气溶胶中的水溶性有机物研究进展

首先指出了对气溶胶中水溶性有机物（ ＷＳＯＣ） 研究的意义，接着对气溶胶中水溶性有机物的分子组成、来源和浓度水平进行了介绍，综述了采样和分析方法的历史及其进展，并对当前研究工作中存在的问题和在中国的应用前景进行了评述     

近年来昆明关上点降水酸度浅析

昆明市关上点历年降水均偏酸性，且近年来酸雨频次有所增多，频率有所增高，主要是昆明市地形地貌、气候特征、土壤酸度及废气排放中酸性物质排放量逐年上升所致。     

Effects of methyl-CD and humic acid on hydrolytic degradation of the herbicide diclofop-methyl

Hydrolytic degradation of the herbicide diclofop-methyl was investigated in the multi-pH deionized water, natural aquatic systems and soil suspensions. Resulting data indicated that the herbicide was stable in the acidic and neady neutral solutions for at least 15 d. The herbicide diclofop-methyl rapidly dissipated in the natural aquatic systems and soil suspensions with half-lives less than 4 d. Methyl-CD(partially methylated β-cyclodextdn) improved its hydrolytic degradation in the pH 8 deionized water and natural aquatic systems while humic acid inhibited its hydrolytic degradation at the same conditions. But dissolved organic matter in the natural aquatic systems and soil suspensions increased its hydrolysis. Two catalysis mechanisms were introduced to describe the effects of cyclodextrin and organic matter on its hydrolytic metabolism. Though inorganic ions maybe improved its hydrolysis reaction in the natural aquatic systems, Fe^2 and Cu^2 did not form complexes with the herbicide and had poor influences on its hydrolytic degradation whether cyclodextrin was added or not.     

云南省酸雨控制区二氧化硫污染现状及综合防治措施

能源结构的特点,使酸雨控制区的二氧化硫排放量高居不下,"西电东送"将进一步增加酸雨控制区的二氧化硫排放量.必须采取严格的、切实有效的综合防治措施削减二氧化硫排放量,确保"十五"期间酸雨控制区总目标的实现.     

The transformation of outdoor ammonium nitrate aerosols in the indoor environment

Recent studies associate particulate air pollution with adverse health effects; however, the exposure to indoor particles of outdoor origin is not well characterized, particularly for individual chemical species. We conducted a field study in an unoccupied, single-story residence in Clovis, California to provide data and analyses to address issues important for assessing exposure. We used real-time particle monitors both outdoors and indoors to quantify nitrate, sulfate, and carbon particulate matter of particle size 2.5 μm or less in diameter (PM-2.5). The results show that measured indoor ammonium nitrate concentrations were significantly lower than would be expected based solely on penetration and deposition losses. The additional reduction can be attributed to the transformation indoors of ammonium nitrate into ammonia and nitric acid gases, which are subsequently lost by deposition and sorption to indoor surfaces. A mass balance model that accounts for the kinetics of ammonium nitrate evaporation was able to reproduce measured indoor ammonium nitrate and nitric acid concentrations, resulting in a fitted value of the deposition velocity for nitric acid of 0.56 cm s⁻¹. The results indicate that indoor exposure to outdoor ammonium nitrate in Central Valley of California are small, and suggest that exposure assessments based on total particle mass measured outdoors may obscure the actual causal relationships for indoor exposure to particles of outdoor origin.     

磷钨酸光催化降解甲基橙溶液的研究

以磷钨酸为光催化剂,在紫外灯照射下,对模拟染料废水甲基橙溶液进行光催化降解,并研究了催化剂加入量、pH值、甲基橙初始浓度和外加氧化剂H2O2对光催化降解效果的影响.结果表明,磷钨酸光催化剂加入量为300 mg/100 mL,pH=2.5时,甲基橙溶液的降解率明显高于其他pH值的降解率;在较低浓度下,甲基橙溶液的光催化降解反应符合一级动力学方程;外加氧化剂H2O2可提高光催化反应速率.     

无机陶瓷纳滤膜分离高钠盐废水中的锶

本实验研究表明,仅用截留分子量为1000的无机陶瓷纳滤膜分离高钠盐模拟溶液中的锶,分离效果并不理想.为提高陶瓷纳滤膜对锶的选择分离效果,选择了分子量为3000的聚丙烯酸作为陶瓷纳滤膜分离的强化剂,重点探讨了溶液pH值、聚丙烯酸浓度、温度及离子强度对模拟溶液盐分离效果和膜通量的影响,并得到了适宜的锶钠分离条件.实验结果表明,在适宜条件下,通过聚丙烯酸强化和两级分离,陶瓷纳滤膜可大大提高模拟溶液中锶离子的选择分离效果,锶/钠的分离因子高达205.     

施加磷元素后对小麦抗重金属铜毒性的影响

将小麦幼苗放在含有不同浓度磷元素（1 mmol/L和10 mmol/L）和铜元素（0.16μmol/L、100μmol/L和1 mmol/L）的培养液中处理12 h后,观察植物体内铜元素的含量、叶绿素含量、抗坏血酸循环的变化.结果表明,当培养液中施加的铜元素浓度相同时,施加较高浓度的磷（10 mmol/L）能促进植物根部吸收和积累铜,并能促进铜元素从根部向地上部的运输.此外,实验结果还表明,当培养液中都含有较少量的铜（0.16μmol/L）元素时,比较磷浓度对植物体内生理反应的影响时,发现在含有高浓度磷的培养液中培养的小麦体内的受到较少的膜质过氧化损伤,光合色素的含量保持稳定.但是,当培养液中有较高浓度的铜元素（100μmol/L和1 mmol/L）时,施加高浓度的磷反而加剧了植物体内的膜质过氧化损伤和引起光合色素的分解,从而不利于植物正常的生长发育.     

酸雨对苏州市文物古建筑的影响初探

近年来，苏州市区酸雨出现频率增加，降水pH值下降，威胁着众多的文物古建筑。因此从苏州现存文物古建筑的五种材质入手，剖析酸雨对文物古建筑的影响，并对国家重点保护文物罗汉院双塔及正殿遗址典型的案例进行了剖析。     

基于不同基质的强化生物除磷系统中生化反应机理研究进展

阐述了3种不同基质(乙酸盐、丙酸盐和葡萄糖)在强化生物除磷系统中的生化模型反应机理.重点介绍了聚磷菌(PAOs)、聚糖菌(GAOs)和产乳酸菌在厌氧/好氧条件下对能量及还原力(NADH2)的利用方式;聚-β-羟基链烷酸盐(PHA)的合成方式及存在形式,糖原、乳酸(L型)的代谢途径等.虽然控制基质条件可以实现稳定的强化生物除磷效果,但目前的生化模型并不能完全解释所有的代谢过程,今后要在分离纯种的PAOs及相关生化代谢过程中酶的活动等方面进行深入研究.