灾害的机理,有针对性地提出了一些防治措施。 相似文献
18.
Mechanical Properties with the Functional Group of Additives for Starch/PVA Blend Film 总被引:1,自引:0,他引:1
This paper deals with the mechanical properties and degree of swelling (DS) of starch/PVA blend film with the functional groups
i.e., hydroxyl and carboxyl group, of additives. Starch/PVA blend films were prepared by using the mixing process. Glycerol
(GL) with 3 hydroxyl group, sorbitol (SO) with 6 hydroxyl group, succinic acid (SA) with 2 carboxyl group, malic acid (MA)
with 1 hydroxyl and 2 carboxyl group, tartaric acid (TA) with 2 hydroxyl and 2 carboxyl group and citric acid (CA) with 1
hydroxyl and 3 carboxyl group were used as additives. The results of measured tensile strength (TS) and elongation (%E) verified
that both hydroxyl and carboxyl group as a functional groups increased the flexibility and strength of the film. Values of
DS for GL-added and SA-added films were low. However, DS values of the films added MA, TA or CA with both hydroxyl and carboxyl
group were comparatively high. When the film was dried at low temperature, the properties of the films were evidently improved.
The reason is probably because the hydrogen bonding was activated at low temperature. 相似文献
19.
瑞利波探测公路施工隧道地质灾害的可行性分析 总被引:3,自引:1,他引:3
瑞利波探测是一种原位测试的工程地震探测技术,其频散曲线的变化与地下地质条件存在联系,通过频散曲线的特征识别,可得到探测方向上一定范围内的地质构造情况;瑞利波在介质中的传播速度与介质的工程物理特性有关,据此可对探测范围内岩土的物理力学性质做出评价.本文针对公路隧道施工过程中普遍存在的地质问题,结合瑞利波的探测原理,论述了瑞利波探测公路隧道施工地质灾害的可行性. 相似文献
20.
李瑞粦 《中国安全生产科学技术》2006,2(5):41-44
本文根据广州市地质水文气象及隧道暗挖工程的施工特点,对广州市轨道交通工程隧道暗挖塌方事故进行了危险性分析,阐述了隧道暗挖工程的竖井、隧道开挖施工中塌方事故的主要防控对策与预防措施,以及塌方事故的应急准备及响应要点。 相似文献